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以不同氮离子辅助轰击能量制备CrN膜层,利用纳米压入仪及显微硬度计分别测试单晶Si片上膜层的硬度及断裂韧度K1C使用XRD、XPS及EPMA分析离子轰击能量对镀层组织结构的影响.结果表明,采用能量较低的氮离子轰击得到的涂层,由于金属Cr的存在,涂层硬度虽有所降低,但断裂韧度K1C数值较高.选择较低的4keV辅助轰击能量,在M2高速钢基体上沉积CrN涂层,膜层在空气介质中表现出优异的耐磨减摩特性.但在水介质条件下,由于膜层接触区域的去钝化/再钝化使腐蚀和磨损相互加速,导致CrN膜层摩擦系数,尤其是磨损量明显高于基材.

参考文献

[1] Kenji Sugiyama;Kasunori Hayashi;Jun Sasaki .Basic characteristics of chromium nitride films by dynamic ion beam mixing[J].Nuclear Instruments and Methods in Physics Research,1993,B80-B81:1376-1380.
[2] Berg S;Nyberg T;Blom H O;Nender C .Computer modeling as a tool to predict deposition rate and film composition in reactive sputtering process[J].Journal of Vacuum Science and Technology,1998,A16(03):1277-1285.
[3] Mehrotra P K;Quinto D T .Techniques for evaluating mechanical properties of hard coatings[J].Journal of Vacuum Science and Technology A,1985,A3(06):2401-2405.
[4] Lee Shen·Chin;Ho Wei-yu;Pao Wen-Lon .Process and properties of CrN coating deposited on plasma nitrided high-speed steel[J].Surface and Coatings Technology,1995,73:34-38.
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