根据热失重曲线和运用 X 射线衍射(XRD)所测得的实验结果,讨论了聚糠醇(PFA)和聚糠酮(PFK)两种呋喃树脂在氮气气氛中热解过程中的结构变化.结果表明,两种试样在450℃以前,随着炭化温度的升高,聚合物分子的原有序态结构逐渐被破坏;450℃以后,随着炭化温度的升高,六角碳网新的序态结构形成并逐渐增长.
参考文献
| [1] | 齐藤羲平;山田惠彦 .特殊炭素制品[J].工业材料(日本),1966,14(12):46-52. |
| [2] | Marsh H;Rand B .The process of activation of carbons by gasification with CO2-Ⅱ.The role of catalytic impurities[J].Carbon,1971,9(01):63-77. |
| [3] | 本田英昌;真田雄三;古田毅 等.Vitro carbon made from acetone-furfural resin[J].炭素(日),1966,46:2-9. |
| [4] | Marsh H;Adair R R .Catalytic gasification of doped carbon-A kinetic study[J].Carbon,1975,13(04):327-332. |
| [5] | Neffe S .Electrochemical corrosion of glasslike carbon in sulfuric acid solution[J].Carbon,1988,26(05):687-692. |
| [6] | Uwai T;Inagaki W.Preparation of high-density glassy carbon from polyimide[A].,1990:318. |
| [7] | Kyotani T;Moriyama H;Tomita A .High temperature treatment of polyfurfuryl alcohol/graphite oxide intercalation compound[J].CARBON,1997,35(08):1185-1203. |
| [8] | Johnson K K;Jones L E.Phenol-formaldehyde resin structure for the synthesis of glassy carbon[A].Pennsylvania university,1997:478. |
| [9] | Fitzer E;Schāefer W;Yamada S .The formation of glasslike carbon by pyrolysis of polyfurfuryl alcohol and phenolic resin[J].Carbon,1969,7(06):643-648. |
| [10] | Fitzer E;Schāfer W .The effect of crosslinking on the formation of glasslike carbon from thermosetting resins[J].Carbon,1970,8(03):353-364. |
| [11] | 赵根祥;贾世军;钱树安 .PI 膜转变为炭膜过程中的结构变化[J].炭素技术,1997,4(05):12-17. |
| [12] | 小林和夫.用X射线衍射法测定的碳结构的参量[J].炭素译从,1982(02):19-23. |
| [13] | Wang Z.;Huang X.;Xue R.;Chen L.;Lu Z. .Chemical and crystalline structure characterizations of polyfurfuryl alcohol pyrolyzed at 600 degrees C[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(1/2):51-59. |
| [14] | Mathur R B;Bahl O P;Mittal J et al.Structure of thermally stabilized PAN fibers[J].CARBON,1991,29(07):1059-1061. |
| [15] | Mitra G B;GiriA K;Sanyal S K .Origin of extragraphitic low angle peaks in X-ray diffraction patterns of amorphous carbon[J].Indian Journal of Physics and Proceedings of The Indian Association For The Cultivation of Science,1986,60:256. |
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