合成了金刚烷胺改性丙烯酸-N-乙烯基吡咯烷酮(AMA-m-P(AA-co-NVP))共聚物水凝胶,通过改变原料配比可有效调控水凝胶的溶胀率.金刚烷胺(AMA)的比例越大,反应中和效率越低.随着反应物中AMA/AA和NVP/AA比例的升高,共聚物水凝胶的溶胀率逐渐增大.产物AMA-m-P(AA-co-NVP)聚合物水凝胶最大吸水率为312g/g.
参考文献
| [1] | 伊长青,欧阳思婕,程发,魏玉萍.PVP（K-30）的合成工艺[J].化学工业与工程,2008(06):527-529. |
| [2] | 徐建,张睿,何江川.P（NIPA-co-NVP）温敏性凝胶微粒的药物释放与降解[J].化学研究与应用,2010(08):1015-1020. |
| [3] | 张玉平,叶彦春,郭燕文,张军良.P（AM-DAAM-NVP）三元共聚物的耐温抗盐性能研究[J].精细化工,2006(05):494-496. |
| [4] | Hatta M;Neumann G;Kawaoka Y .Reverse genetics approach towards understanding pathogenesis of H5N1 Hong Kong influenza A virus infection[J].Philosophical Transactions Of the Royal Society of London Series B Biological Sciences,2001,356(1416):1841-1853. |
| [5] | Contreras .Protein glycosylation modification in Pichia pastoris[P].US:6803225,2004-10-12. |
| [6] | Fatima R;Joa B;Miguel C .Kinetic sofwater absorbency in AA/AMPS copolymers[J].Polymer,2002,43:63-70. |
| [7] | Nowatzki PJ;Tirrell DA .Physical properties of artificial extracellular matrix protein films prepared by isocyanate crosslinking.[J].Biomaterials,2004(7/8):1261-1267. |
| [8] | Zulfiqar S.;Masud K. .Thermal degradation of blends of allyl methacrylate-methyl methacrylate copolymers with aluminum isopropoxide[J].Polymer Degradation and Stability,2002(2):305-313. |
| [9] | Lili Qie;Marc A. Dub .Manipulation of chain transfer agent and cross-linker concentration to modify latex micro-structure for pressure-sensitive adhesives[J].European Polymer Journal,2010(6):1225-1236. |
| [10] | Kennedy, JE;Devine, DM;Lyons, JG;Geever, LM;Higginbotham, CL .The synthesis and characterisation of grafted random styrene butadiene for biomedical applications[J].Journal of Materials Science,2009(3):889-896. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%