本文通过电化学沉积方法制备了一种四氯苯醌/三苯磷可控掺杂四取代酞菁铜薄膜材料体系,研究了该可控掺杂有机薄膜材料的导电性能.研究结果表明,四取代酞菁铜可控掺杂薄膜材料的电导率,随着温度的升高或掺杂剂浓度的增加而显著增加,其原因是酞菁铜给体与四氯苯醌和三苯基磷等小分子电子受体之间发生了较强的氧化还原作用.
参考文献
| [1] | G- Winter;H Heckmann;P Haisch et al.Study of substituent effects on the photoconductivity of soluble 2, (3) and 1, (4)-substituted phthalocyaninato- and naphthalocyaninato- itanium( Ⅳ )oxides[J].Journal of the American Chemical Society,1998,120:11663. |
| [2] | R Rella;A Serra;P Siciliano et al.Langmuir-Blodgett Multilayers Based on Copper Phthalocyanine as Gas Sensor Materials:Active Layer-Gas Interaction Model and Conductivity Modulation[J].Langmuir,1997,13:6562. |
| [3] | Z L Yang;H Z Chen;L Cao et al.Synthesis and photoconductivity study of carbon nanotube bonded by tetrasubstituted amino manganese phthalocyanine[J].Materials Science and Engineering B,2004,106:73. |
| [4] | A Yamashita;S Matsumoto;S Sakata et al.Formation and ThirdOrder Nonlinear Optical Properties of Triclinic Metallophthalocyanine Films[J].Journal of Physical Chemistry B,1998,102:5165. |
| [5] | M F Lawrence;J P Dodelet;L H Dao .Electrodeposited cadmium sulfide/SAIPc heterojunction cell: origin of the p-type semiconducting character of the surfactant aluminum phthalocyanine[J].Journal of Physical Chemistry,1985,89:1395. |
| [6] | Y Amao;TKomori .Dye-Sensitized Solar Cell Using a TiO2 Nanocrystalline Film Electrode Modified by an Aluminum Phthalocyanine and Myristic Acid Coadsorption Layer[J].Langmuir,2003,19:8872. |
| [7] | M Pfeiffer;A Beyer;B Plonnigs et al.Controlled Doping of Organic Dyes:Basic Mechanisms and Implications for their Use in Organic Photovoltaic Cells[J].Sol Eng Mater and Sol Cells,2000,63:83. |
| [8] | J Blochwitz;T Fritz;M Pfeiffer et al.Interface electronic structure of organic semiconductors with controlled doping levels[J].Organic Electronics,2001,2:97. |
| [9] | Tashiro K.;Kawai T.;Yoshino K.;Kobayashi M. .CRYSTAL STRUCTURAL CHANGE IN POLY(3-ALKYL THIOPHENE)S INDUCED BY IODINE DOPING AS STUDIED BY AN ORGANIZED COMBINATION OF X-RAY DIFFRACTION, INFRARED/RAMAN SPECTROSCOPY AND COMPUTER SIMULATION TECHNIQUES[J].Polymer: The International Journal for the Science and Technology of Polymers,1997(12):2867-2879. |
| [10] | J. Blochwitz;M. Pfeiffer;T. Fritz .Low voltage organic light emitting diodes featuring doped phthalocyanine as hole transport material[J].Applied physics letters,1998(1/6):729-731. |
| [11] | 杨正龙,陈红征,汪茫.共升华可控掺杂有机半导体薄膜材料的研究进展[J].功能材料,2004(03):275-278. |
| [12] | C L Huisman;A Goossens;J Schoonman .Photodoping of Zinc Phthalocyanine:Formation,Mobility,and Influence of Oxygen Radicals in Phthalocyanine-Based Solar Cells[J].Journal of Physical Chemistry B,2002,106:10578. |
| [13] | J Murr;C Ziegler .Interaction of Na with sexithiophene thin films[J].Physical Review B,1998,57:7299. |
| [14] | B L Wheeler;G Nagasubramanian;A J Bard et al.A silicon phthalocyanine and a silicon naphthalocyanine:synthesis,electrochemistry,and electrogenerated chemiluminescence[J].Journal of the American Chemical Society,1984,106:7404. |
| [15] | H Shirai;K Hanabusa;M Kitamura et al.Functional metal porphyrasine derivatives and their polymers,14:Synthesis and properties of [ bis- or tetrakis (decyloxycarbonyl) phthalocyaninato]metal complexes[J].Makromolekulare Chemie,1984,185:2537. |
| [16] | Jingsong Huang;Jan Blochwitz-Nimoth;Martin Pfeiffer;Karl Leo .Influence of the thickness and doping of the emission layer on the performance of organic light-emitting diodes with PiN structure[J].Journal of Applied Physics,2003(2):838-844. |
| [17] | K Yamashita;Y Harima;T Matsubayashi .Conductance control of porphyrin solids by molecular design and doping[J].Journal of Physical Chemistry,1989,93:5311. |
| [18] | J. Drechsel;M. Pfeiffer;X. Zhou .Organic Mip-diodes by p-doping of amorphous wide-gap semiconductors: CV and impedance spectroscopy[J].Synthetic Metals,2002(1/3):201-205. |
| [19] | 甘昌胜,闫天堂,彭必先.酞菁染料的金属化和溴化与光物理影响的研究[J].化学物理学报,2003(04):293-298. |
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