随着超滤膜技术的发展,人们对超滤膜提出了各种各样的特性要求,其中解决膜表面的污染问题变得越来越紧迫.超滤膜改性,尤其是在膜表面引入亲水性基团是解决问题的关键.本文从这点出发,结合自身的工作,总结了近年高分子超滤膜改性方面的研究进展,包括表面活性剂在膜表面的吸附改性、等离子体改性、辐照改性、高分子合金和表面化学反应等几种改性方法.
参考文献
[1] | Osada Y;Nakagawa T.Membrane Science and Technology[M].New York: Marcel Dekker,Inc,1992:321-326. |
[2] | 陆晓峰;陈仕意;李存珍 等.表面活性剂对超滤膜表面改性的研究[J].膜科学与技术,1997,17(04):6-41. |
[3] | Shigendo A;Yang L;Takeuchi H .Micellar-enhanced ultrafiltration of gold with ninionic sufactant[J].Journal of Membrane Science,1997,133(02):189-194. |
[4] | Christian S D;Bhat S N;Tucker E E et al.Micellar-enhanced ultrafiltration of chromate anion from aqueous streams[J].AICHE Journal,1988,34:189-194. |
[5] | Morel G.;Graciaa A.;Lachaise J.;Ouazzani N. .SURFACTANT MODIFIED ULTRAFILTRATION FOR NITRATE ION REMOVAL[J].Journal of Membrane Science,1997(1):47-57. |
[6] | Yooh Y;Yoon J;Amy G et al.Ues of surfactants to modify negatively charged ultrafiltration membranes for perchlorate removal[J].Am Chem Soc Division of Environmental Chemistry,2000,40(02):300-302. |
[7] | 邱晔;王真;洪品杰 等.微波等离子体处理聚乙烯膜的表面结构分析[J].化学物理学报,1997,10(03):280-283. |
[8] | Ulbricht M;Belfort G .Surface modifcation of ultrafiltration membranes by low temperature plasma.Ⅱ.Graft polymerization onto polyacrylonitrile and polysulphone[J].Journal of Membrane Science,1996,111(02):193-215. |
[9] | 郭明远;樊芷芸;杨牛珍 等.醋酸纤维素超滤膜低温氧等离子体表面改性[J].膜科学与技术,1997,17(06):10-15. |
[10] | 陆晓峰,刘光全,刘忠英,王彬芳.紫外辐照改性聚砜超滤膜[J].膜科学与技术,1998(05):50-54. |
[11] | John Pieracci;James V. Crivello;Georges Belfort .Increasing membrane permeability of UV-modified poly(ether sulfone) ultrafiltration membranes[J].Journal of Membrane Science,2002(1/2):1-16. |
[12] | Pieracci J;David D W;Crivello J et al.UV-assisted graft Polymerization of N-vinyl-2-pyrrilidinone onto poly(ether sulfone)ultrafiltration membranes:Comparison of dip versus Immersion modification techniques[J].American Chemical Society,2000,12(08):2123-2133. |
[13] | Ulbricht M;Oechel A .Photomodification of ultrafiltration membranes.7.Photobromination and photo-induced graft polymerization as a two-step approach for surface modification of polyacrylonitrile ultrafiltration membranes[J].European Polymer Journal,1996,32(09):1045-1054. |
[14] | Kobayashi T;Fujii N .Preparation and properties of negative charged ultrafiltration membrane:Photografted sodium styrenesulfonate on brominated polyacrylonitrile membrane[J].Journal of Applied Polymer Science,1992,45(11):1897-1902. |
[15] | 郭明远,杨牛珍,樊芷芸,田伟,蒋莉.醋酸纤维素超滤膜γ射线辐照改性[J].水处理技术,1997(06):315. |
[16] | 郭远明;杨牛珍 .大剂量钴源辐照使醋酸纤维素膜改性的初探[J].西北纺织工学院学报,1996,10(03):302-304. |
[17] | 刘玉荣,陈东升,王力宁,陈一鸣,洪勇奇,龚敏.醋酸纤维素-丙烯腈接枝改性反渗透干膜[J].水处理技术,1996(06):323. |
[18] | 陆晓峰,汪庚华,梁国明,刘光全,王彬芳.聚偏氟乙烯超滤膜的辐照接枝改性研究[J].膜科学与技术,1998(06):54-57. |
[19] | Becker W;Schmidt-Naake G .Properties of polymer exchange membranes from irradiation introduces graft polymerization[J].Chemical Engineering and Technology,2001,24(11):1128-1132. |
[20] | Becker WI;Schmidt-Naake G .Proton exchange membranes by irradiation induced grafting of styrene onto FEP and ETPE:Influences of the crosslinker N,N,methylene-bisacrylamide[J].Chemical Engineering and Technology,2002,25(04):373-377. |
[21] | Ruskov T;Turmanova S;Kostov G;INST NUCL SCI & NUCL RES SOFIA 1574 BULGARIA. .Study of IR and Mossbauer spectroscopy of grafted metal complexes of poly(acrylic acid) on to low density poly(ethylene) and on to poly(tetrafluoroethylene)[J].European Polymer Journal,1997(8):1285-1288. |
[22] | Fang Y E;Zhao X;Ge X et al.Radiation graft copolymerization of 2-hydroxyethyl methacrylate on to poly(γ-methyl L-glutamate)membrane.study of regularity of graft copolymerization in aqueous solution[J].Radiation Physics and Chemistry,1997,49(05):589-593. |
[23] | Nakada S;Sawatari C;Tamura K et al.Hyperbranched modification of unsaturated side chains of polyethylene introduced by γ-ray irradiation under a 1,3-butadiene atmosphere[J].Colloid and Polymer Science,2001,279:754-762. |
[24] | 陆晓峰,毛伟钢,刘光全,沈卫东,梁国明,王彬芳.特种高分子合金的相容性及对合金超滤膜性能的影响[J].水处理技术,1993(05):253. |
[25] | 梁国明;陆晓峰;刘光全 等.特种高分子PEK/SPFS合金超滤膜性能与结构研究[J].膜科学与技术,1995,15(01):40-45. |
[26] | 陆晓峰,毛伟钢,刘光全,王彬芳.热孔法表征特种高分子合金超滤膜的孔径[J].膜科学与技术,1998(04):50-54. |
[27] | 刘振;郭敏杰 .聚丙烯腈共混膜的发展现状及研究进展[J].化工新型材料,1999,27(05):18-20. |
[28] | 刘永建,王庆瑞,陈雪英.聚丙烯腈与羟乙基纤维素共混膜的研制[J].中国纺织大学学报,1997(03):31-36. |
[29] | 刘永建;沈新元;王庆瑞 等.聚丙烯腈与二醋酸纤维素共混膜的研制[J].膜科学与技术,1997,17(06):34-45. |
[30] | 程洪斌,尹秀丽.聚偏氟乙烯/聚丙烯腈共混膜的研究[J].天津纺织工学院学报,1998(01):54-60. |
[31] | 邓国宏,余立新,郝继华,陈翠仙,李琳.聚乙烯醇/二氧化硅共混膜的制备及耐温、耐溶剂性能研究[J].高分子材料科学与工程,2001(06):122-125. |
[32] | 张裕卿,丁健.Al2O3的添加对聚砜膜性能的影响[J].化学工程,2000(05):42-44. |
[33] | Jerome D;Charles H.Method for gas phase sulfonation of polymer membranes[J].USAWO Pat:9726284,1997 |
[34] | HiguchiA;Iwata N;Nakagawa T .Surface-modified polysulfone hollow fibers.Ⅱ Fibers having CH2CH2CH2SO-3 segments and immersed in hydrochloric acid solution[J].Journal of Applied Polymer Science,1990,40:709-717. |
[35] | HiguchiA;Nakagawa T .Surface-modified polysulfone hollow fibers.Ⅲ.Fiber having a hydroxide group[J].Journal of Applied Polymer Science,1990,41:1973-1979. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%