引入了一种可以直观展现出聚合物体异质结太阳能电池伏安特性的数值模型,该模型主要研究由双分子复合以及温度和电场效应下自由载流子产生的机制.该机理在聚合物材料中得到很好的体现,材料中空间电荷效应只起到微弱的作用,从而在模型中形成相对恒定的电场.此外,在短路条件下只有7％的自由载流子由于双分子复合而消失.理论模型及结果表明在PPV/PCBM太阳能电池中随着空穴迁移率的增加和减少受体0.5电子伏特将得到5.5％的最高转换效率.
参考文献
| [1] | Wallace C H;Sha W;Li X.Multi-physical properties of plasmonic organic solar cells[J].Progress in Electromagnetics Research,2014146:25-46. |
| [2] | Shaheen S E;Brabec C J;Sariciftci N S.2.5％ efficient organic plastic solar cells[J].Applied Physics Letters,201178:835-841. |
| [3] | Duren J V;Yang X;Loos J.Relating the morphology of poly(p-phenylene vinylene)/methanofullerene blends to solar-cell performance[J].Advanced Functional Materials,200414:420-425. |
| [4] | Christoph J. Brabec;Antonio Cravino;Dieter Meissner.Origin of the Open Circuit Voltage of Plastic Solar Cells[J].Advanced functional materials,20015(5):374-380. |
| [5] | Vlaentin D. Mihailetchi;Jeroen K. J. van Duren;Paul W. M. Blom;Jan C. Hummelen;Rene A. J. Janssen;Jan M. Kroon;Minze T. Rispens;Wil Jan H. Verhees;Martijn M. Wienk.Electron Transport in a Methanofullerene[J].Advanced functional materials,20031(1):43-46. |
| [6] | Selberherr S.Analysis and Simulation of Semiconductor Devices[M].Wien,Germany:Springer-Verlag,1984 |
| [7] | Melzer C;Koop EJ;Mihailetchi VD;Blom PWM.Hole transport in poly(phenylene vinylene)/methanofullerene bulk-heterojunction solar cells[J].Advanced functional materials,20049(9):865-870. |
| [8] | Brabec C J;Sariciftci N S;Hummelen J C.Tracing photoinduced electron transfer process in conjugated polymer/fullerene bulk heterojunctions in real time[J].Advanced Functional Materials,201111:10-15. |
| [9] | Green M A.Solar Cells Operating Principles,Technologyand System Applications[M].Prentice Hall,Englewood Cliffs,N J,1982 |
| [10] | Onsager L.Initial recombination of ions[J].Physical Review,193854(8):550-554. |
| [11] | Scharfetter D L;Gummel H K.Large-signal analysis of a silicon read diode oscillator[J].IEEE Transactions on Electron Devices,196916:60-64. |
| [12] | Mihailetchi V D;Blom P W;Hummelen J C.Cathode dependence of the open-circuit voltage of polymer:Fullerene bulk heterojunction solar cells[J].Journal of Applied Physics,200394:6840-6849. |
| [13] | Sakata I;Hayashi Y.Theoretical analysis of trapping and recombination of photogenerated carriers in amorphous silicon solar cells[J].Applied Physics A(Materials Science and Processing),198537(3):153-164. |
| [14] | Bright A W;Makin B.Polar liquids:A survey of purification,conduction mechanisms,and interfacial effects[J].Journal of Materials Science,19672(2):184-193. |
| [15] | Boeuf J P.Self-consistent models of DC and transient glow discharges[J].Physics and Applications of Pseudosparks,1990219:255-275. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%