从催化剂负载于碳纳米管的方法,碳纳米管的电学性能、储氢性能及独特的管腔结构对催化反应的影响几方面对碳纳米管作为催化剂载体的研究进展进行了论述,指出由于碳纳米管的疏水性,使得制备催化剂时,溶剂的选择十分重要;碳纳米管独特的电学性能使之成为催化剂载体的同时亦充当了助剂;碳纳米管的储氢性能使之在催化加氢反应中得到了最为广泛的应用;其独特的管腔结构则成为择形催化的好场所.而制约碳纳米管应用的因素在于其制备的规模和工艺.
参考文献
| [1] | Lijima sumio .Helical Microtubules of Griphitic Carbon[J].Nature,1991,354:56-58. |
| [2] | 慈立杰,魏秉庆,梁吉.碳纳米管的制备[J].新型碳材料,1998(02):65-71. |
| [3] | 朱宏伟,慈立杰,梁吉,魏秉庆,徐才录,吴德海.浮游催化法半连续制取碳纳米管的研究[J].新型炭材料,2000(01):48-51. |
| [4] | 刘畅,丛洪涛,成会明.氢等离子电弧法半连续制备单壁纳米碳管[J].新型炭材料,2000(02):1-5. |
| [5] | 杨子芹,沈曾民,陈晓红,查旭峰.Co催化热分解制备弯曲状碳纳米管的研究[J].新型炭材料,2000(02):34-38. |
| [6] | 刘畅,成会明.电弧放电法制备纳米碳管[J].新型炭材料,2001(01):67-71. |
| [7] | 潘春旭,Liming Yuan,Kozo Saito.扩散火焰合成碳纳米管研究[J].新型炭材料,2001(03):24-27. |
| [8] | 邱介山,韩红梅,周颖,胡德生,曾适之,P J F Harris.由二种烟煤制备碳纳米管的探索性研究[J].新型炭材料,2001(04):1-6. |
| [9] | 沈建其,何少龙,王新庆,王淼.单壁纳米碳管储氢机制研究[J].新型炭材料,2001(02):24-26,65. |
| [10] | 刘治,陈晓红,宋怀河.一维碳纳米材料储氢机理及应用前景[J].新型炭材料,2002(02):73-76. |
| [11] | Dresselhaus M S .Nanotechnology: new tricks with nanotubes[J].Nature,1998,391:19. |
| [12] | Collins PG. Zettl A. Bando H. Thess A. Smalley RE. .NANOTUBE NANODEVICE[J].Science,1997(5335):100-103. |
| [13] | Chiohio L;Crespi V H .Pure carbon nanoscale devices: nanotube heterojunctions[J].Physical Review Letters,1996,76:971. |
| [14] | Rodriguez Nelly M;Kim myung-soo;Terry R et al.Carbon nanofibers: a unique catalyst support medium[J].Journal of Physical Chemistry,1994,98:13108-13111. |
| [15] | Zhang Yu;Zhang Hong-Bin .Preparation, characterization and catalytic hydroformylation properties of carbon nanotubes-supported Rh-phosphine catalyst[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2000(2):213-224. |
| [16] | Chen hong-bo;Lin jing-dong;Cai Yun et al.Novel multi-walled nanotubes-supported and alkali-promoted Ru catalysts for ammonia synthesis under atmosphenic pressure[J].Applied Surface Science,2001,180:328-335. |
| [17] | 张爱民,谢德,王仰东,鲍书林,须沁华.Co/纳米碳管的催化裂化性能[C].新世纪的催化科学与技术（第十届全国催化学术会议：论文专辑）,2000:363-364. |
| [18] | Ago Hiroki;Kugler Thomas;Cacialli Franco et al.Articles-physical chemistry of surfaces and interfaces-work functions and surface functional groups of multiwall carbon nanotubes[J].Journal of Physical Chemistry,1999,B103:8116-8121. |
| [19] | 陈萍,张鸿斌,林国栋,蔡启瑞.催化裂解CH4或CO制碳纳米管结构性能的谱学表征[J].高等学校化学学报,1998(05):765-769. |
| [20] | 黄仲涛;林维明;庞先燊.工业催化剂的设计与开发[M].广州:华南理工大学出版社,1992:378. |
| [21] | 林敬东,陈鸿博,蔡云,魏光,张鸿斌,廖代伟.钾促进纳米碳管负载型铁基合成氨催化剂[C].新世纪的催化科学与技术（第十届全国催化学术会议：论文专辑）,2000:45-46. |
| [22] | Chen P;Wu X;Lin J et al.High H2 uptake by alkali-doped carbon nanotubes under ambient pressure and moderate temperature[J].Science,1999,285:91-93. |
| [23] | 陈鸿博;王进;林敬东.碳纳米管负载的铑基甲醇合成催化剂的研究[A].太原:山西科学技术出版社,2000:421-422. |
| [24] | Planeix J M;Coustel N;Coq B et al.Application of carbon nanotubes as support in heterogeneous catalysis[J].Journal of the American Chemical Society,1994,116:7935-7940. |
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