采用氧化和析出的方法在氧化硅中凝聚生成锗纳米晶体量子点结构.其形成的锗晶体团簇没有突出的棱角和支晶结构,锗晶体团簇的轮廓较圆混,故可以用球形量子点模型来模拟实际的锗晶体团簇.对比了在高温(800℃~1000℃)条件下和在低温(200℃~500℃)用激光照射条件下所生成的锗纳米晶体结构的PL光谱和对应的锗纳米晶体团簇的尺寸分布.低温用激光照射条件下所生成的锗纳米晶体较小,其PL光谱出现蓝移.用量子点受限模型计算了锗纳米晶体团簇的能隙结构,用Monte Carlo方法模拟了PL光谱和对应的锗纳米晶体团簇的尺寸分布,分别与实验结果吻合较好.
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