刚性粒子增韧技术是制备兼具高刚性和高韧性的聚合物复合体系的有效手段,不仅具有重要的理论研究价值,而且具有广阔的应用前景和商业价值.本文综述了近20年来有关刚性粒子增韧聚合物复合体系的研究概况,并着重讨论了刚性无机粒子增韧结晶性聚合物的增韧机理.大量研究表明,刚性粒子增韧聚合物的实现来源于两方面的贡献,其一是刚性粒子的引入所导致的局部应力状态的改变.通过脱粘、空化、三维应力约束的解除,为基体的剪切屈服提供应力条件.其二是刚性粒子对基体的结晶行为产生影响,使晶粒尺寸变小,完善程度降低,甚至在界面附近形成择优取向的滑移阻力较小的结晶层,从而促进基体发生屈服变形.基于大量的研究结果,作者指出最佳的增韧效果是适当的界面粘结强度,足够高的填料含量,基体较低的结晶度和屈服应力等因素所决定的.由此作者提出了刚性无机粒子增韧聚合物体系的界面设计方案.
参考文献
| [1] | 曾汉民.高技术新材料要览[M].北京:中国科学技术出版社,1993 |
| [2] | BucknellC B.Toughened Plastics[M].Applied Science Pu blishers Ltd London,1977 |
| [3] | KurauchiT;OhtaT .[J].Journal of Materials Science,1984,19:1699. |
| [4] | KooK-K;InoueTand MiyasakaK .[J].Polymer Engineering and Science,1985,25:741. |
| [5] | Liu;T M Xie;H Q O'Callaghan;K J Rudin A Baker,W E .[J].Journal of Polymer Science Part B:Polymer Physics,1993,31:134. |
| [6] | IkuroY .[J].Polymer,1995,36:17. |
| [7] | TjongS C;XuS A .[J].Plastics Rubber and Composites Processing and Applications,1997,26:184. |
| [8] | NezbedovaE .Ponesicky[J].Acta Polymerica,1990,41:36. |
| [9] | 傅强,沈九四,王贵恒.碳酸钙刚性粒子增韧HDPE的影响因素[J].高分子材料科学与工程,1992(01):107-112. |
| [10] | FuQ;WangG .[J].Journal of Applied Polymer Science,1993,49:1985. |
| [11] | 朱晓光;邓小华;洪萱;漆宗能 蔡忠龙.[J].高分子学报,1996(02):195. |
| [12] | WangK;WuJ S;KimJ.K.in "Fracture Mechanics and Adva nced Engineering Materials”[M].The University of Sydney Australia,1999:380. |
| [13] | 曾汉民.树脂基复合材料界面工程[A].北京:清华大学出版社,1990 |
| [14] | 曾汉民 .[J].科学通报,1977,22(12):513. |
| [15] | WuJ S;MaiY -W .[J].Journal of Materials Science,1993,28:6167. |
| [16] | WuJ S;MaiY -W;YeeA F .[J].Journal of Materials Science,1993,28:3373. |
| [17] | WuJ S;YeeA F .[J].Mai Y-W J Mater Sci,1994,29:4510. |
| [18] | SueH J;YeeA F .[J].Journal of Materials Science,1989,24:1447. |
| [19] | SueH .PhD thesis[D].University of Michigan Ann Arbor MI,USA,1988. |
| [20] | ZhangM Q;ZengH M;MaiK C;He Y T.[J].Advances in Composites Letters,1993(03):107. |
| [21] | Zhang MQ.;He YT.;Mai KC.;Zeng HM. .EFFECT OF A POLYARYLETHERKETONE-BEARING BULKY SUBSTITUENT ON THE NON-ISOTHERMAL CRYSTALLIZATION KINETICS OF POLYPHENYLENE SULFIDE[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,1995(0):183-188. |
| [22] | DekkersM.E.J;HobbsS Y;WatkinsV.H .[J].POLYMER,1991,32:2150. |
| [23] | HobbsS Y;DekkersM E J;WatkinsV H .[J].Journal of Materials Science,1988,23:1219. |
| [24] | DekkersM E J;HobbsS Y;WatkinsV H .[J].Journal of Materials Science,1988,23:1225. |
| [25] | BucknallC.B.in "Failure in Polymers:Molecular & Phenomenoligical aspects”[C].Springer-Verlag,1978 |
| [26] | KinlochA.J;YoungR J.Fracture Bechavior of Polymers[C].Elsevier Applied Science London and New York,1983:128. |
| [27] | 王珂;曾戎;曾汉民.[A].:1019. |
| [28] | 王珂 .聚丙烯/硫酸钡复合体系界面设计与增强增韧[D].中山大学,2001. |
| [29] | WangK;WuJ S;ZengH.M.[J].Journal of Polymer Science Part B:Polymer Physics |
| [30] | WangK;WuJ S;ZengH.M.[J].Journal of Polymer Science Part B:Polymer Physics |
| [31] | Wang,K;Wu,J.S;Zeng,H.M.[M]. |
| [32] | Wu Souheng .[J].Polymer,1985,26:1885. |
| [33] | MargolinaA;Wu S .[J].Polymer,1988,29:2170. |
| [34] | Fu Q.;Liu CX.;Wang GH. .POLYETHYLENE TOUGHENED BY CACO3 PARTICLES - THE INTERFACE BEHAVIOUR AND FRACTURE MECHANISM IN HIGH DENSITY POLYETHYLENE/CACO3 BLENDS[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(12):2397-2401. |
| [35] | LiD;ZhengW;QiZ.[J].Journal of Materials Science,1994:3754. |
| [36] | HancockM.Particulate-filled polymer composites[M].Particulate-filled polymer composites" Rotho n R,Ed,Longman group limited,1995 |
| [37] | JancerJ;DibenedettoA Tand DianselmoA .[J].Polymer Engineering and Science,1993,33:559. |
| [38] | BazhenovS .[J].Polymer Engineering and Science,1995,35:813. |
| [39] | FriedrichK;KarschU A.[J].Journal of Materials Science,1981:2167. |
| [40] | DenaultJ;Vu-KhanhT .[J].Polymer Composites,1988,9:360. |
| [41] | Hornsby PR.;Watson CL. .INTERFACIAL MODIFICATION OF POLYPROPYLENE COMPOSITES FILLED WITH MAGNESIUM HYDROXIDE[J].Journal of Materials Science,1995(21):5347-5355. |
| [42] | WuJ S;YuD M;MaiY W;Yee A F .[J].Journal of Materials Science,2000,35:1. |
| [43] | VargaJ.in "Polypropylene:Structure Blends and Composites”[M].Chapman and Hall,1995(03):56. |
| [44] | Velasco JI.;Martinez AB.;Desaja JA. .CRYSTALLIZATION BEHAVIOR OF POLYPROPYLENE FILLED WITH SURFACE-MODIFIED TALC[J].Journal of Applied Polymer Science,1996(1):125-132. |
| [45] | KowalewskiT;GaleskiA J .[J].Journal of Applied Polymer Science,1986,32:2929. |
| [46] | van der Wal A.;Gaymans RJ.;Mulder JJ. .Fracture of polypropylene: 2. The effect of crystallinity[J].Polymer: The International Journal for the Science and Technology of Polymers,1998(22):5477-5481. |
| [47] | van der Wal;AMulderJ J;OderkerkJ .[J].Gaymans R J Polymer,1998,39:6781. |
| [48] | GaymansR J.in "Polymer Blends” Vol.2,Performance.Paul,D.R,Buck nell,C.B[M].Editors John Wiley & Sons New York,2000:177. |
| [49] | BiceranoJ.Prediction of Polymer Properties[M].Marcel Dekker Inc New York,1993.Chapter 11,,Mechanical Properties,234,1993 |
| [50] | KisselW J;HanJ H;MeyerJ.A.in "Hand Book of Polypropylene a nd Polypropylene Composites”[M].Karian H.G Editor;Marcel Dekker;Inc;New Yo rk,1999:15. |
| [51] | Perkins WG .Polymer toughness and impact resistance[J].Polymer engineering and science,1999(12):2445-2460. |
| [52] | Lustiger A.;Mueller RR.;Marzinsky CN. .Spherulite boundary strengthening concept for toughening polypropylene[J].Journal of Polymer Science, Part B. Polymer Physics,1998(12):2047-2056. |
| [53] | FriedrichK .[J].Progress in Colloid and Polymer Science,1978,64:103. |
| [54] | Varga J .[J].Journal of Materials Science,1992,27:2557. |
| [55] | WayJ L;AtkinsonJ R .[J].Materials Science,1971,6:102. |
| [56] | Way J L;Atkinson J R;Nutting J .[J].Mate Sci,1974,9:293. |
| [57] | ReinshagenJ H;Dunlap R W .[J].Journal of Applied Polymer Science,1976,20:9. |
| [58] | BartczakZ;ArgonA S;CohenR E;WeinbergM .[J].Polymer,1999,40:2331. |
| [59] | BartczakZ;ArgonA S;CohenR E;WeinbergM .[J].Polymer,1999,40:2347. |
| [60] | BartczakZ;ArgonA S;CohenR E;KowalewskiT .[J].Polymer,1999,40:2367. |
| [61] | LinL;ArgonA S .[J].Journal of Materials Science,1994,29:294-323. |
| [62] | Aboulfaraj M.;Ulrich B.;Dahoun A.;Gsell C. .IN SITU OBSERVATION OF THE PLASTIC DEFORMATION OF POLYPROPYLENE SPHERULITES UNDER UNIAXIAL TENSION AND SIMPLE SHEAR IN THE SCANNING ELECTRON MICROSCOPE[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(4):731-742. |
| [63] | BartczakZ;GaleskiA .[J].Polymer,1999,40:3677-3684. |
| [64] | MuratogluO K;ArgonA S;CohenR E;Weinberg M .[J].Polymer,1995,36:4771. |
| [65] | ShinozakiD;GrovesG W.[J].Journal of Materials Science,1973(08):71. |
| [66] | SadowskiM M;NorthT H;WeatherlyG C .[J].Journal of Materials Science Letters,1991(10):1007. |
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