综述了燃料电池用各种质子交换膜(PEM)材料及其改性方法.PEM材料包括全氟磺酸型离子交换树脂、聚苯并咪唑(PBI)、聚醚醚酮(PEEK)以及各种新型聚合物、嵌段共聚物等,而将这些材料制成PEM所采用的改性方法可分为磺化、酸基络合、杂化、共混、共聚、以及辐射接枝、等离子体等改性处理.还介绍了各种PEM材料的物性特点和PEM材料改性方法及其最新PEM研究报道.
参考文献
| [1] | 卢婷利,梁国正,辛文利,李文锋.燃料电池质子交换膜的研究进展[J].化工新型材料,2002(04):9-12. |
| [2] | 何燕,周震涛.燃料电池用质子交换膜的研究进展[J].电池,2002(03):168-170. |
| [3] | 吴洪,王宇新,王世昌.用于聚合物电解质膜燃料电池中的质子导电膜[J].高分子材料科学与工程,2001(04):7-11. |
| [4] | 于景荣,邢丹敏,刘富强,刘建国,衣宝廉.燃料电池用质子交换膜的研究进展[J].电化学,2001(04):385-395. |
| [5] | M.Rikukawa;K.Sauni .Proton-conducting polymer electrolyte membranes based on hydrocarbon polymers[J].Progress in Polymer Science,2000(10):1463-1502. |
| [6] | Kobayashi T.;Sanui K.;Ogata N.;Rikukawa M. .Proton-conducting polymers derived from poly(ether-etherketone) and poly(4-phenoxybenzoyl-1,4-phenylene)[J].Solid state ionics,1998(3/4):219-225. |
| [7] | Bae JM.;Honma I.;Murata M.;Yamamoto T.;Rikukawa M.;Ogata N. .Properties of selected sulfonated polymers as proton-conducting electrolytes for polymer electrolyte fuel cells[J].Solid state ionics,2002(1/2):189-194. |
| [8] | Glipa X.;Jones DJ.;Roziere J.;Elhaddad M. .SYNTHESIS AND CHARACTERISATION OF SULFONATED POLYBENZIMIDAZOLE - A HIGHLY CONDUCTING PROTON EXCHANGE POLYMER[J].Solid state ionics,1997(1/4):323-331. |
| [9] | Kawahara M.;Sanui K.;Ogata N.;Rikukawa M. .Synthesis and proton conductivity of sulfopropylated poly(benzimidazole) films[J].Solid state ionics,2000(Special Issue SI):1193-1196. |
| [10] | Vincenzo Tricoli;Nicola Carretta .Polymer electrolyte membranes formed of sulfonated polyethylene[J].Electrochemistry communications,2002(3):272-276. |
| [11] | Guo Qunhui;Tang Hao;O'Connor Sally;Pintauro Peter N. .Sulfonated and crosslinked polyphosphazene-based proton-exchange membranes[J].Journal of Membrane Science,1999(2):175-181. |
| [12] | Lufrano F.;Staiti P.;Antonucci V.;Passalacqua E.;Gatto I. .Sulfonated polysulfone ionomer membranes for fuel cells[J].Solid state ionics,2001(1/4):47-51. |
| [13] | Wang F.;Hickner M.;Kim YS.;Zawodzinski TA.;McGrath JE. .Direct polymerization of sulfonated poly(arylene ether sulfone) random (statistical) copolymers: candidates for new proton exchange membranes[J].Journal of Membrane Science,2002(1/2):231-242. |
| [14] | CA.Edmondson;J.J.Fontanella;S.H.Chung;S.G.Greebaum .Complex impedance studies of S-SEBS block polymer proton-conducting membranes[J].Electrochimica Acta,2001(10/11):1623-1628. |
| [15] | Kim J.;Kim B.;Jung B. .Proton conductivities and methanol permeabilities of membranes made from partially sulfonated polystyrene-block-poly(ethylene-ran-butylene)-block-polystyrene copolymers[J].Journal of Membrane Science,2002(1):129-137. |
| [16] | Kaur S;Florio G;Michalak D.Cross-linking of sulfonated styrene-ethylene/butylene-styrene triblock polymer via sulfonamide linkages[J].POLYMER,2003(19):5163-5167. |
| [17] | Mokrini A.;Acosta JL. .Studies of sulfonated block copolymer and its blends[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(1):9-15. |
| [18] | Bashir H.;Acosta JL.;Linares A. .Heterogeneous sulfonation of blend systems based on hydrogenated poly(butadiene-styrene) block copolymer. Electrical and structural characterization[J].Solid state ionics,2001(3/4):189-196. |
| [19] | C.Hasiotis;V.Deimede;C.Kontoyannis .New polymer electrolytes based on blends of sulfonated polysulfones with polybenzimidazole[J].Electrochimica Acta,2001(15):2401-2406. |
| [20] | Qiao J L;Yoshimoto N;Morita M.Proton conducting behavior of a novel polymeric gen membrane based on poly( ethylene oxide)-grafted-poly(methacrylate)[J].Journal of Power Sources,2002:45-51. |
| [21] | 周其凤;胡汉杰.高分子化学[M].北京:化学工业出版社,2001 |
| [22] | ADJEMIAN K T;Srinivasan S;Benziger J.Investigation of PEMFC operation above 100 ℃ employing perfluorosulf onic acid silicon oxide composite membranes[J].Journal of Power Sources,2002:356-364. |
| [23] | Jung D H;Cho S Y;Peck D H.Performance evaluation of a Nafion/silicon oxide hybrid membrane for direct methanol fuel cell[J].Journal of Power Sources,2002:173-177. |
| [24] | I. Hoflttid;S. HifalLSWdb;K. Y8ttisdd;J.M. Bdeld .Synthesis of organic/inorganic nanocomposites protonic conductingmembrane through sol-gel processes[J].Solid state ionics,1999(1/2):29-36. |
| [25] | I. Honma;Y.Takeda .Protonic conducting properties of sol-gel derived organic/inorganicnanocomposite membranes doped with acidic functional molecules[J].Solid state ionics,1999(1/4):255-264. |
| [26] | I. Honma;S. Nomura;H. Nakajima .Protonic conducting organic/inorganic nanocomposites for polymer electrolyte membrane[J].Journal of Membrane Science,2001(1):83-94. |
| [27] | Nakajima H.;Honma I. .Proton-conducting hybrid solid electrolytes for intermediate temperature fuel cells[J].Solid state ionics,2002(3/4):607-610. |
| [28] | Homna I.;Nakajima H.;Nomura S. .High temperature proton conducting hybrid polymer electrolyte membranes[J].Solid state ionics,2002(Pt.B):707-712. |
| [29] | Honma I;Nishikawa O;Sugimoto T.A sol-gel derived organic/inorganic hybrid membrane for intermediate temperature PEMFC[J].Fuel Cells,2002(01):52-58. |
| [30] | P. Costamagna;C. Yang;A. B. Bocarsly;S. Srinivasan .Nafion 115/zirconium phosphate composite membranes for operation of PEMFCs above 100 ℃[J].Electrochimica Acta,2002(7):1023-1033. |
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