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根据实测高精度氮气吸附等温线详细介绍了活性炭纤维微孔结构的分析方法如DR图、t图和αs图。由这三种分析方法获得的活性炭纤维的微孔容量相同,由t图和αs图获得的微孔结构参数也具有很好的一致性。DR图法有一定的理论基础,不需要标准吸附等温线,能获得与微孔表面能相关的特征吸附能;t图和αs图法能得到总表面积、内表面积和外表面积。一般认为αs图法比t图法更适合于微孔结构的分析。

Several methods for analysis on micropore structure of activatedcarbon fiber, such as DR-plot, t-plot and αs-plot, were described on the basis of the nitrogen adsorption isotherms determined experimentally. Micropore volume of activated carbon fiber obtained by the three methods was identical, and the micropore structure parameters obtained by t-plot and αs-plot were in good agreement. DR-plot, which can be deduced theoretically without standard adsorption isotherm, can get the characteristic adsorption energy related to the micropore surface, while t-plot and αs-plot can get the total, internal and external surface area. It is considered that αs-plot is more suitable for the analysis of micropore structure than t-plot.

参考文献

[1] 王曾辉;高晋生.碳素材料[M].上海:华东化工学院出版社,1991:185.
[2] Kaneko K;Ishii C;Ruike M et al.Origin of superhigh surface area and microcrystalline graphitic structures of activated carbons[J].Carbon,1992,30(07):1075-1088.
[3] 杨全红;郑经堂;李开喜 等.用密度函数理论和杜比宁方程研究活性炭纤维多段填充机理[J].离子交换与吸附,1998,14(05):397-404.
[4] Gregg S J;Sing K S W.Adsorption,Surface area and porosity[M].London:Academic Press,1982
[5] 杨全红;郑经堂;王茂章 等.超大比表面积活性炭纤维对氮的多段吸附机理[J].材料研究学报,1999,13(02):194-201.
[6] 刘振宇;郑经堂;王茂章 等.PAN基ACF的孔结构表征[J].材料研究学报,1999,13(05):477-482.
[7] 濑户山德;金子克美 .活性炭のナノ构造と分子吸着性[J].材料科学(日本),1995,32(05):213-218.
[8] 进藤精一;石川达雄;安部郁夫.吸着の科学(日文)[M].东京:丸善,1991:76-82.
[9] 金子克美 .气体の吸着[J].色材(日本),1994,67(02):115-123.
[10] Setoyama N;Li G;Kaneko K et al.Nitrogen adsorption on fluorinated activated carbon fiber[J].ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY,1996,2:293-297.
[11] McEnaney B .Adsorption and structure in microporous carbons[J].Carbon,1988,26(03):267-274.
[12] 李国希,刘晓春.活性炭纤维微孔结构的t图法分析[J].湖南大学学报,1999(01):26-28.
[13] 金子克美 .ナノ糸 田孔体と分子吸着[J].Petrotech(日本),1994,17(05):396-401.
[14] Setoyama N;Ruike M;Kaneko K et al.Surface characterization of microporous solids with He adsorption and small angle X-ray scattering[J].Langmuir,1993,9(10):2612-2617.
[15] Carrott P J M;Roberts R A;Sing K S W .Adsorption of neopentane by nonporous carbons and solids[J].LANGMUIR,1988,4(03):740-743.
[16] Carrott P J M;Roberts R A;Sing K S W .Standard nitrogen adsorption data for nonporous carbons[J].Carbon,1987,25(06):769-770.
[17] Carrott P J M;Roberts R A;Sing K S W .Adsorption of nitrogen by porous and non-porous carbons[J].Carbon,1987,25(01):59-68.
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