采用TiOSO4为前驱体,制备出比较稳定的纯水性透明TiO2溶胶,该溶胶为中性.利用该TiO2溶胶作为光催化剂对水中微量1,1,2,2-四氯乙烷进行紫外光催化处理.研究发现,1,1,2,2-四氯乙烷在光催化下分解并使溶液的电导率增加,表明在光催化分解下,不断生成氯离子和氢离子,不同的1,1,2,2-四氯乙烷的初始浓度和催化剂的用量等因素对光催化的脱氯的量都有一定的关联.在此实验条件下,固定光照时间,二氧化钛溶胶的浓度在5至10ppm时,光催化的效率达到最大,电导率的变化最大.
参考文献
[1] | Sidebottom H.;Franklin J. .THE ATMOSPHERIC FATE AND IMPACT OF HYDROCHLOROFLUOROCARBONS AND CHLORINATED SOLVENTS[J].Pure and Applied Chemistry,1996(9):1757-1769. |
[2] | 陈翔;许嘉琳 .几种氯代烃的光催化降解试验研究[J].北京师范大学学报(自然科学版),1997,33(02):270-274. |
[3] | A Fujishima;K Honda .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238:37-38. |
[4] | 梁喜珍,黄国林,陈中胜,覃业贤,郑建英.光催化氧化法处理难降解废水的研究进展[J].华东地质学院学报,2003(02):179-182. |
[5] | Goswami D Y .Engineering of solar photocatalytic detoxification and processes[J].Advances in Solar Energy,1995,10:165. |
[6] | 金相灿.有机化合物污染化学[M].北京:清华大学出版社,1990:22-24. |
[7] | 罗仲宽,李明,蔡弘华,刘剑洪.二氧化钛溶胶光催化二氯甲烷溶液的电导率特性研究[J].材料科学与工程学报,2004(04):523-526. |
[8] | Y-M Gao et al.Preparation and photocatalytic properties of titanium(Ⅳ) oxide films[J].Materials Research Bulletin,1992,27(09):1023-1030. |
[9] | Wonyong Choi et al.Kinetics and Mechanism of CCl4 Photoreductive Degradation on TiO2: The Role of Trichloromethyl Radical and Dichlorocarbene[J].Journal of Physical Chemistry,1996,100:2161-2169. |
[10] | 邱健斌,曹亚安,马颖,管自生,姚建年.担载材料对TiO2薄膜光催化活性的影响[J].物理化学学报,2000(01):1-4. |
[11] | Istvan Ilisz et al.Photocatalytic water treatment with different TiO2 nanoparticles and Hydrophilic/hydrophobic layer silicate adsorbents[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2004,230:89-97. |
[12] | S Kataoka.Microwave-assisted heterogeneous photocatalytic oxidation[A].Orlando, FL.American Ceramic Society,2000 |
[13] | CatherineB;Almquist Pratim Biswas .The Photo-oxidation of cyclohexane on titanium dioxide: an investigation of competitive adsorption and is effects on product formation and selectivity[J].Applied Catalysis A:General,2001,214:259-271. |
[14] | T Tsuru et al.A photocatalytic membrane reactor for gas-phase reactions using porous titanium oxide membranes[J].Catalysis Today,2003,82:41-48. |
[15] | 罗仲宽,宋力昕,李明,刘剑洪,蔡弘华.TiOSO4水性溶胶制备TiO2薄膜及其亲水性研究[J].无机材料学报,2004(06):1397-1401. |
[16] | Zhongkuan Luo;Honghua Cai;Jianhong Liu;Weiliang Hong;Shaojin Tang .Preparation of TiO_2 Coating on the Glass and Hydrophilicity under Sunlight Irradiation[J].Key engineering materials,2005(1):827-830. |
[17] | M R Hoffman;S T Martin;W Choi;D W Bahnemann .[J].Chemical Reviews,1995,95:69. |
[18] | A L Linsebigler;G Lu;J T Yates Tr .[J].Chemical Reviews,1995,95:735. |
[19] | C S Turchi;D F Ollis .[J].Journal of Catalysis,1990,122:178. |
[20] | 李太友,刘琼玉,赵俐敏,赵琼.氯仿在TiO2悬浮液中的光催化降解[J].江汉大学学报(社会科学版),2001(03):21-25. |
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