欢迎登录材料期刊网

材料期刊网

高级检索

PV/PVP/Ag+膜在苯、环己烷混合物中的溶胀实验发现,膜优先吸附苯,且膜中Ag+含量越大,膜在苯中的溶胀率越大,在环己烷中溶胀率越小.渗透汽化测试结果也表明,PVA/PVP/Ag+膜对苯/环己烷的分离性能明显优于PVA/PVP膜.而且,随着膜中Ag+含量的增加,膜的渗透通量J增大;分离因子先增大后减小,当膜中w(聚合物)∶w(AgNO3)=1∶1时,分离因子α达到最大值,为47.5,通量为7.8 g/(m2*h)(进料的质量分数为10%,20 ℃).而对膜进行交联改性后,分离因子可进一步提高,但通量下降.

参考文献

[1] Teremoto M H;Matsuyama Yamashiro T et al.Separation of ethylene from ethane by supported liquid membranes containing sil er nitrate as a carrier[J].Journal of Chemical Engineering of Japan,1986,19(05):419-424.
[2] Kawakami M;Tateishi Twamoto M et al.Selecti e permeation of ethylene and propylene through Rh3+-polyethylene glycol liquid membranes[J].Journal of Membrane Science,1987,30:105-110.
[3] Ko al C A;Noble R D;Way J D et al.Selectie transport of gaseous CO through liquid membranes using an iron(II) macrocylic complex[J].Inorganic Chemistry,1985,24(08):1147-1152.
[4] Chen H L;Wu L G;Tan J .P A membrane filled β-cyclodextrin for separation of isomeric xylenes by per aporation[J].Chemical Engineering Journal,2000,78:159-164.
[5] Erisen O I;Aksnes E;Dahl I M .Facilitated transport of ethane through Nafion membranes Part I:Water swollen membranes[J].Journal of Membrane Science,1993,85:89-97.
[6] Kohls SL.;Koval CA.;Noble RD. .EFFECTS OF MOLECULAR STRUCTURE AND EQUIVALENT WEIGHT ON FACILITATED TRANSPORT OF ALKENES IN AG(I)-PFSI MEMBRANES[J].Journal of Membrane Science,1997(1):61-73.
[7] Ho W S;Dalrymple D C .Facilitated transport of olefins in Ag+-containing polymer membranes[J].Journal of Membrane Science,1994,91:13-25.
[8] Ryu J H;Lee H;Yong Jin Kim.Facilitated olefin transport by re ersible olefin coordination to sil er ions in a dry cellulose acetate membrane[J].Chemistry-A European Journal,2001(07):7-13.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%