采用干-湿法纺丝技术制备了α-Al2O3中空纤维支撑体,系统研究了Al2O3/PESf(聚醚砜)原料比、焙烧温度、保温时间以及原料粒径等因素对支撑体结构性能的影响.优化的支撑体渗透性为4.09×10-5 mol/(m2·s·Pa),弯曲强度为142.7 MPa,最大孔径与平均孔径分别为0.66 μm和0.56μm在该支撑体上合成了NaA分子筛膜,其水/乙醇分离因子>5 000,通量达7.37 kg/(m2·h).
参考文献
| [1] | 徐南平;邢卫红;赵宜江.无机膜分离技术与应用[M].北京:化学工业出版社,2004:1-4. |
| [2] | Hsieh H P.General characteristics of inorganic membranes[A].New York:Elsevier Science Publishing Company,1991:65-93. |
| [3] | Mulder M.膜技术基本原理[M].北京:清华大学出版社,1999:302-303. |
| [4] | Xiaoyao Tan;Shaomin Liu;K. Li .Preparation and characterization of inorganic hollow fiber membranes[J].Journal of Membrane Science,2001(1):87-95. |
| [5] | J. Smid;C.G. Avci;V. Guenay;R.A. Terpstra;J.P.G.M. Van Eijk .Preparation and characterization of microporous ceramic hollow fibre membranes[J].Journal of Membrane Science,1996(1):85-90. |
| [6] | 李健生,郝艳霞,王连军,赵宝昌.反应结合制备增强氧化铝中空纤维膜[J].无机材料学报,2002(01):180-184. |
| [7] | Liu Shaomin;Li K;Hughes R .Preparation of porous a-luminium oxide (Al2 O3) hollow fiber membranes by a combined phase-inversion and sintering method[J].Ceramics International,2003,29(09):875-881. |
| [8] | Wei C C;Chen O Y;Liu Y et al.Ceramic asymmetric hollow fiber membranes-One step fabrication process[J].Journal of Membrane Science,2008,320(1-2):191-197. |
| [9] | Yin Weining;Meng Bo;Meng Xiuxia et al.Highly asymmetric yttria stabilized zirconia hollow fiber membranes[J].Journal of Alloys and Compounds,2009,476(1-2):566-570. |
| [10] | Schiestel T;Kilgus M;Peter S et al.Hollow fiber perovskite membranes for oxygen separation[J].Journal of Membrane Science,2005,258(1-2):1-4. |
| [11] | Alshebani A;Pera-Titus M;Landrivon E et al.Nanocomposite MFI-ceramic hollow fibers:prospects for CO2 separation[J].Microporous and Mesoporous Materials,2008,115(l-2):197-205. |
| [12] | Daramola M O;Burger A J;Pera-Titus M et al.Nanocomposite MFI-ceramic hollow fiber membranes via pore-plugging synthesis:Prospects for xylene iso-mer separation[J].Journal of Membrane Science,2009,337(1-2):106-112. |
| [13] | Xiaochun Xu;Weishen Yang;Jie Liu;Liwu Lin;Norbert Stroh;Herwig Brunner .Synthesis of NaA zeolite membrane on a ceramic hollow fiber[J].Journal of Membrane Science,2004(1/2):81-85. |
| [14] | Zhengbao Wang;Qinqin Ge;Jia Shao;Yushan Yant .High Performance Zeolite LTA Pervaporation Membranes on Ceramic HollowFibers by Dipcoating—Wiping Seed Deposition[J].Journal of the American Chemical Society,2009(20):6910-6911. |
| [15] | 张叶,刘艳梅,陆双佳,顾学红,邢卫红.NaA分子筛膜的制备及其在醇类脱水中的应用[J].南京工业大学学报（自然科学版）,2010(01):41-45. |
| [16] | Kondo M.;Kita H.;Okamoto K.;Komori M. .TUBULAR-TYPE PERVAPORATION MODULE WITH ZEOLITE NAA MEMBRANE[J].Journal of Membrane Science,1997(1):133-141. |
| [17] | Kiminori Sato;Takashi Nakane .A high reproducible fabrication method for industrial production of high flux NaA zeolite membrane[J].Journal of Membrane Science,2007(1/2):151-161. |
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