有机-无机杂化体异质结太阳电池以无机半导体纳米晶作为电子受体,共轭聚合物作为电子给体,是近年来的一个研究热点.在设计上,有机-无机杂化材料兼具有机材料的柔性、结构多样性、易加工和无机材料载流子迁移率高、稳定性好的优势,具有良好的发展前景.介绍了有机-无机杂化体异质结太阳电池的结构、工作原理,从共轭聚合物、无机半导体纳米材料以及电池制备工艺3个方面综述了近年来国内外研究现状,主要包括有机-无机杂化体异质结太阳电池中常用共轭聚合物结构、带隙,无机纳米晶种类、形貌、表面改性以及有源层厚度、形貌调控等内容.着重介绍了基于CdSe、TiO2、PbS类纳米晶的太阳电池.最后讨论了有机-无机杂化体异质结太阳电池目前存在的问题和发展方向.
参考文献
[1] | Darling S B .Block Copolymers for Photovoltaics[J].Energy & Environmental Science,2009,2 |
[2] | Krebs F C,Nielsen T D,Fyenbo J,et al.Manufacture,Integration and Demonstration of Polymer Solar Cells in a Lamp for the “ Lighting Africa” Initiative[J].Energy & Environmental Science,2010(3):512-525.,2010. |
[3] | Taranekar P,Qiao Q,Jiang J,et al .Hyperbranched Conjugated Polyelectrolyte Bilayers for Solar-Cell Applications[J].Journal of the American Chemical Soc&ty,2007,129 |
[4] | Qiao Q,Xie Y,McLeskey J T .Organic/Inorganic Polymer Solar Cells Using a Buffer Layer from All-Water-Solution Processing[J].The Journal of Physical Chemistry C,2008,112 |
[5] | Gao F,Ren S Q,Wang J P.The Renaissance of Hybrid Solar Cells:Progresses,Challenges,and Perspectives[J].Energy & Environmental Science,2013(6):2 020-2 040.,2013. |
[6] | You J B,Dou L T,Yang Y,et al.A Polymer Tandem Solar Cell with 10.6% Power Conversion Efficiency[J].Nature Communications,2013,DOI:10.1038/ncomms2411.,2013. |
[7] | Wright M,Uddin A .Organic-Inorganic Hybrid Solar Cells:A Comparative Review[J].Solar Energy Materials and Solar Cells,2012,107 |
[8] | Xu T T,Qiao Q.Conjugated Polymer-Inorganic Semiconductor Hybrid Solar Cells[J].Energy & Environmental Science,2011(4):2 700-2 720.,2011. |
[9] | Wei H T,Zhang H,Sun H Z,et al.Preparation of Polymer-Nanocrystals Hybrid Solar Cells Through Aqueous Approaches[J].Nano Today,2012(7):316-326.,2012. |
[10] | TangAW,QuSC,TengF,etal.Recent Developments of Hybrid Nanocrystal/Polymer Bulk Heterojunction Solar Cells[J].Journal of Nanoscience and Nanotechnology,2011 (11):9 384-9 394.,2011. |
[11] | Greenham N C,Peng X G,Alivisatos A P .Charge Separation and Transport in Conjugated-Polymer/Semiconductor-Nanocrystal Composites Studied by Photoluminescence Quenching and Photoconductivity[J].Physical Review B,1996,54 |
[12] | Wendy U Huynh,Janke J Dittmer,Paul Alivisatos A .Hybrid Nanorod-Polymer Solar Cells[J].Science,2002,295 |
[13] | Sun B G,Marx E,Greenham N C.Photovoltaic Devices Using Blends of Branched CdSe Nanoparticles and Conjugated Polymers[J].Nano Letters,2003(3):961-963.,2003. |
[14] | Liu Z,Sun Y,Yuan J,et al .High-Efficiency Hybrid Solar Cells Based on Polymer_ PbSxSe1-x Nanocrystals Benefiting from Vertical Phase Segregation[J].Advanced Materials,2013,25 |
[15] | Yamanari T,Taima T,Sakai J,et al .Origin of the Open-Circuit Voltage of Organic Thin-Film Solar Cells Based on Conjugated Polymers[J].Solar Energy Materials and Solar Cells,2009,93 |
[16] | Beek W J E,Wienk M M,Janssen R A J .Efficient Hybrid Solar Cells from Zinc Oxide Nanoparticles and a Conjugated Polymer[J].Advanced Materials,2004,16 |
[17] | Shen L,Zhu G H,Guo W B,et al .Performance Improvement of TiO2/P3HT Solar Cells Using CuPc As a Sensitizer[J].Applied Physics Letters,2008,92 |
[18] | Soci C,Hwang I W,Heeger A,et al .Photoconductivity of a Low-Bandgap Conjugated Polymer[J].Advanced Functional Materials,2007,17 |
[19] | Liang Y,Xu Z,Xia J,et al .For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4%[J].Advanced Materials,2010,22 |
[20] | Yue W,Zhao Y,Shao S,et al .Novel NIR-Absorbing Conjugated Polymers for Efficient Polymer Solar cells:Effect of Alkyl Chain Length on Device Performance[J].Journal of Materials Chemistry,2009,19 |
[21] | Zhang Y,Li Z,Ouyang J,et al .Hole Transfer from PbS Nanocrystal Quantum Dots to Polymers and Efficient Hybrid Solar Cells Utilizing Infrared Photons[J].Organic Electronics,2012,13 |
[22] | Guchhait A,Rath A K,Pal A J .To Make Polymer:Quantum Dot Hybrid Solar Cells NIR-Active By Increasing Diameter of PbS Nanoparticles[J].Solar Energy Materials and Solar Cells,2011,95 |
[23] | Reynolds L X,Lutz T,Dowland S,et al.Charge Photogeneration in Hybrid Solar Cells:A Comparison Between Quantum Dots and in Situ Grown CdS[J].Nanoscale,2012(4):1 561-1 564.,2012. |
[24] | Ren S,Chang L Y,Lim S K,et al.Inorganic-Olrganic Hybrid Solar Cell:Bridging Quantum Dots to Conjugated Polymer Nanowires[J].Nano letters,2011 (11):3 998-4 002.,2011. |
[25] | Jeltsch K F,Schadel M,Bonekamp J B,et al .Efficiency Enhanced Hybrid Solar Cells Using a Blend of Quantum Dots and Nanorods[J].Advanced Functional Materials,2012,22 |
[26] | Zhou R,Zheng Y,Qian L,et al.Solution-Processed Nanostructured Hybrid Solar Cells with Broad Spectral Sensitivity and Stability[J].Nanoscale,2012(4):3 507-3 514.,2012. |
[27] | Celik D,Krueger M,Veit C,et al .Performance Enhancement of CdSe Nanorod-Polymer Based Hybrid Solar Cells Utilizing a Novel Combination of Post-Synthetic Nanoparticle Surface Treatments[J].Solar Energy Materials and Solar Cells,2012,98 |
[28] | Dayal S,Kopidakis N,Olson D C,et al.Photovoltaic Devices with a Low Band Gap Polymer and CdSe Nanostructures Exceeding 3% Efficiency[J].Nano Letters,2009(10):239-242.,2009. |
[29] | Kuo C Y,Su M S,Chen G Y,et al .Annealing Treatment Improves the Morphology and Performance of Photovoltaic Devices Prepared from Thieno【3,4-c】Pyrrole-4,6-Dione-Based Donor/Acceptor Conjugated Polymers and CdSe Nanostructures[J].Energy & Environmental Science,2011,4 |
[30] | Wu Y,Zhang G.Performance Enhancement of Hybrid Solar Cells Through Chemical Vapor Annealing[J].Nano Letters,2011(10):1 628-1 631.,2011. |
[31] | Gur,Fromer N A,Chen C P,et al.Hybrid Solar Cells with Prescribed Nanoscale Morphologies Based on Hyperbranched Semiconductor Nanocrystals[J].Nano Letters,2006 (7):409-414.,2006. |
[32] | Yang J,Tang A,Zhou R,et al .Effects of Nanocrystal Size and Device Aging on Performance of Hybrid Poly (3-Hexylthiophene):CdSe Nanocrystal Solar Cells[J].Solar Energy Materials and Solar Cells,2011,95:CdSe Nanocrystal Solar Cells[J].Solar Energy Materials and Solar Cells,2011,95:476-482.,2011. |
[33] | Chen H C,Lai C W,Wu I C,et al .Enhanced Performance and Air Stability of 3.2% Hybrid Solar Cells:How the Functional Polymer and CdTe Nanostructure Boost the Solar Cell Efficiency[J].Advanced Materials,2011,23 |
[34] | Beek W JE,Wienk M M,Janssen R A J .Hybrid Solar Cells from Regioregular Polythiophene and ZnO Nanoparticles[J].Advanced Functional Materials,2006,16 |
[35] | Li F,Chen W,Yuan K,et al .Photovoltaic Performance Enhancement in P3HT/ZnO Hybrid Bulk-Heterojunction Solar Cells Induced by Semiconducting Liquid Crystal Ligands[J].Organic Electronics,2012,13 |
[36] | Oosterhout S D,Wienk M M,Van Bavel S S,et al.The Effect of Three-Dimensional Morphology on the Efficiency of Hybrid Polymer Solar Cells[J].Nature Materials,2009 (8):818-824.,2009. |
[37] | Wu J,Yue G,Xiao Y,et al.An Ultraviolet Responsive Hybrid Solar Cell Based on Titania/poly(3-Hexylthiophene)[J].Scientific reports,2013(3):1 283.,2013. |
[38] | Hsu C W,Wang L,Su W F .Effect of Chemical Structure of Interface Modifier of TiO2 on Photovoltaic Properties of Poly (3-Hexylthiophene)/TiO2 Layered Solar Cells[J].Journal of Colloid and Interface Science,2009,329(1):182-187.,2009. |
[39] | Bouclé J,Chyla S,Shaffer M,et al .Hybrid Solar Cells from a Blend of Poly (3-hexylthiophene) and Ligand-Capped TiO2 Nanorods[J].Advanced Functional Materials,2008,18(4):622-633.,2008. |
[40] | ZengTW,Lin Y Y,Lo H H,et al .A Large Interconnecting Network Within Hybrid MEH-PPV/TiO2 Nanorod Photovoltaic Devices[J].Nanotechnology,2006,17(21):5 387-5 392.,2006. |
[41] | Lin Y Y,Chu T H,Chen C W,et al .Improved Performance of Polymer/TiO2 Nanorod Bulk Heterojunction Photovoltaic Devices by Interface Modification[J].Applied Physics Letters,2008,92(5):053 312.,2008. |
[42] | Lin Y Y,Chu T H,Li S S,et al .Interfacial Nanostructuring on the Performance of Polymer/TiO2 Nanorod Bulk Heterojunction Solar Cells[J].Journal of the American Chemical Society,2009,131 |
[43] | Yu Y Y,Chen W C,Ko Y H,et al .Preparation and Characterization of P3HT:CuInSe2:TiO2 Thin Film for Hybrid Solar Cell Applications[J].Thin Solid Films,2011,520 |
[44] | Kumar Dixit,Madan S,Kaur S,et al .Enhancement of Efficiency of a Conducting Polymer P3HT:CdSe/ZnS Quantum Dots Hybrid Solar Cell by Adding Single Walled Carbon Nanotube for Transporting Photogenerated Electrons[J].Journal of Renewable and Sustainable Energy,2013,5(3):033 107.,2013. |
[45] | Tan FR,QuSC,WangZG,etal .Synthesis of Silver Quantum Dots Decorated TiO2 Nanotubes and Their Incorporation in Organic Hybrid Solar Cells[J].Journal of Nanoparticle Research,2013,15 |
[46] | Liu K,Bi Y,Qu S,et al.Efficient Hybrid Plasmonic Polymer Solar Cells with Ag Nanoparticles Decorated TiO2 Nanorods Embedded in the Active Layer[J].Nanoscale,2014,DOI:10.1039/C4NR00030G.,2014. |
[47] | Huynh W U,Dittmer J J,Alivisatos A P,et al .Charge Transport in Hybrid Nanorod-Polymer Composite Photovoltaic Cells[J].Physical Review B,2003,67 |
[48] | Kim Y,Choulis S A,Nelson J,et al .Device Annealing Effect in Organic Solar Cells with Blends of Regioregular Poly(3-Hexylthiophene) and Soluble Fullerene[J].Applied Physics Letters,2005,86 |
[49] | Li G,Yao Y,Yang H,et al .“ Solvent Annealing” Effect in Polymer Solar Cells Based on Poly (3-Hexylthiophene) and Methanofullerenes[J].Advanced Functional Materials,2007,17 |
[50] | Müller C,Wang E,Andersson L M,et al .Influence of Molecular Weight on the Performance of Organic Solar Cells Based on a Fluorene Derivative[J].Advanced Functional Materials,2010,20 |
[51] | Günes S,Neugebauer H,Sariciftci N S .Conjugated PolymerBased Organic Solar Cells[J].Chemical reviews,2007,107 |
[52] | Sun B,Grccnham N C.Improved Efficiency of Photovoltaics Based on CdSe Nanorods and Poly (3-Hexylthiophene) Nanofibers[J].Physical Chemistry Chemical Physics,2006 (8):3 557-3560.,2006. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%