采用干湿周浸实验模拟海洋大气环境研究含Cu耐候桥梁钢腐蚀过程中耐腐蚀性能的变化,并利用XRD,SEM等方法研究了两种不同Cu含量耐候桥梁钢的锈层变化.结果表明:Cu能够有效地降低钢的平均腐蚀深度和腐蚀速率,利于提高钢的耐蚀性能.锈层组成随腐蚀时间而变化,腐蚀初期锈层主要由Fe3O4和γ-FeOOH组成,腐蚀中期锈层开始生成Ni(0.6-1)Fe(2.4-2) O4尖晶石类复合氧化物和α- FeOOH两种晶相;腐蚀后期组成基本保持不变,主要由Ni(0.6-1) Fe(2.4-2) O4、α- FeOOH、γ- FeOOH和少量We3 O4组成.
参考文献
[1] | Akira U;Hiroshi K;Takashi K .3%-Ni weathering steel plate for uncoated bridges at high airborne salt environment[J].NIPPON STEEL TECHNICAL REPORT,2003,87:21-23. |
[2] | Minoru ITOU;Akira USAMI .Performances of Coastal Weathering Steel[J].NIPPON STEEL TECHNICAL REPORT,2000(81):79-84. |
[3] | 刘丽宏,齐慧滨,卢燕平,李晓刚.耐大气腐蚀钢的研究概况[J].腐蚀科学与防护技术,2003(02):86-89. |
[4] | Zhang QC.;Wu JS.;Wang JJ.;Zheng WL.;Chen JG.;Li AB. .Corrosion behavior of weathering steel in marine atmosphere[J].Materials Chemistry and Physics,2003(2):603-608. |
[5] | 张全成,吴建生,郑文龙,王建军,陈家光,李爱柏,杨晓芳.合金元素的二次分配对耐钢抗大气腐蚀性能的影响[J].材料保护,2001(04):4-5. |
[6] | 肖葵,董超芳,李晓刚,王福明.大气腐蚀下耐候钢的初期行为规律[J].钢铁研究学报,2008(10):53-58. |
[7] | Durmwald J;Otto A .An investigation of phase transitions in rust layers using Raman spectroscopy[J].Corrosion Science,1989,29(11):1167-1172. |
[8] | 张淑泉 .关于"自然环境腐蚀”的国际研究动向[J].腐蚀与防护,1997,18(05):18-19,33. |
[9] | Misawa T;Asami K;Hashimoto K et al.The mechanism of atmospheric rusting and the protective amorphous rust on low alloy steel[J].Corrosion Science,1974,14(02):279-292. |
[10] | 于福洲.金属材料的耐蚀性[M].北京:科学出版社,1989:102-104. |
[11] | 王笑天.金属材料学[M].北京:机械工业出版社,1987:63-64. |
[12] | Nishimura T;Kodama T .Clarification of chemical state for alloying elements in iron rust using a binary-phase potential-pH diagram and physical analyses[J].Corrosion Science,2003,45(03):1073-1084. |
[13] | Kimura M;Kihira H;Hashimoto M et al.Control of Fe(O,OH) 6 nano-network structures of rust for high atmosphericcorrosion resistance[J].Corrosion Science,2005,47(07):2499-2059. |
[14] | Nishimura T;Katayama H;Noda K et al.Effect of Co and Ni on the corrosion behavior of alloy steels in wet/dry environments[J].Corrosion Science,2000,42(03):1611-1621. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%