通过以 L-天冬氨酸为原料的热缩催化聚合、以马来酸酐和碳酸铵为原料的常规合成和微波幅照合成等不同方法制备了聚天冬氨酸.分别通过红外光谱技术和粘度法对产物进行了结构和分子量的表征,并研究了每种制备方法对产物的产率、分子量及其阻垢性能的影响.结果表明所有聚合产物均具有聚天冬氨酸的结构特征.虽然由L-天冬氨酸法制备的产物产率和分子量最高,但是由微波辐照合成所得产物的阻垢性能最佳.
参考文献
[1] | Ross R J;Low K C;Shannon J E .Polyaspartate scale inhibition biodegradable alternatives to polyacrylates[J].Materials Performance,1997,36(04):53-57. |
[2] | Koweton S;Huang S J;Swift G .Poly(aspartic acid):synthesis,biodegradation and current applications[J].Journal of Environmental Polymer Degradation,1997,5(03):175-181. |
[3] | Low K C;Koskan L P .Synthetic polyaspartic acid and its uses[J].Polymeric Materials Science and Engineering,1993,69:253-254. |
[4] | Takao Aoyagi;Ken-ichi Sugi;Yasuhisa Sakura .Peptide drug carrier:studies on incorporation of vasopressin into nano-associates comprising poly(ethylene glycol)-poly(L-aspartic acid) block copolymer[J].Colloids and Surfaces,1999,16:237-242. |
[5] | Kazunori Kataokaa;Atsushi Harada;Yukio Nagasaki .Block copolymer micelles for drug delivery:design,characterization and biological significance[J].Advanced Drug Delivery Reviews,2001,47:113-131. |
[6] | 熊蓉春,董雪玲,魏刚.绿色生物高分子聚天冬氨酸的合成及其阻垢性能研究[J].工业水处理,2001(01):17-20. |
[7] | Grigory YM;Jacob M .Production of D,L-aspartic acid[P].US 5907057,1999. |
[8] | 杨士林,黄君礼,陶虎春,张玉玲.马来酸酐合成聚天冬氨酸及其分子质量对阻垢性能的影响[J].现代化工,2003(12):26-29. |
[9] | 陶敬奇,李景宁,王广洪,曾广益.热缩催化聚合合成聚天冬氨酸[J].华南师范大学学报(自然科学版),2004(02):134-136. |
[10] | 徐耀军,杨文忠,唐永明,俞斌.聚天冬氨酸的阻垢缓蚀性能[J].南京工业大学学报(自然科学版),2002(01):87-89. |
[11] | Ian Ralph Collins .Surface Electrical Properties of Barium Sulfate Modified by Adsorption of Poly α,βAspartic Acid[J].Journal of Colloid and Interface Science,1999,212:535-544. |
[12] | 杨士林,黄君礼,张玉玲,陶虎春.聚天冬氨酸的合成及其粘均分子量对阻垢性能的影响[J].化工科技,2003(05):24-28. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%