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首次以二乙烯基苯为交联剂,在酸性催化剂的作用下对煤沥青进行了改性研究,同时对改性后的煤沥青进行显微结构和耐热性分析。研究结果表明:改性后的煤沥青不仅出现大量的中间相小球,而且耐热性优良,可作为炭材料优质的基体前驱体。

Modification of coal tar pitch as a carbon precursor was studied using divinylbenzene (DVB) as a cross-linking agent by the aid of acid catalyst. The microstructure and thermostability of modified coal tar pitch had been studied. It was indicated that the modified coal pitch, which had not only a great deal of mesophase microbead but good thermostability as well, can be qualified to be an excellent carbon precursor.

参考文献

[1] 李铁虎.用改质沥青制备C/C复合材料的研究[J].材料工程,1992(07):17.
[2] 李铁虎;杨峥;郑修麟 .交联剂在C/C复合材料沥青基体中的作用[J].西北工业大学学报,1992,10(04):482-485.
[3] 唐恢同.有机化合物的光谱分析[M].北京:北京大学出版社,1992:157-159.
[4] 吕永根,凌立成,吴东,刘朗,张碧江.煤焦油热解制备中间相炭微球[J].燃料化学学报,1998(05):463-467.
[5] Gerard I.;Furdin G.;Mareche JF.;Begin D. .Pyrolysis of coal tar pitch with graphite-MoCl5 intercalation compound[J].Fuel,1998(6):607-611.
[6] Brzozowha T;Zielinski J;Machnikowski J .Effect of polymeric additives to coal tar pitch on carbonization behavior and opitcal testure of resultant cokes[J].Journal of Analytical and Applied Pyrolysis,1998,48(01):45-58.
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