用稻壳灰为硅源,用十六烷基三甲基溴化铵作为模板剂,在酸性或碱性条件下均成功地合成了有序介孔SiO2材料MCM-41.利用XRD、N2吸附曲线、SEM、TEM等测试方法分别对稻壳灰及介孔SiO2样品进行了表征.结果表明,稻壳灰为非晶体,呈粒状的多孔结构,其比表面积为250m2/g;在酸性条件下合成的MCM-41具有周期性规则排列的介孔结构,最可几孔径为2.4nm,比表面积为1100m2/g.
参考文献
| [1] | Zheng Shan;Gao Lian;Zhang Qinghong;Guo Jingkun .[J].Journal of Materials Chemistry,2000,10(04):723-727. |
| [2] | Jeffrey Brinker C;Lu Yunfeng;Alan Sellinger;Fan Hongyou .[J].Advanced Materials,1999,11(07):579-585. |
| [3] | He Xun;Michel Trudeau .David Antonelli[J].Advanced Materials,2000,12(14):1036-1040. |
| [4] | Stein A.;Schroden RC.;Melde BJ. .Hybrid inorganic-organic mesoporous silicates - Nanoscopic reactors coming of age [Review][J].Advanced Materials,2000(19):1403-1419. |
| [5] | Ulrike Ciesla;Ferdi Schuth .Ordered mesoporous materials[J].Microporous and Mesoporous Materials,1999(2/3):131-149. |
| [6] | Sierra L.;Gil H.;Guth JL.;Lopez B. .Synthesis of mesoporous silica from sodium silica solutions and a poly(ethylene oxide)-based surfactant[J].Advanced Materials,1999(4):307-311. |
| [7] | N. Yalcin;V. Sevinc .Studies on silica obtained from rice husk[J].Ceramics International,2001(2):219-224. |
| [8] | Rawtani A V;Rao M S;Gokaale K V .[J].Industrial and Engineering Chemistry Research,1998,28(08):1411-1415. |
| [9] | 王连洲,施剑林,禹剑,严东生.介孔氧化硅材料的研究进展[J].无机材料学报,1999(03):333-342. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%