CVD一步法制备纳米碳管的研究

材料科学与工程学报, 2003, 21(2): 242-245. doi: 10.3969/j.issn.1673-2812.2003.02.023

CVD一步法制备纳米碳管的研究

应永飞 ^1, , 严新焕 ^2, , 王文静 ^3, , 徐振元 ^4,

1.浙江工业大学催化加氢研究中心,浙江,杭州,310014

2.浙江工业大学催化加氢研究中心,浙江,杭州,310014

3.浙江工业大学催化加氢研究中心,浙江,杭州,310014

4.浙江工业大学催化加氢研究中心,浙江,杭州,310014

基金项目: 浙江省自然科学基金 (200021)

关键词：纳米碳管 , 化学气相沉积法 , 一步法

One Step Synthesis for Carbon Nanotubes Using CVD Method

CVD法是制备纳米碳管的重要方法.本文研究了以乙炔为原料气,无需预先还原催化剂,以一定的程序速率从500℃升至750℃一步法生长纳米碳管,直接制备出了管径在8～12nm之间,石墨化程度好的纳米碳管.同时,对升温速率、原料气配比等因素进行了讨论,确定了CVD一步法制备纳米碳管较佳条件范围.

参考文献

[1]	Iijima S .Helical Microtubules of Griphitic Carbon[J].Nature,1991,354:56-58.
[2]	Calvert P .Strength in disunity[J].Nature,1992,357:365-366.
[3]	Pennisi E .Simple recipe yields fullerene tubules[J].Science News,1992,142:36.
[4]	Liu C;Fan Y Y;Liu M etc.Hydrogen storage in singlewalled carbon nanotubes at room temperature[J].Science,1999,286:1127-1129.
[5]	Ebbesen T W;Ajayan P M .Large-scale synthesis of carbon nanotubes[J].Nature,1992,358:220-222.
[6]	Fonseca A.;Piedigrosso P.;Colomer JF.;Mukhopadhyay K. Doome R.;Lazarescu S.;Biro LP.;Lambin P.;Thiry PA.;Bernaerts D.;Nagy JB.;Hernadi K. .Synthesis of single- and multi-wall carbon nanotubes over supported catalysts[J].Applied physics, A. Materials science & processing,1998(1):11-22.
[7]	Hernadi K.;Nagy JB.;Bernaerts D.;Lucas AA.;Fonseca A. .FE-CATALYZED CARBON NANOTUBE FORMATION[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(10):1249-1257.
[8]	吕德义,徐铸德,徐丽萍,葛忠华.催化剂载体对CVD法制备碳纳米管的影响[J].无机化学学报,2002(05):475-480.
[9]	李亚利;于瀛大;梁勇 .纳米碳管制备新技术-固相热解法[J].科学通报,1997,42(16):1787-1789.
[10]	Bethume D S;Kiang C H;de Vires etc.Cobalt-catalyzed growth of carbon nanotubes with single-atomic layer walls[J].Nature,1993,363:605.
[11]	Ivanov V;Nagy J B;Lambin P etc.The study of carbon nanotubes produced by catalytic method[J].Chemical Physics Letters,1994,223:329-335.
[12]	melinckx S;Zhang X B;Bermaerts D etc.A formation mechanism for catalytic grown helix shaped graphite nanotubes[J].SCIENCE,1994,256:635-639.
[13]	董树荣,涂江平,王春生.催化热分解法制备纳米碳管的研究[J].炭素,1998(03):28-33.
[14]	Ting G;Pavel Nikolaev;Andrew G etc.Self-assembly of tubular fullerene[J].Journal of Physical Chemistry,1995,99:10694-10697.
[15]	Tibberts G G .Why are carbon filaments tubular?[J].Journal of Crystal Growth,1984,66:632-638.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

CVD一步法制备纳米碳管的研究

One Step Synthesis for Carbon Nanotubes Using CVD Method

参考文献