制备了一种以聚乙烯醇(Poly(vinyl alcohol),PVA)为基,掺杂物为钨硅酸(silicotungstic acid,STA,SiO2·12WO3·26H2O)和二氧化硅的新型有机/无机复合电解质膜.YIIR及XRD分析表明,STA和SiO2被掺杂进复合电解质中;TGA和DSC分析表明,此种复合电解质膜具有很好的热稳定性,能承受115℃的高温.将复合电解质膜应用于SO2传感器中,传感器电流响应信号与SO2气体浓度有较好的线性关系.这种新型的电解质应用于传感器中,能消除液体电解质传感器易漏液或干涸带来的弊端,具有很好的研究价值.
参考文献
[1] | Chiou-Yen Chiou;Tse-Chuan Chou .Amperometric SO_2 gas sensors based on solid polymer electrolytes[J].Sensors and Actuators, B. Chemical,2002(11):1-7. |
[2] | Chiou CY.;Chou TC. .Characteristics of the gas-diffusion electrode for SO2 sensors[J].Electroanalysis,1998(13):897-903. |
[3] | Liu G;Ding J;Guo A et al.Potential skin layers for membranes with tunable nanochannels[J].Macro,1997,30:1851-1855. |
[4] | Park Yong-il;Nagai Masayuki .Proton exchange nanocomposite membranes based on 3-glycidoxypropyltrimethoxysilane silico-tungstic acid and α-zirconium phosphate hydrate[J].Solid State Ionics,2001,145:149-160. |
[5] | I. Honma;S. Nomura;H. Nakajima .Protonic conducting organic/inorganic nanocomposites for polymer electrolyte membrane[J].Journal of Membrane Science,2001(1):83-94. |
[6] | I. Honma;Y.Takeda .Protonic conducting properties of sol-gel derived organic/inorganicnanocomposite membranes doped with acidic functional molecules[J].Solid state ionics,1999(1/4):255-264. |
[7] | Shao Zhi-gang;Prabhuram Joghee;I-Ming Hsing .Preparation and characterization of hybrid Nafion-silica membrane doped with phosphotungstic acid for proton exchange membrane fuel cells[J].Journal of Membrane Science,2004,229:43-51. |
[8] | 金日光;华幼卿.高分子物理[M].北京:化学工业出版社,1999:120. |
[9] | 杜泽学;何奕工;闵恩泽 .结晶水的性质及其对含钨杂多酸酸性的影响[J].石油学报(石油加工),1999,15(02):1. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%