本文报道了4-[4-((4-吡啶基)乙烯基)苯乙烯基]-N,N-二正丁基苯胺的合成及晶体结构,并讨论了它的吸收光谱、荧光光谱、荧光寿命、荧光量子产率及电致发光性质.该分子晶体属于三斜晶系,P-1空间群,晶胞参数为:a=1.0101(3) nm,b=1.0352(2) nm,c=2.6220(5) nm,Z=4,V=2.4224(10)nm3,R1=0.1006,wR2 =0.1818.研究结果表明,该化合物在电致发光方面有潜在的应用价值.CCDC号:815101.
参考文献
| [1] | Tang C W;Vanslyke S A .Organic electroluinescent diodes[J].Applied Physics Letters,1987,51:913-915. |
| [2] | Buda M.;Kalyuzhny G.;Bard AJ. .Thin-film solid-state electroluminescent devices based on tris(2,2 '-bipyridine)ruthenium(II) complexes[J].Journal of the American Chemical Society,2002(21):6090-6098. |
| [3] | Liu C Y;Bard A .Individually addressable submicron scale light-emitting devices based on electroluminescence of solid Ru(bpy)3(ClO4)2films[J].Journal of the American Chemical Society,2002,124(16):4190-4191. |
| [4] | Mukundan Thelakkat .Star-Shaped, Dendrimeric and Polymeric Triarylamines as Photoconductors and Hole Transport Materials for Electro-Optical Applications[J].Macromolecular materials and engineering,2002(7):442-461. |
| [5] | Peter Strohriegl;Juozas V. Grazulevicius .Charge-Transporting Molecular Glasses[J].Advanced Materials,2002(20):1439-1452. |
| [6] | 蒋希,田仁玉,莫越奇,曹镛.含噻吩单元的硅芴共聚物的合成及其蓝色电致发光性能[J].高等学校化学学报,2007(08):1586-1592. |
| [7] | Yan Ren;Xiao-Qiang Yu;Dong-Ju Zhang;Ming-Liang Zhang;Dong Wang;Gui-Bao Xu;Xian Zhao;Yu-Peng Tian;Zong-Shu Shao;Min-Hua Jiang .Synthesis, structure and properties of a new two-photon photopolymerization initiator[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2002(12):3431-3437. |
| [8] | Wang CK.;Zhao K.;Su Y.;Ren Y.;Zhao X.;Luo Y. .Solvent effects on the electronic structure of a newly synthesized two-photon polymerization initiator[J].The Journal of Chemical Physics,2003(2):1208-1213. |
| [9] | 苗泉,赵鹏,孙玉萍,刘纪彩,王传奎.超短脉冲激光在DBASVP分子中传播时的双光子面积演化和光限幅效应[J].物理学报,2009(08):5455-5461. |
| [10] | Jin F;Li JF;Zhou HP;Wu JY;Yang JX;Tian YP;Jiang MH .Synthesis, crystal structures, and optical properties of a novel imidazole derivative and its Zn(II) complex[J].Journal of Molecular Structure,2007(1/3):202-207. |
| [11] | Shelderik G M.SHELXL-97 Program for Crystal Structure Refinement[M].Germany:University of G(o)ttingen,1997 |
| [12] | 徐筱杰,唐有祺.晶体工程及其在化学中的应用[J].无机化学学报,2000(02):157-166. |
| [13] | 宁永成.有机化合物结构鉴定与有机波谱学[M].北京:科学出版社,2000 |
| [14] | 陈国珍.荧光分析法[M].北京:科学出版社,1990 |
| [15] | 樊美公.光化学基本原理与光子学材料科学[M].北京:科学出版社,2001 |
| [16] | 黄达,叶俊,赵伟明,郑才俊,王静,陶斯禄,欧雪梅,张晓宏.双极绿色磷光主体材料1-甲基-3-[4-（9-咔唑基）苯基]-4-苯基喹啉-2（1H）-酮的合成与性能研究[J].影像科学与光化学,2010(06):408-415. |
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