采用热刺激电流(TSC)对自制的4种不同纳米Al2O3含量的聚酰亚胺(PI)薄膜进行测试,发现复合材料的热刺激电流峰值随着纳米Al2O3填充量的增加而降低,当纳米Al2O3的填充量大于10%后,热刺激电流峰的峰值随着温度升高持续一段时间后才出现下降趋势.对4种薄膜的TSC高温峰分别进行计算,得出薄膜中陷阱电荷的数量.并结合纳米复合材料的多核模型和陷阱理论,得出该现象的出现是由于PI/Al2O3纳米复合薄膜中界面结构影响了载流子输运过程造成的.
参考文献
[1] | Lewis T J .Interface are the Dominant Fature of Dielectrics at Nanometric Level[J].IEEE Transaction on Dielectrics and Electrical Iinaulation,2004,11(05):739-753. |
[2] | Nelson J K;Fothergill J C;Dissado L A.Towards an Understanding of Nanometric Dielectrics[A].,2002:295-298. |
[3] | Nelson J K;Hu Y.The Impact of Nanocomposite Formulations on Electrical Voltage Endurance[J].IEEE-ICSD,2004:832-835. |
[4] | Toshikatsu Tanaka .Dielectric Nanocomposites with Insulating Properties[J].IEEE transactions on dielectrics and electrical insulation: A publication of the IEEE Dielectrics and Electrical Insulation Society,2005(5):914-928. |
[5] | Meloni .High Temperature Polymeric Materials Containing Corona Resistant Composite Filler,and Methods Thereto[P].US,7015260B2,2004-12-09. |
[6] | Yin W;Barta D .Pulsed Voltage Surge Resistant Magnet Wire[P].US,6180888,2001-01-30. |
[7] | 储焱,张明艳,王坤,衷敬和,雷清泉.耐电晕纳米杂化聚酰亚胺的合成及表征[J].哈尔滨理工大学学报,2002(06):118-120,123. |
[8] | Bhardwaj R;Quamara J;Nagpaul K et al.Field-induced Thermally Stimulated Currents in Kapton-H Polyimide Films[J].Physics Status Solidi A:Applied Research,1983,80(02):559-566. |
[9] | Toshikatsu Tanaka;Masahiro Kozako;Norikazu Fuse;Yoshimichi Ohki .Proposal of a Multi-core Model for Polymer Nanocomposite Dielectrics[J].IEEE transactions on dielectrics and electrical insulation: A publication of the IEEE Dielectrics and Electrical Insulation Society,2005(4):669-681. |
[10] | 屠德民;王新生 .聚烯烃化合物电老化中的电子动力学机理[J].西安交通大学学报,1993,27(02):33-40. |
[11] | 王新生;屠德民 .用陷阱参数作为电老化特性参数的试验研究[J].西安交通大学学报,1993,27(13):1-6. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%