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  4. 炭膜制备及其高效氧氮分离性能

新型炭材料, 2004, 19(1): 69-76. doi: 10.3969/j.issn.1007-8827.2004.01.015

炭膜制备及其高效氧氮分离性能

李新贵 1, , 刘睿 2, , 黄美荣 3,

1.同济大学,材料学院混凝土材料研究实验室,材料化学研究所,上海,200092

2.同济大学,材料学院混凝土材料研究实验室,材料化学研究所,上海,200092

3.同济大学,材料学院混凝土材料研究实验室,材料化学研究所,上海,200092

基金项目:   国家自然科学基金(20174028)  

关键词： 炭膜 , 炭分子筛膜 , 氧氮分离 , 无机膜

The preparation of a carbon membrane and its highly effective separation of oxygen over nitrogen

通过论述炭膜的制备方法及其关键影响因素,系统总结了炭膜的氧氮分离性能,并将其与高性能聚吡咙膜和聚苯胺膜进行了比较,提出了今后的发展方向.指出炭膜具有优异的氧氮分离性能,其氧氮分离因子一般为10以上,最高可达36.聚酰亚胺基和聚吡咙基炭膜均表现出较好的综合氧氮分离性,大大突破了富氧膜材料的Robeson上限,位于极具吸引力的商业化区域,在空气分离中显示出了极大的应用潜力和工业化前景.

参考文献

[1] 郑领英;王学松.膜技术[M].北京:化学工业出版社,2000
[2] 黄美荣,周海骏,李新贵,张炜.高性能气体分离聚苯胺膜[J].现代化工,2003(01):16-19,23.
[3] Li XG.;Zhu LH.;Yang YL.;Huang MR. .Synthesis and air separation of soluble terpolymers from aniline, toluidine, and xylidine[J].Journal of Applied Polymer Science,2001(4):790-798.
[4] Li X G;Huang M R;Gu G F .Actual air separation through poly(aniline- co-toluidine)/ethylcellulose blend thin-film composite membranes[J].Journal of Applied Polymer Science,2000(75):458-463.
[5] Huang MR.;Xu QW.;Gu SY.;Wu YH.;Dong ZQ.;Wang J.;Shao HT.;Wang XS. .Oxygen enrichment across blend membranes of bipyridine and ethyl cellulose[J].Journal of Applied Polymer Science,2003(8):1371-1381.
[6] Li XG.;Springer J.;Nissen J.;Yang YL.;Kresse I. .Morphology and gas permselectivity of blend membranes of polyvinylpyridine with ethylcellulose[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(16):6859-6869.
[7] 邱海鹏,刘朗.炭分离膜[J].新型炭材料,2003(01):80-80.
[8] 赵银祥.炭膜[J].新型炭材料,2003(03):237-238.
[9] JONES C W;Koros W J .Carbon molecular sieve gas separation membranes-I.Preparation and characterization based on polyimide precursors[J].CARBON,1994,32:1419-1427.
[10] A. B. Fuertes;T. A. Centeno .Carbon molecular sieve membranes from polyetherimide[J].Microporous and Mesoporous Materials,1998(1/3):23-26.
[11] Shiflett M B;Foley H C .Ultrasonic deposition of high selectivity nanoporous carbon membranes[J].Science,1999,285:1902-1904.
[12] Michael S. Strano;Henry C.Foley .Temperature-and pressure-dependent transient analysis of single component permeation through nanoporous carbon membranes[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(7):1029-1041.
[13] Kusakabe K.;Morooka S.;Yamamoto M. .Gas permeation and micropore structure of carbon molecular sieving membranes modified by oxidation[J].Journal of Membrane Science,1998(1):59-67.
[14] Fuertes A B;Nevskaia D M;Centeno T A .Carbon composite membranes from Matrimid(R) and Kapton(R) polyimides for gas separation[J].Microporous and Mesoporous Materials,1999(33):115-125.
[15] Hayashi J.;Yamamoto M.;Kusakabe K.;Morooka S.;Mizuta H. .PORE SIZE CONTROL OF CARBONIZED BPDA-PP'ODA POLYIMIDE MEMBRANE BY CHEMICAL VAPOR DEPOSITION OF CARBON[J].Journal of Membrane Science,1997(2):243-251.
[16] Wang H T;Zhang L X;Gavalas G .Preparation of supported carbon membrane from furfuryl alcohol by vapor deposition polymerization[J].Journal of Membrane Science,2000,177:25-31.
[17] Liu P K T;Gallaher G R;Wu J C S .Method of producing a carbon coated ceramic membrane and associated product[P].US:5262198,1993.
[18] Soffer A;Azariah M;Amar A et al.Method of improving the selectivity of carbon membranes by chemical carbon vapor deposition[P].US:5695818,1997.
[19] Li YY.;Nomura T.;Sakoda A.;Suzuki M. .Fabrication of carbon coated ceramic membranes by pyrolysis of methane using a modified chemical vapor deposition apparatus[J].Journal of Membrane Science,2002(1/2):23-35.
[20] Shiflett MB.;Foley HC. .On the preparation of supported nanoporous carbon membranes[J].Journal of Membrane Science,2000(1/2):275-282.
[21] H. Hatorl;T. Kobayashi;Y. Hanzawa .Mesoporous Carbon Membranes from Polyimide Blended with Poly(ethylene glycol)[J].Journal of Applied Polymer Science,2001(5):836-841.
[22] Madhav Acharya;Brenda A.Raich;henry C.Foley .Metal-supported carbogenic molecular sieve membranes: synthesis and applications[J].Industrial & Engineering Chemistry Research,1997(8):2924-2930.
[23] Acharya Madhav;Foley Henry C. .Spray-coating of nanoporous carbon membranes for air separation[J].Journal of Membrane Science,1999(1):1-5.
[24] Shiflett M B;Foley H C .Reproducible production of nanoporous carbon membranes[J].Carbon,2001,39:1421-1446.
[25] David LIB.;Ismail AF. .Influence of the thermastabilization process and soak time during pyrolysis process on the polyacrylonitrile carbon membranes for O-2/N-2 separation[J].Journal of Membrane Science,2003(1/2):285-291.
[26] Kita H;Yoshino M;Tanaka K.Gas permselecivity of carbonized polypyrrolone membrane[J].Journal of the Chemical Society,Chemical Communications,1997:1051-1052.
[27] Keisha M. Steel;William J. Koros .Investigation of porosity of carbon materials and related effects on gas separation properties[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(2):253-266.
[28] Anshu Singh-Ghosal;W.J.Koros .Air separation properties of flat sheet homogeneous pyrolytic carbon membranes[J].Journal of Membrane Science,2000(2):177-188.
[29] Suda H;Haraya K .Gas permeation through micropores of carbon molecular sieve membranes derived from kapton polyimide[J].Journal of Physical Chemistry B,1997,101:3988-3994.
[30] A. F. Ismail;L. I. B. David .A review on the latest development of carbon membranes for gas separation[J].Journal of Membrane Science,2001(1):1-18.
[31] Gao X S;Tan Z S;Lu F C .Gas permeation properties of some polypyrrolones[J].Journal of Membrane Science,1994,88(01):37-45.
[32] ZIMMERMAN CATHERINE M.;KOROS WILLIAM J. .Polypyrrolones for Membrane Gas Separations. I. Structural Comparison of Gas Transport and Sorption Properties[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(12):1235-1249.
[33] Anderson M R;Mattes B R;Reiss H et al.Conjugated polymer films for gas separation[J].Science,1991,252:1412-1415.
[34] Cheryl W. Jones;William J. Koros .Characterization of Ultramicroporous Carbon Membranes with Humidified Feeds[J].Industrial & Engineering Chemistry Research,1995(1):158-163.
[35] Ivan Menendez;Antonio B.Fuertes .Aging of carbon membranes under different environments[J].Carbon: An International Journal Sponsored by the American Carbon Society,2001(5):733-740.
[36] Cheryl W. Jones;William J. Koros .Carbon Composite Membranes: A Solution to Adverse Humidity Effects[J].Industrial & Engineering Chemistry Research,1995(1):164-167.
[37] Vu D Q;Koros W J;Miller S J .Mixed matrix membranes using carbon molecular sieves Ⅰ.Preparation and experimental results[J].Journal of Membrane Science,2003,211:311-334.
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