采用抽空涂晶二次生长法在管状α-Al2O3基膜上合成了具有高选择性、高渗透量的A型分子筛膜.XRD结果表明,分子筛膜晶相中只有A型分子筛存在;SEM表明,基膜表面覆盖了一层致密连续的分子筛膜.考察了A型分子筛膜的渗透汽化性能,结果表明,在温度为323 K和343 K下,当原料液中异丙醇的质量分数为95%时,其水/异丙醇分离系数都大于10000,渗透量分别为1.27 kg/(m2·h)和1.74 kg/(m2·h).
参考文献
[1] | Xiaochun Xu;Weishen Yang;Jie Liu;Liwu Lin .Synthesis and perfection evaluation of NaA zeolite membrane[J].Separation and Purification Technology,2001(1):475-485. |
[2] | Triebe R W;Tezel F H;Khulbe K C .Adsorption of methane,ethane and ethylene on molecular sieve zeolite[J].Gas Separation and Purification,1996,10(01):81-84. |
[3] | Dudukovic M P .Trends in catalytic reaction engineering[J].Catalysis Today,1999,48:5-15. |
[4] | Re Lai;George R. Gavalas .Surface Seeding in ZSM-5 Membrane Preparation[J].Industrial & Engineering Chemistry Research,1998(11):4275-4283. |
[5] | Katsuki Kusakabe;Takahiro Kuroda;Atsushi murata .Formation of a Y-Type zeolite membrane on a porous α-alumina tube for gas separation[J].Industrial & Engineering Chemistry Research,1997(3):649-655. |
[6] | 张雄福,王金渠,殷德宏,刘长厚.用喷涂晶种法合成ZSM-5沸石膜及其影响因素考察[J].催化学报,2000(05):451-454. |
[7] | Munoz Jr T;Balkus Jr K J .Preparation of oriented zeolite UTD- 1 membranes via pulsed laser ablation[J].Journal of the American Chemical Society,1999,121:139-146. |
[8] | George Xomeritakis;Sankar Nair;Michael Tsapatsis .Transport properties of alumina-supported MFI membranes made by secondary (seeded) growth[J].Microporous and Mesoporous Materials,2000(1):61-73. |
[9] | Mintova S.;Valtchev V.;Schoeman BJ.;Sterte J.;Hedlund J. .ZSM-5 films prepared from template free precursors[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,1998(10):2217-2221. |
[10] | Sano T;Yanagishta H;Kiyozumi Y et al.Separation of ethanol/water mixture by silicate membrane on pervaporation[J].Journal of Membrane Science,1994,95:221-228. |
[11] | 徐晓春;杨维慎;刘杰 等.管状分子筛膜的乙醇/水渗透汽化分离性能[J].膜科学与技术,1999,19(04):39-43. |
[12] | Kita H;Horii K;Ohtoshi Y et al.Synthesis of zeolite NaA membrane for pervaproation of water/organic liquid mixtures[J].Journal of Materials Science Letters,1995,14:206-208. |
[13] | Jafar J J;Budd P M .Separation of alcohol/water mixtures by pervaporation through zeolite A membranes[J].Microporous Materials,1997,12:305-311. |
[14] | Shah D.;Ghorpade A.;Hannah R.;Bhattacharyya D.;Kissick K. .Pervaporation of alcohol-water and dimethylformamide-water mixtures using hydrophilic zeolite NaA membranes: mechanisms and experimental results[J].Journal of Membrane Science,2000(1/2):185-205. |
[15] | Sano T;Hasegawa M;Kawakami et al.Potentials of silicate membranes for the separation of alcohol/water mixtures[J].Journal of Studies in Surface Science and Catalysis,1994,84:1175-1182. |
[16] | 徐晓春 .分子筛膜的合成及渗透分离性能[D].中国科学院大连化学物理研究所,1999. |
[17] | 董强,徐南平,时钧.A型沸石分子筛膜微波合成及渗透汽化性能[J].化工学报,2001(08):749-752. |
[18] | Kondo M.;Kita H.;Okamoto K.;Komori M. .TUBULAR-TYPE PERVAPORATION MODULE WITH ZEOLITE NAA MEMBRANE[J].Journal of Membrane Science,1997(1):133-141. |
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