用Triton X-100/正己醇/环己烷/水四元反相微乳液体系制备了纳米羟基磷灰石(HA)粉体,确定了影响制备过程的最佳pH值和煅烧温度等工艺条件.x-射线衍射仪、TEM、SEM对羟基磷灰石的颗粒进行表征和分析表明:颗粒分散均匀,呈杆状,a轴尺寸为20~40nm左右,c轴尺寸为60~80nm,此方法可以有效地控制和改变HAP的分散性和粒度大小.
参考文献
[1] | 沈兴海;高宏成.纳米微粒的微乳液制备法[J].化学通报(印刷版),1995(11):6-9. |
[2] | 韩颖超,王欣宇,李世普.纳米级磷灰石粉末制备工艺进展[J].硅酸盐通报,2002(03):27-29. |
[3] | Lim G K;Wang J;Ng S C.Nanosized hydroxyapatite powders from microemulsion and emulsions stabilized by a biodegradable surfactant[J].Journal of Materials Chemistry,1999(09):1635-1639. |
[4] | 王笃金;吴瑾光.反胶团或微乳液法制备超细颗粒的研究进展[J].化学通报(印刷版),1995(09):1-5. |
[5] | Fang X L;Yang C F .An experimental study on the relationship between the physical properties of CTAB/hexano/water reverse micelles and ZrO2-Y2O3 nanoparticals prepared[J].Journal of Colloid and Interface Science,1999,212:242-251. |
[6] | Corma A .From microporous to Mesoporous molecular sieve materials and their use in catalysis[J].Chemical Reviews,1997,97:2373-2419. |
[7] | Liu Changsheng;Huang Yue;Shen Wei .Kinetics of hydroxyapatite precipitation at pH=10-11[J].Biomaterials,2001,22:301-306. |
[8] | 周公度;段连云.结构化学基础[M].北京:北京大学出版社,2001 |
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