基于有机分子的光、电、磁功能材料因其巨大的产业化前景,一直受到科技界的高度关注,已成为21世纪重要研究方向之一,也取得了一系列重大进展.有机光电功能材料的研究涉及物理、化学、材料、信息、电子乃至生物学等,是名副其实的交叉学科.在有机光电材料的研究中,一个重要的目标就是搞清材料结构与性能之间的关系,利用一系列先进的方法和工具,对材料的各级结构信息进行表征,找到材料特定性能与结构之间的内在联系,为材料的设计与改性提供必要的依据.晶体学作为一个已经诞生100年的方法,在这一进程中起到了关键的作用.从对材料作用机理的认识,到结构与功能关系的探讨,以及功能材料的定向设计,都需要晶体学知识和方法.结合作者课题组近年来在有机光电材料研究过程中一些比较有代表性的研究工作,阐述晶体学在探明材料的光电性能与结构之间的关系,特别是研究一些材料特殊性质的起源中不可或缺的作用.
参考文献
[1] | Shih-Chun Lo;Paul L.Burn .Development of Dendrimers:Macromolecules for Use in Organic Light-Emitting Diodes and Solar Cells[J].Chemical Reviews,2007(4):1097-1116. |
[2] | Liu Y;Tao X T.Unpublished Work[M]. |
[3] | 马於光,沈家骢.光电功能有机晶体研究进展[J].中国科学B辑,2007(02):105-123. |
[4] | Conwell EM. .EXCIMERS IN POLY(PHENYLENE VINYLENE) AND ITS DERIVATIVES[J].Synthetic Metals,1997(1/3):995-999. |
[5] | Birks J B.Photophysics of Aromatic Molecules[M].London:John Wiley and Sons,1970 |
[6] | Kulkami A P;Kong X;Jenekhe S A .Fluorenone-Containing Polyfluorenesan Doligofluorenes:Photophysics,Ori-Gin of the Green Emission and Efficient Green Electroluminescence[J].Journal of Physical Chemistry B,2004,108:8689-8701. |
[7] | Jenekhe S A;Osaheni J A .Excimers and Exciplexes of Conjugated Polymers[J].SCIENCE,1994,265:765-768. |
[8] | Liu Y;Tao XT;Wang FZ;Shi JH;Sun JL;Yu WT;Ren Y;Zou DC;Jiang MH .Intermolecular hydrogen bonds induce highly emissive excimers: Enhancement of solid-state luminescence[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(17):6544-6549. |
[9] | Yuning Hong;Jacky W. Y. Lam;Ben Zhong Tang .Aggregation-induced emission[J].Chemical Society Reviews,2011(11):5361-5388. |
[10] | Liu Y;Tao XT;Wang FZ;Dang XN;Zou DC;Ren Y;Jiang MH .Aggregation-induced emissions of fluorenonearylamine derivatives: A new kind of materials for nondoped red organic light-emitting diodes[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(10):3975-3981. |
[11] | Yuan M S;Liu Y;Wang J et al.Fluorenone Organic Crystals:Two-Color Luminescence Switchingand Reversible Phase Transformations between π-π Stacking-Directed Packing and Hydrogen Bond-Directed Packing[J].CHEMISTRY OF MATERIALS,2014,26(07):2467-2477. |
[12] | Yuan C X;Xin Q;Liu H J et al.∧-Shaped Optoelectronic Materials Based on Tr(o)ger's Base[J].Science China Chemistry,2011,54(04):587-595. |
[13] | Yuan CX;Tao XT;Ren Y;Li Y;Yang JX;Yu WT;Wang L;Jiang MH .Synthesis, structure, and aggregation-induced emission of a novel lambda (Lambda)-Shaped pyridinium salt based on troger's base[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(34):12811-12816. |
[14] | Yuan C X;Tao X T;Wang L et al.Fluorescence Turn-on Detection and Assay of Protein Based on Lambda(∧)-Shaped Pyridinium Salts With Aggregation-Induced Emissioncharacteristics[J].J Phys Chem C,2009,113:6809-6814. |
[15] | Xin Q;Tao XT;Wang FZ;Sun JL;Zou DC;Wang FJ;Liu HJ;Liu Z;Ren Y;Jiang MH .Fluorene-based Troger's base analogues: Potential electroluminescent materials[J].Organic electronics,2008(6):1076-1086. |
[16] | Xin Q;Tao X T;Liu H J.Synthesis,Structure Andpacking Properties of Three Tr(o)ger' s Base Analogues Containing Substituted Fluoreneunits[J].CrystEng Comm,2008(10):1204-1210. |
[17] | Xi H;Yuan C X;Li Y X et al.Crystal Structures and Solid-State Fuorescence of BODIPY Dyes Based on ∧-Shaped Tr(o)ger' s Base[J].CrystEng Comm,2012,14:2087-2093. |
[18] | Yuan C X;Tao X T.unpublished work[M]. |
[19] | 陶然,乔娟,段炼,邱勇.蓝色磷光有机发光材料[J].化学进展,2010(12):2255-2267. |
[20] | 肖立新,胡双元,孔胜,亓博远,张明骁,陈志坚,曲波,龚旗煌.蓝色荧光小分子电致发光材料[J].光学学报,2010(07):1895-1903. |
[21] | Simone Hofmann;Markus Hummert;ReinhardScholz et al.Preparation and Properties of NdFeB/Nb Multi-Layer Films[J].Chemistry of Materials,2014,26(07):2414-2426. |
[22] | Liu, Y;Tao, XT;Wang, FZ;Dang, XN;Zou, DC;Ren, Y;Jiang, MH .Parallel H-shaped phenylenevinylenes: Quasi-coplanar molecules for highly luminescent blue OLEDs[J].Organic electronics,2009(6):1082-1090. |
[23] | Zengqi Xie;Bing Yang;Feng Li;Gang Cheng;Linlin Liu .Cross Dipole Stacking in the Crystal of Distyrylbenzene Derivative:The Approach toward High Solid-State Luminescence Efficiency[J].Journal of the American Chemical Society,2005(41):14152-14153. |
[24] | Feng He;Hai Xu;Bing Yang;Yu Duan;Leilei Tian;Keke Huang;Yuguang Ma;Shiyong Liu;Shouhua Feng;Jiacong Shen .Oligomeric Phenylenevinylene with Cross Dipole Arrangement and Amorphous Morphology: Enhanced Solid-State Luminescence Efficiency and Electroluminescence Performance[J].Advanced Materials,2005(22):2710-2714. |
[25] | Wang S;Oldham W J;Hudack R A et al.Synthesis,Morphology,and Optical Properties of Tetrahedral Oligo(Phenylenevinylene) Materials[J].Journal of the American Chemical Society,2000,122:5695-5709. |
[26] | Würthner F;Thalacker C;Diele S et al.Fluorescent J-Type Aggregates and Thermotropic Columnar Mesophases of PeryleneBisimide Dyes[J].Chemistry-A European Journal,2001,7(10):2245-2253. |
[27] | Xie Z;Yang B;Cheng G et al.Supramolecular Interactions Induced Fluorescence in Crystal:Anomalous Emission of 2,5-Diphenyl-1,4-Distyrylbenzene With All Cis Double Bonds[J].Chemistry of Materials,2005,17(06):1287-1289. |
[28] | Liu Y;Tao XT;Wang FZ;Dang XN;Zou DC;Ren Y;Jiang MH .Efficient non-doped pure blue organic light-emitting diodes based on an asymmetric phenylenevinylene with cis double bond[J].Organic electronics,2008(5):609-616. |
[29] | Roncali J;Leriche P;Cravino A .From one- to three-dimensional organic semiconductors: In search of the organic silicon?[J].Advanced Materials,2007(16):2045-2060. |
[30] | Tang QX;Li HX;Liu YL;Hu WP .High-performance air-stable n-type transistors with an asymmetrical device configuration based on organic single-crystalline submicrometer/nanometer ribbons[J].Journal of the American Chemical Society,2006(45):14634-14639. |
[31] | Sundar V C;Zaumseil J;Podzorov V et al.Elastomeric Transistor Stamps:Reversible Probing of Charge Transport in Organic Crystals[J].SCIENCE,2004,303:1644-1646. |
[32] | Reese, C;Bao, Z .High-resolution measurement of the anisotropy of charge transport in single crystals[J].Advanced Materials,2007(24):4535-4538. |
[33] | Vendrell O;Moreno M;Lluch J M et al.Molecular Dynamics of Excited State Intramolecular Proton Transfer:2-(2'-Hydroxyphenyl)-4-Methyloxazole in Gas Phase,Solution,and Protein Environments[J].Journal of Physical Chemistry B,2004,108(21):6616-6623. |
[34] | Mukherjee TK;Ahuja P;Koner AL;Datta A .ESPT of 2-(2'-pyridyl)benzimidazole at the micelle-water interface: Selective enhancement and slow dynamics with sodium dodecyl sulfate[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2005(25):12567-12573. |
[35] | Li Y X;Tao X T;Wang F J et al.Structurally Tailored Tiophene-Based Hybrid Materials for Thin-Film and Single-Crystal Transistors:Synthesis,Photophysics and Carrier-Transport Properties[J].ORGANIC ELECTRONICS,2009,10(05):910-917. |
[36] | Li, YX;Tao, XT;Wang, FJ;He, T;Zhang, LL;Jiang, MH .Effect of substituents on the properties of distyrylarylene-based field-effect transistor materials[J].Chemical Physics Letters,2009(4/6):264-268. |
[37] | Tao He;Xiying Zhang;Jiong Jia;Yexin Li;Xutang Tao .Three-Dimensional Charge Transport in Organic Semiconductor Single Crystals[J].Advanced Materials,2012(16):2171-2175. |
[38] | Tomohiro Seki;Kenta Sakurada;Hajime Ito .Controlling Mechano- and Seeding-Triggered Single-Crystal-to-Single-Crystal Phase Transition: Molecular Domino with a Disconnection of Aurophilic Bonds[J].Angewandte Chemie,2013(49):12828-12832. |
[39] | Martin K.Beyer;Hauke Clausen-Schaumann .Mechanochemistry:The Mechanical Activation of Covalent Bonds[J].Chemical Reviews,2005(8):2921-2948. |
[40] | Skoko, ?.;Zamir, S.;Naumov, P.;Bernstein, J. .The thermosalient phenomenon. "jumping crystals" and crystal chemistry of the anticholinergic agent oxitropium bromide[J].Journal of the American Chemical Society,2010(40):14191-14202. |
[41] | Sahoo, S.C.;Panda, M.K.;Nath, N.K.;Naumov, P. .Biomimetic crystalline actuators: Structure-kinematic aspects of the self-actuation and motility of thermosalient crystals[J].Journal of the American Chemical Society,2013(33):12241-12251. |
[42] | Miguel A. Garcia-Garibay .Molecular Crystals on the Move: From Single-Crystal-to- Single-Crystal Photoreactions to Molecular Machinery[J].Angewandte Chemie,2007(47):8945-8947. |
[43] | Kobatake S;Takami S;Muto H;Ishikawa T;Irie M .Rapid and reversible shape changes of molecular crystals on photoirradiation[J].Nature,2007(7137):778-781. |
[44] | Pance Naumov;Subash Chandra Sahoo;Boris A. Zakharov .Dynamic Single Crystals: Kinematic Analysis of Photoinduced Crystal Jumping (The Photosalient Effect)[J].Angewandte Chemie,2013(38):9990-9995. |
[45] | Elinor C. Spencer;Ross J. Angel;Nancy L. Ross;Brian E. Hanson;Judith A. K. Howard .Pressure-Induced Cooperative Bond Rearrangement in a Zinc Imidazolate Framework: A High-Pressure Single-Crystal X-Ray Diffraction Study[J].Journal of the American Chemical Society,2009(11):4022-4026. |
[46] | Nagura, K.;Saito, S.;Yusa, H.;Yamawaki, H.;Fujihisa, H.;Sato, H.;Shimoikeda, Y.;Yamaguchi, S. .Distinct responses to mechanical grinding and hydrostatic pressure in luminescent chromism of tetrathiazolylthiophene[J].Journal of the American Chemical Society,2013(28):10322-10325. |
[47] | Guangfeng Liu;Jie Liu;Yang Liu;Xutang Tao .Oriented Single-Crystal-to-Single-Crystal Phase Transition with Dramatic Changes in the Dimensions of Crystals[J].Journal of the American Chemical Society,2014(2):590-593. |
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