采用放电等离子烧结(SPS)法,在烧结温度为1 200℃,压力从20 MPa到60 MPa的条件下,以聚碳硅烷(PCS)为结合剂,制备出一种新型的大块多壁碳纳米管(MWCNTs).用SEM和TEM进行观察.结果表明,烧结后材料的纳米级结构仍被保留;XRD分析显示,纳米管通过聚碳硅烷热解的SiC纳米晶相互粘结;随着PCS含量的增加及烧结压力的升高,材料的密度和维氏硬度增加,比表面积减少.动物试验表明,CNTs/PCS材料的炎性反应随着PCS含量增加有轻度增加;通过此种方法制备的碳纳米管,物理性能接近于骨组织,且具有较好的生物相容性,是适宜的候选牙用种植体材料.
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