选用4种聚合单体:4,4'-六氟亚异丙基一邻苯二甲酸酐(6FDA)、双酚A二酐(BPA-DA)、4,4'-二氨基二苯甲烷(MDA)、3,3'-二甲基-4,4'-二氨基二苯甲烷(DMMDA),采用低温溶液缩聚-化学亚胺化合成了3种可溶性的聚酰亚胺:6FDA-MDA,6FDA-DMMDA,BPADA-DMMDA,利用FI-IR、NMR等对其结构进行了分析表征,测试了它们的溶解性能与热性能.将这3种聚酰亚胺溶于氯仿溶液中,在高湿度环境下浇铸形成规整多孔膜结构;研究了其规整孔结构的拉伸与吹扫特定形变,最后还研究了所得的规整多孔膜的高温热稳定性,发现在350℃仍能保持规整结构的稳定.
参考文献
| [1] | Jiang P;Hwang K S;Mittleman D M et al.Templatedirected preparation of macroporous polymers with oriented and crystalline arrays of voids[J].Journal of the American Chemical Society,1999,121:11630-11637. |
| [2] | Widawski G;Rawiso B;Francois B .Self-organized honeycomb morphology of star -polyrnerpolystyrene films[J].Nature,1994,369:387-389. |
| [3] | 陈观文,曾一鸣.膜微孔形成方法的研究进展[J].膜科学与技术,2003(04):116-122. |
| [4] | O. Pitois;B. Francois .Formation of ordered micro-porous membranes[J].The European physical journal, B. Condensed matter physics,1999(2):225-231. |
| [5] | Stenzel M H .Formation of regular honeycomb -patterned porous film by self-organization[J].Australian Journal of Chemistry,2002,55:239 -2243. |
| [6] | Stenzel M H;Davis T P;Fane A G et al.Porous polymer films and honeycomb structure made by the self-organization of well-defined macronaolecular structures created by living radical polymerization techniques[J].Angew Chem Ine Ed,2001,40(18):3428-3432. |
| [7] | Cheng CX;Tian Y;Shi YQ;Tang RP;Xi F .Porous polymer films and honeycomb structures based on amphiphilic dendronized block copolymers[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(14):6576-6581. |
| [8] | Cheng CX;Tian Y;Shi YQ;Tang RP;Xi F .Ordered honeycomb-structured films from dendronized PMA-b-PEO rod-coil block copolymers[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2005(15):1266-1272. |
| [9] | Wang LH;Tian Y;Ding HY;Li JD .Microstructure and properties of organosoluble polyimide/silica hybrid films[J].European Polymer Journal,2006(11):2921-2930. |
| [10] | Liaw D J;Liaw B Y;Yu C W .Synthesis and characterization of new organcsoluble polyimides based on flexible diamine[J].Polymer,2001,42:5175 -55179. |
| [11] | 王丽华,赵之平,李继定,陈翠仙.一种可溶性聚酰亚胺的合成及其渗透汽化脱有机硫化物性能测试[J].高分子学报,2006(03):496-499. |
| [12] | Yabu H.;Tanaka M.;Ijiro K.;Shimomura M. .Preparation of honeycomb-patterned polyimide films by self-organization[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(15):6297-6300. |
| [13] | 赵晓勇,蔡晴,石桂欣,施艳荞,陈观文.水蒸气辅助法制备LA-GA共聚物蜂窝状多孔膜[J].膜科学与技术,2004(02):1-6. |
| [14] | Tian Y;Jiao QZ;Ding HY;Shi YQ;Liu BQ .The formation of honeycomb structure in polyphenylene oxide films[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(11):3866-3873. |
| [15] | Wang LH;Tian Y;Ding HY;Liu BQ .Formation of ordered macroporous films from fluorinated polyimide by water droplets templating[J].European Polymer Journal,2007(3):862-869. |
| [16] | Nishikawa T.;Nonomura M.;Arai K.;Hayashi J.;Sawadaishi T.;Nishiura Y. Hara M.;Shimomura M. .Micropatterns based on deformation of a viscoelastic honeycomb mesh[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(15):6193-6201. |
| [17] | Li J;Peng J;Huang WH;Wu Y;Fu J;Cong Y;Xue LJ;Han YC .Ordered honeycomb-structured gold nanoparticle films with changeable pore morphology: From circle to ellipse[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(5):2017-2021. |
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