以甲烷为碳源,Fe2O3/Ni为固定相催化剂,在常压条件下利用等离子体射流的高温将甲烷裂解生成碳自由基和氢气.同时联合原位催化法将碳自由基在Fe2O3/Ni双催化剂的共同作用下生长出碳纳米管.运用TEM和元素分析等测试手段对所得碳纳米管进行形貌、含量、结构的表征分析.结果表明,在一定反应条件下,可获得外径为10 nm~30 nm,管长约数百纳米、产率为75 %左右的碳纳米管.与单催化剂相比,双催化剂的联合催化作用更有利于碳管的生长.
参考文献
[1] | Endo M.;Kobori K.;Takahashi K.;Kroto HW.;Sarkar A.;Takeuchi K. .PYROLYTIC CARBON NANOTUBES FROM VAPOR-GROWN CARBON FIBERS[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(7):873-881. |
[2] | 李峰,白朔,成会明.纳米碳管[J].新型炭材料,2000(03):79-80. |
[3] | 陈晓红,宋怀河.多壁碳纳米管填充丁苯橡胶复合材料的研究[J].新型炭材料,2004(03):214-218. |
[4] | 童昕,赫秀娟,成会明.添加纳米碳管对高密度聚乙烯力学行为和结晶过程的影响[J].新型炭材料,2004(04):261-267. |
[5] | 佟钰,任文才,赵志刚,刘畅,成会明.真空度对纳米碳管场发射性能的影响[J].新型炭材料,2003(02):101-105. |
[6] | 戴贵平,刘敏,王茂章,成会明.纳米碳管电化学储氢的研究进展[J].新型炭材料,2002(03):70-74. |
[7] | 王敏炜,李凤仪,彭年才.碳纳米管--新型的催化剂载体[J].新型炭材料,2002(03):75-79. |
[8] | Joumet C;Maser W K;Bernier P et al.Large-scale synthesis of carbon nanotubes[J].Nature,1997,388(6644):756-758. |
[9] | 刘畅,丛洪涛,成会明.氢等离子电弧法半连续制备单壁纳米碳管[J].新型炭材料,2000(02):1-5. |
[10] | Yacaman M J;Yoshida M;Rendon L .Catalytic growth of carbon microtubes with fullerene structure[J].Applied Physics Letters,1993,62(06):657-659. |
[11] | 王敏炜,李凤仪,彭年才.Ni-La-Mg上催化裂解甲烷生成碳纳米管的研究[J].新型炭材料,2005(01):28-32. |
[12] | 李颖,李轩科,刘朗.不同原料气催化热解法制备碳纳米管的研究[J].新型炭材料,2004(04):298-302. |
[13] | 杨子芹,沈曾民,陈晓红,查旭峰.Co催化热分解制备弯曲状碳纳米管的研究[J].新型炭材料,2000(02):34-38. |
[14] | Guo T;Nikolaev D;Rinzler A D et al.Self - assembly of tubular fullerenes[J].Journal of Chemical Physics,1995,243:49-54. |
[15] | Cho W S;Hamada E;Kondo Y et al.Synthesis of carbon nanotubes from polymer[J].Applied Physics Letters,1996,69(02):278-280. |
[16] | Tibbetts G G .Why are carbon filaments tubular[J].Journal of Crystal Growth,1984,66:632-638. |
[17] | 朱宏伟,慈立杰,梁吉,魏秉庆,徐才录,吴德海.浮游催化法半连续制取碳纳米管的研究[J].新型炭材料,2000(01):48-51. |
[18] | 潘春旭,Liming Yuan,Kozo Saito.扩散火焰合成碳纳米管研究[J].新型炭材料,2001(03):24-27. |
[19] | 王茂章,李峰,杨全红,成会明.由不同碳源合成及制备纳米碳管的进展[J].新型炭材料,2003(04):250-264. |
[20] | Iijima S;Ichihashi T .Single-shell carbon nanotubes of 1-nm diameter[J].Nature,1993,363:603-605. |
[21] | Zhang X B;Zhang X F;Bernastrts D et al.The texture of catalytically grown coil-shaped carbon nanotubes[J].Europhysics Letters,1994,27:141-144. |
[22] | Hsu W.K.;Trasobares S.;Terrones H.;Terrones M.;Grobert N.;Takikawa H.;Hare J.P.;Kroto H.W.;Walton D.R.M.;Zhu Y.Q. .Solid-phase production of carbon nanotubes[J].Applied physics, A. Materials science & processing,1999(4):493-495. |
[23] | Lijima S .Helical Microtubules of Griphitic Carbon[J].Nature,1991,354(6348):56-58. |
[24] | Shi Z J;Lian Y F;Zhou X H et al.Production of single-wall carbon nanotubes at high pressure[J].Journal of Physical Chemistry B,1999,103:8689-8691. |
[25] | Wang XK.;Mesleh M.;Jarrold MF.;Dravid VP.;Ketterson JB. Chang RPH.;Lin XW. .THE EFFECT OF HYDROGEN ON THE FORMATION OF CARBON NANOTUBES AND FULLERENES[J].Journal of Materials Research,1995(8):1977-1983. |
[26] | Hernadi K;Fonseca A;Nagy J B et al.Catalytic synthesis and purification of carbon nanotubes[J].Synthetic Metals,1996,77:31-34. |
[27] | Feigney A;Laurent C;Dobigeon F et al.Carbon nanotubes grown in a novel catalytic method[J].Journal of Materials Research,1997,12(03):613-615. |
[28] | 雷中兴,刘静,王建波,李轩科,汪厚植.催化剂结构与形态对碳纳米管生长的影响[J].新型炭材料,2003(04):271-276. |
[29] | Thess A;Lee R;Nikolaev P et al.Crystalline ropes of metallic carbon nanotubes[J].Science,1996,273:483-487. |
[30] | Baker R T K;Haris P S;Thomas R B et al.Formation of filamentous carbon from iron,cobalt and chromium caralyzed decomposition of acetylene[J].Journal of Catalysis,1983,30:86-95. |
[31] | Ivanov V;Nagy J B;Lambin P et al.The study of carbon nanotubes produced by catalytic method[J].Chemical Physics Letters,1994,223:329-335. |
[32] | RODRIGUEZ N M .Commentaries and reviews[J].Journal of Materials Research,1993,8(12):3233-3250. |
[33] | Jose-Yacaman M;Miki-Yoshida M;Rendon L .Caralytic growth of carbon microtubes with fullerens structure[J].Applied Physics Letters,1993,62(06):657-659. |
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