实验对厌氧膜生物反应器(AnMBR)处理活性黑KN-B印染废水进行了探讨.研究了厌氧反应器内活性污泥的驯化培养状况,考察了厌氧反应器与管式超滤膜对印染废水BOD5,COD的去除作用,并对厌氧反应器产气量、出水的碳酸氢盐碱度和VFA进行了分析,通过UV-Vis光谱图分析了AnMBR对活性黑KN-B的脱色效果.结果表明,液流较低的低负荷启动方式使该AnMBR活性污泥的驯化培养顺利进行,厌氧反应器污泥床区域的污泥浓度培养至35 g/L;AnMBR对废水BODs和COD的去除率分别达到90%和85%以上;该厌氧反应器的活性污泥体系和缓冲体系相对稳定,出水的碳酸氢盐碱度和VFA分别在16~18mmol/L与1.0~3.5 mmol/L的范围内波动,pH稳定在7.70~8.00之间;AnMBR对500mg/L的活性黑KN-B废水的脱色率能达到90%以上.
Experiments on the printing and dyeing wastewater containing reactive black 5 treated with anaerobic membrane bioreactor(AnMBR)were discussed.The cultivation and domestication of activated sludge were researched.The effect of anaerobic bioreactor and tubular ultrafiltration membrane on the removal of BOD5 and COD were studied.Gas production, bicarbonate alkalinity and volatile fatly acid(VFA)were analyzed.The decolorization effect of reactive black 5 was analyzed by UV-Vis spectrophotometer.In this study, the changes of MLSS, bicarbonate alkalinity and VFA, pH were in the regular range, along with the loading enhancement during the startup period of AnMBR.The removal rate of BOD5 and COD by AnMBR were above 90 % and 85 %, respectively.Decolorization of reactive black 5 wastewater increased progressively, and up to 90 % finally.The results has shown that low organic loading startup method for AnMBR startup is feasible.
参考文献
[1] | Grethlein H E .Anaerobic digestion and membrane separation of domestic wastewater[J].Journal of Water Pollution and Control Federation,1978,50:754-763. |
[2] | Strohwald N K H;Ross W R .Application of the ADUFR process to brewery effluent on a laboratory scale[J].Water Science and Technology,1992,25(10):95-105. |
[3] | Saddoud A;Hassairi I;Sayadi S .Anaerobic membrane reactor with phase separation for the treatment of cheese whey[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2007(11):2102-2108. |
[4] | Faisal Ibney Hai;Kazuo Yamamoto;Kensuke Fukushi .Performance of newly developed hollow fiber module with spacer in integrated anaerobic-aerobic fungi reactor treating textile wastewater[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2006(1/3):305-307. |
[5] | W. Fuchs;H. Binder;G. Mavrias;R. Braun .Anaerobic treatment of wastewater with high organic content using a stirred tank reactor coupled with a membrane filtration unit[J].Water research: A journal of the international water association,2003(4):902-908. |
[6] | Yiliang He;Pei Xu;Chunjie Li;Bo Zhang .High-concentration food wastewater treatment by an anaerobic membrane bioreactor[J].Water research: A journal of the international water association,2005(17):4110-4118. |
[7] | Harada H;Momoni K;Yamazaki S et al.Application of anaerobic-UF membrane reactor for treatment of a wastewater containing high strength particulate organics[J].Water Science and Technology,1994,30(12):307-319. |
[8] | Can H K;Kirci B;Kavlak S et al.Removal of some textile dyes from aqueous solutions by poly(N-vinyl-2-pyrrolidone)and poly(N-vinyl-2-pyrrolidone)/K2S2O8 hydrogels[J].Radiation Physics and Chemistry,2003,68(05):811-818. |
[9] | Ciardelli G.;Ranieri N. .The treatment and reuse of wastewater in the textile industry by means of ozonation and electroflocculation[J].Water research: A journal of the international water association,2001(2):567-572. |
[10] | Szpyrkowicz L.;Kaul SN.;Juzzolino C. .A comparative study on oxidation of disperse dyes by electrochemical process, ozone, hypochlorite and Fenton reagent[J].Water research: A journal of the international water association,2001(9):2129-2136. |
[11] | A.G. Vlyssides;D. Papaioannou;M. Loizidoy .Testing an electrochemical method for treatment of textile dye wastewater[J].Waste Management,2000(7):569-574. |
[12] | S.M. Ghoreishi;R. Haghighi .Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent[J].Chemical Engineering Journal,2003(1/3):163-169. |
[13] | Zissi U;Lyberatos G .Azo-dye biodegradation under anoxic conditions[J].Water Science and Technology,1996,34(5-6):495-500. |
[14] | Onur O.Sogut;Mesut Akgun .Treatment of textile wastewater by SCWO in a tube reactor[J].The Journal of Supercritical Fluids,2007(1):106-111. |
[15] | Dogruel S;Dulekgurgen E;Orhon D .Effect of ozonation on chemical oxygen demand fractionation and color profile of textile wastewaters[J].Journal of Chemical Technology & Biotechnology,2006(3):426-432. |
[16] | Erdal Kusvuran;Osman Gulnaz;Sibel Irmak;Osman M. Atanur;H. Ibrahim Yavuz;Oktay Erbatur .Comparison of several advanced oxidation processes for the decolorization of Reactive Red 120 azo dye in aqueous solution[J].Journal of hazardous materials,2004(1/3):85-93. |
[17] | Ulusoy Bali;Ebru Catalkaya;Fuesun Senguel .Photodegradation of Reactive Black 5, Direct Red 28 and Direct Yellow 12 using UV, UV/H_2O_2 and UV/H_2O_2/Fe~(2+): a comparative study[J].Journal of hazardous materials,2004(1/3):159-166. |
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