超分子凝胶中的光化学反应是比较特殊的一类反应,通常是将具有光响应活性的基团或分子引入到超分子凝胶的自组装体系中,因此,能够将超分子凝胶独特的性质与光化学反应的优势有效地结合起来,构筑新型的光功能材料,这使得此类超分子凝胶在光信息存储、光开关及光转换器件等前沿领域具有广阔的应用前景.本文主要总结近年来国内外包括作者课题组对超分子凝胶中光化学反应方面的研究进展,以及其在多重响应凝胶、手性光学开关以及手性合成方面的应用.
参考文献
| [1] | MATHEW GEORGE;RICHARD G.WEISS .Molecular Organogels.Soft Matter Comprised of Low-Molecular-Mass Organic Gelators and Organic Liquids'[J].Accounts of Chemical Research,2006(8):489-497. |
| [2] | Parthasarathi Dastidar .Supramolecular gelling agents: can they be designed?[J].Chemical Society Reviews,2008(12):2699-2715. |
| [3] | Xudong Yu;Liming Chen;Mingming Zhang .Low-molecular-mass gels responding to ultrasound and mechanical stress: towards self-healing materials[J].Chemical Society Reviews,2014(15):5346-5371. |
| [4] | Fan Zhao;Man Lung Ma;Bing Xu .Molecular hydrogels of therapeutic agents[J].Chemical Society Reviews,2009(4):883-891. |
| [5] | Xingyuan Yang;Guanxin Zhang;Deqing Zhang .Stimuli responsive gels based on low molecular weight gelators[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2012(1):38-50. |
| [6] | Shiki Yagai;Akihide Kitamura .Recent advances in photoresponsive supramolecular self-assemblies[J].Chemical Society Reviews,2008(8):1520-1529. |
| [7] | Photoswitches: From Molecules to Materials[J].Advanced Materials,2010(31):3348-3360. |
| [8] | Kim JH;Seo M;Kim YJ;Kim SY .Rapid and Reversible Gel-Sol Transition of Self-Assembled Gels Induced by Photoisomerization of Dendritic Azobenzenes[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(3):1761-1766. |
| [9] | Xiaojuan Liao;Guosong Chen;Xiaoxia Liu .Photoresponsive Pseudopolyrotaxane Hydrogels Based on Competition of Host-Guest Interactions[J].Angewandte Chemie,2010(26):4409-4413. |
| [10] | Guosong Chen;Ming Jiang .Cyclodextrin-based inclusion complexation bridging supramolecular chemistry and macromolecular self-assembly[J].Chemical Society Reviews,2011(5):2254-2266. |
| [11] | de Jong JJD;Lucas LN;Kellogg RM;van Esch JH;Feringa BL .Reversible optical transcription of supramolecular chirality into molecular chirality[J].Science,2004(5668):278-281. |
| [12] | Jaap J.D.de Jong;Theodora D.Tiemersma-Wegman;Jan H.van Esch;Ben L.Feringa .Dynamic Chiral Selection and Amplification Using Photoresponsive Organogelators[J].Journal of the American Chemical Society,2005(40):13804-13805. |
| [13] | Jochem T. van Herpt;Jetsuda Areephong;Marc C. A. Stuart;Wesley R. Browne;Ben L. Feringa .Light-Controlled Formation of Vesicles and Supramolecular Organogels by a Cholesterol-Bearing Amphiphilic Molecular Switch[J].Chemistry: A European journal,2014(6):1737-1742. |
| [14] | Tian H;Wang S .Photochromic bisthienylethene as multi-function switches[J].Chemical communications,2007(8):781-792. |
| [15] | Wang S;Shen W;Feng YL;Tian H .A multiple switching bisthienylethene and its photochromic fluorescent organogelator[J].Chemical communications,2006(14):1497-1499. |
| [16] | Zhang, J.;Jin, J.;Zou, L.;Tian, H. .Reversible photo-controllable gels based on bisthienylethene-doped lecithin micelles[J].Chemical communications,2013(85):9926-9928. |
| [17] | Cao, X.;Zhou, J.;Zou, Y.;Zhang, M.;Yu, X.;Zhang, S.;Yi, T.;Huang, C. .Fluorescence and morphology modulation in a photochromic diarylethene self-assembly system[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(8):5090-5097. |
| [18] | Lee, H.-Y.;Diehn, K.K.;Sun, K.;Chen, T.;Raghavan, S.R. .Reversible photorheological fluids based on spiropyran-doped reverse micelles[J].Journal of the American Chemical Society,2011(22):8461-8463. |
| [19] | Light-Triggered Self-Assembly of a Spiropyran-Functionalized Dendron into Nano-/Micrometer-Sized Particles and Photoresponsive Organogel with Switchable Fluorescence[J].Advanced functional materials,2010(1):36. |
| [20] | Reppy MA;Pindzola BA .Biosensing with polydiacetylene materials: structures, optical properties and applications[J].Chemical communications,2007(42):4317-4338. |
| [21] | Jiseok Lee;Jinsang Kim .Multiphasic Sensory Alginate Particle Having Polydiacetylene Liposome for Selective and More Sensitive Multitargeting Detection[J].Chemistry of Materials: A Publication of the American Chemistry Society,2012(14):2817-2822. |
| [22] | Yan-lei Su .Preparation of polydiacetylene/silica nanocomposite for use as a chemosensor[J].Reactive & functional polymers,2006(9):967-973. |
| [23] | Norifumi Fujita;Yoshimine Sakamoto;Michihiro Shirakawa;Masayoshi Ojima;Akihiko Fujii;Masanori Ozaki;Seiji Shinkai .Polydiacetylene Nanofibers Created in Low-Molecular-Weight Gels by Post Modification: Control of Blue and Red Phases by the Odd-Even Effect in Alkyl Chains[J].Journal of the American Chemical Society,2007(14):4134-4135. |
| [24] | Simon Rondeau-Gagne;Jules Romeo Neabo;Maude Desroches .The importance of the amide configuration in the gelation process and topochemical polymerization of phenylacetylene macrocycles[J].Journal of Materials Chemistry, C. materials for optical and electronic devices,2013(15):2680-2687. |
| [25] | Rondeau-Gagné, S.;Néabo, J.R.;Desroches, M.;Larouche, J.;Brisson, J.;Morin, J.-F. .Topochemical polymerization of phenylacetylene macrocycles: A new strategy for the preparation of organic nanorods[J].Journal of the American Chemical Society,2013(1):110-113. |
| [26] | Néabo, J.R.;Rondeau-Gagné, S.;Vigier-Carrieìre, C.;Morin, J.-F. .Soluble conjugated one-dimensional nanowires prepared by topochemical polymerization of a butadiynes-containing star-shaped molecule in the xerogel state[J].Langmuir: The ACS Journal of Surfaces and Colloids,2013(10):3446-3452. |
| [27] | DUAN PengFei,LI YuanGang,LIU MingHua.Preparation of optical active polydiacetylene through gelating and the control of supramolecular chirality[J].中国科学：化学（英文版）,2010(02):432-437. |
| [28] | Wang, J.;Yang, G.;Jiang, H.;Zou, G.;Zhang, Q. .Photo-responsive cholesterol-substituted diacetylenic organogels: Morphology tuning, photo-switching and photo-polymerization[J].Soft matter,2013(41):9785-9791. |
| [29] | Coates GW.;Henling LM.;Ziller JW.;Lobkovsky EB.;Grubbs RH.;Dunn AR. .Phenyl-perfluorophenyl stacking interactions: Topochemical[2+2] photodimerization and photopolymerization of olefinic compounds[J].Journal of the American Chemical Society,1998(15):3641-3649. |
| [30] | Ramamurthy V;Venkatesan K .Photochemical-reactions of organic-crystals[J].Chemical Reviews,1987,87(2):433-481. |
| [31] | Kole G K;Tan G K;Vittal J J .Crystal engineering studies on the salts of trans-4,4 '-stilbenedicarboxylic acid in the context of solid state 2 + 2 cycloaddition reaction[J].CRYSTENGCOMM,2011,13(9):3138-3145. |
| [32] | Kihara H;Tamaoki N .An H-bonded main-chain liquid-crystalline polymer obtained by in situ photochemical conversion from an H-bonded LC dimer[J].Macromolecular chemistry and physics,2008(14):1424-1431. |
| [33] | Qing Lu;Minghua Liu .Spontaneous two-dimensional crystallization and photochemical reaction of a novel bolaamphiphilic naphthol ester in the spreading Langmuir film at the air/water interface and transferred Langmuir―Blodgett film[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):248-254. |
| [34] | Liu L;Zhang L;Wang T;Liu M .Interfacial assembly of amphiphilicstyrylquinoxalines:alkyl chain length tunable topochemical reactions and supramolecular chirality[J].Physical Chemistry Chemical Physics,2013,15(17):6243-6249. |
| [35] | Xiufeng Wang;Pengfei Duan;Minghua Liu .Organogelation-Controlled Topochemical [2+2] Cycloaddition and Morphological Changes: From Nanofiber to Peculiar Coaxial Hollow Toruloid-Like Nanostructures[J].Chemistry: A European journal,2013(47):16072-16079. |
| [36] | Wang X;Liu M .Vicinal solvent effect on supramolecular gelation:Alcohol controlled topochemical reaction and the toruloid nanostructure[J].Chemistry-A European Journal,2014,20(32):10110-10116. |
| [37] | Pengfei Duan;Yuangang Li;Liangchun Li .Multiresponsive Chiroptical Switch of an Azobenzene-Containing Lipid: Solvent, Temperature, and Photoregulated Supramolecular Chirality[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2011(13):3322-3329. |
| [38] | Lin, YY;Cheng, XH;Qiao, Y;Yu, CL;Li, ZB;Yan, Y;Huang, JB .Creation of photo-modulated multi-state and multi-scale molecular assemblies via binary-state molecular switch[J].Soft matter,2010(5):902-908. |
| [39] | Lin, Y.;Qiao, Y.;Tang, P.;Li, Z.;Huang, J. .Controllable self-assembled laminated nanoribbons from dipeptide-amphiphile bearing azobenzene moiety[J].Soft matter,2011(6):2762-2769. |
| [40] | Lin, YY;Wang, AD;Qiao, Y;Gao, C;Drechsler, M;Ye, JP;Yan, Y;Huang, JB .Rationally designed helical nanofibers via multiple non-covalent interactions: fabrication and modulation[J].Soft matter,2010(9):2031-2036. |
| [41] | Zhan CL;Gao P;Liu MH .Self-assembled helical spherical-nanotubes from an L-glutamic acid based bolaamphiphilic low molecular mass organogelator[J].Chemical communications,2005(4):462-464. |
| [42] | Cao, H.;Jiang, J.;Zhu, X.;Duan, P.;Liu, M. .Hierarchical co-assembly of chiral lipid nanotubes with an azobenzene derivative: Optical and chiroptical switching[J].Soft matter,2011(10):4654-4660. |
| [43] | Cheng Wang;Deqing Zhang;Junfeng Xiang .New Organogels Based on an Anthracene Derivative with One Urea Group and Its Photodimer: Fluorescence Enhancement after Gelation[J].Langmuir: The ACS Journal of Surfaces and Colloids,2007(18):9195-9200. |
| [44] | Dawn, A;Shiraki, T;Haraguchi, S;Sato, H;Sada, K;Shinkai, S .Transcription of Chirality in the Organogel Systems Dictates the Enantiodifferentiating Photodimerization of Substituted Anthracene[J].Chemistry: A European journal,2010(12):3676-3689. |
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