设计合成了具有较长发射波长的苯并香豆素醛——8-二乙氨基-2-氧-2H-苯并[h]香豆素醛(BCA),通过吸收和荧光光谱研究其在不同溶剂中的光物理性质.结果表明,BCA具有明显的溶致变色效应和宽的颜色变化范围.随着溶剂极性的增加,其荧光发射可从蓝绿光变到红光,而荧光量子效率则从0.98减小到0.26.
参考文献
[1] | Chia Y C;Chang F R;Wang J C;Wu C C Chiang M Y N Lan Y H Chen K S Wu Y C .Antiplatelet aggregation coumarins from the leaves of Murraya omphalocarpa[J].Molexales,2008,13(01):122-128. |
[2] | Dekic B R;Radulovic N S;Dekic V S;Vukicevic R D Palic R M .Synthesis and antimicrobial activity of new 4-heteroarylamino coumarin derivatives containing nitrogen and sulfur as heteroatoms[J].MOLECULES,2010,15(04):2246-2256. |
[3] | Xu Z C;Liu X;Pan J;Spring D R .Coumarin-derived transformable fluorescent sensor for Zn2+[J].Chemical Communications,2012,48(39):4764-4766. |
[4] | Ray, D.;Nag, A.;Jana, A.;Goswami, D.;Bharadwaj, P.K. .Coumarin derived chromophores in the donor-acceptor-donor format that gives fluorescence enhancement and large two-photon activity in presence of specific metal ions[J].Inorganica Chimica Acta,2010(12):2824-2832. |
[5] | Wolfbeis O S .Synthesis and properties of some new hydroxy substituted coumarin derived laser-dyes[J].Monatshefte fur Chemie,1978,109(06):1413-1421. |
[6] | U.S. Raikar;V.B. Tangod;S.R. Mannopantar;B.M. Mastiholi .Ground and excited state dipole moments of coumarin 337 laser dye[J].Optics Communications: A Journal Devoted to the Rapid Publication of Short Contributions in the Field of Optics and Interaction of Light with Matter,2010(21):4289-4292. |
[7] | Wojciech Czajkowski;Mariola Kazmierska .Coumarin-derived fluorescent dyes[J].Przemysl Chemiczny,2002(3):177-180. |
[8] | Hwan Myung Kim;Pil Rye Yang;Mun Sik Seo;Jae-Sung Yi;Jin Hee Hong;Seung-Joon Jeon;Young-Gyu Ko;Kyoung J. Lee;Bong Rae Cho .Magnesium Ion Selective Two-Photon Fluorescent Probe Based on a Benzo[h]chromene Derivative for in Vivo Imaging[J].The Journal of Organic Chemistry,2007(6):2088-2096. |
[9] | Chen, J.;Liu, W.;Ma, J.;Xu, H.;Wu, J.;Tang, X.;Fan, Z.;Wang, P. .Synthesis and properties of fluorescence dyes: Tetracyclic pyrazolo[3,4- b]Pyridine-based coumarin chromophores with intramolecular charge transfer character[J].The Journal of Organic Chemistry,2012(7):3475-3482. |
[10] | Eaton D F .Reference materials for fluorescence measurement[J].Pure and Applied Chemistry,1988,60(07):1107-1114. |
[11] | Magde D;Rojas G E;Seybold P G .Solvent dependence of the fluorescence lifetimes of xanthene dyes[J].Photochemistry and Photobiology,1999,70(05):737-744. |
[12] | Chunyan Du;Jianming Chen;Yunlong Guo;Kun Lu;Shanghui Ye;Jian Zheng;Yunqi Liu;Zhigang Shuai;Gui Yu .Dicyanovinyl Heterotetracenes: Synthesis, Solid-State Structures, andPhotophysical Properties[J].The Journal of Organic Chemistry,2009(19):7322-7327. |
[13] | Reichardr C .Solvatochromic dyes as solvent polarity indicators[J].Chemical Reviews,1994,94(08):2319-2358. |
[14] | Teale F W J .Principles of fluorescence spectroscopyLakowicz,Jr[J].NATURE,1984,307(5950):486-486. |
[15] | Raju B B .Photophysical properties of ground-state twisted bicoumarins[J].Journal of Physical Chemistry A,1997,101(06):981-987. |
[16] | Schneide F;Lippert E .Electron spectra and electron structure of 9,9'-dianthryl[J].Berichte Der Bunsen-Gesellscha ft Fiir Physikalische Chemie,1968,72(9-10):1155-1160. |
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