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在大气环境中,测试7YSZ热障涂层抗1 000 ℃高温氧化性能,以模拟发动机叶片的巡航飞行高温氧化过程.采用交流阻抗技术并结合扫描电镜及X射线衍射系统研究了高温氧化过程中TGO层生长与YSZ层微结构演变.结果表明:随着氧化时间的增加,TGO层厚度增加符合抛物线规律,在中频阶段的阻抗谱响应愈加显著.YSZ熔融颗粒在较低测试温度下表现为容抗特征,随测试温度升高逐步表现为感抗特征.阻抗谱分析显示YSZ晶粒的电阻及电容随氧化时间增加,均呈一定幅度波动变化,高温氧化对熔融颗粒本身的电学特征影响不明显;随着氧化时间的增加,YSZ晶界电阻值不断增加,电容值不断下降,表明YSZ内微裂纹发生了生长和扩展,最终导致YSZ层的剥落失效.

参考文献

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