传统的β基Ni-Al-Fe形状记忆合金随Fe含量提高而呈铁磁性,因此可以发展为铁磁性形状记忆合金.通过金相显微分析、DSC、VSM和EDX方法,研究了Co含量x对Ni54 Al25Fe21-xCox合金马氏体相变和磁性的影响.发现该合金马氏体相变温度与x成正比关系,x每增加1at%,1623K淬火时马氏体相变温度约提高30K,1373K淬火时马氏体相变温度约提高38K.淬火温度降低会显著降低Ni54Al2Fe21-xCox合金的马氏体相变温度和Curie点Tc,但随着x的提高,淬火温度对马氏体相变温度和Tc的影响程度减小.Tc随x变化的幅度不大,在Tc-x曲线上出现最大值,为256K,对应于1623K淬火的Ni54Al25Fe19Co2合金.马氏体相变温度的变化与β相的平均s+d总电子浓度变化有关,并首次提出Al含量和结构有序度两方面的变化共同影响Curie点.
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