将二苯二硫醚作为硫源与1-甲基-2-苯基吲哚反应合成了含杂原子环的硫醚类化合物,然后再与二芳基碘三氟甲磺酸(鎓)盐反应,合成了一种新的芳基硫(鎓)盐.采用1 HNMR、MS等技术对目标化合物进行了表征,并确定了最佳反应条件.在硫醚类化合物与二芳基碘三氟甲磺酸(鎓)盐的摩尔比为1∶1.2,催化剂为CuI/Cu,溶剂为1,1,2,2-四氯乙烷的反应条件下,目标化合物的产率达到了62.0％.同时,对这类结构的芳基硫(鎓)盐进行了紫外光固化性能测试,发现其能够在紫外光固化体系中作为阳离子光引发剂得到应用.
参考文献
| [1] | Alcon, N;Tolosa, A;Rodriguez, MT;Moreno, C .Development of photoluminescent powder coatings by UV curing process[J].Progress in Organic Coatings: An International Review Journal,2010(2):92-94. |
| [2] | E. Van Hoeck;T. De Schaetzen;C. Pacquet .Analysis of benzophenone and 4-methylbenzophenone in breakfast cereals using ultrasonic extraction in combination with gas chromatography-tandem mass spectrometry (GC-MS~n)[J].Analytica chimica acta,2010(1):55-59. |
| [3] | Mariani A;Bidali S;Fiori S;Sangermano M;Malucelli G;Bongiovann R;Priola A .UV-ignited frontal polymerization of an epoxy resin[J].Journal of Polymer Science, Part A. Polymer Chemistry,2004(9):2066-2072. |
| [4] | Nason C;Roper T;Hoyle C;Pojman JA .UV-Induced frontal polymerization of multifunctional (meth)acrylates[J].Macromolecules,2005(13):5506-5512. |
| [5] | 付文,刘安华,李建雄,王丽.快速光固化用阳离子光引发剂研究进展[J].热固性树脂,2012(05):69-74. |
| [6] | 张变香,魏保利.紫外阳离子光引发剂及其发展动态[J].中国涂料,2011(04):31-35,54. |
| [7] | 周健,张秋禹,张和鹏,刘清,王为强,周艳阳.鎓盐类阳离子光引发剂的研究进展[J].材料导报,2011(01):16-21. |
| [8] | 张洪,李建雄,刘安华.阳离子光引发剂敏化的研究进展[J].影像科学与光化学,2013(01):69-78. |
| [9] | 钟彦,王新伟,王顺花,冯利邦,李菲菲.鎓盐类阳离子聚合光引发剂的研究进展[J].信息记录材料,2010(02):28-34. |
| [10] | 黄强,熊万斌,姜厚友,刘晓亚,陈明清,杨成.新型阳离子光引发剂[4-（2-羟基-3-丁氧基-1-丙氧基）苯基]苯碘鎓-六氟锑酸盐的合成及光敏性能的研究[J].感光科学与光化学,2006(01):61-66. |
| [11] | Hironori Matsushima;Sukhendu Hait;Qin Li;Hui Zhou;Masamitsu Shirai;Charles E. Hoyle .Non-extractable photoinitiators based on thiol-functionalized benzophenones and thioxanthones[J].European Polymer Journal,2010(6):1278-1287. |
| [12] | Du H A;Tang R Y;Li J H;Zhang X G .Iron-facilitated iodine-mediated electrophilic annulation of N,N-dimethyl2 alkynylanilines with disulfides or diselenides[J].Advanced Synthesis & Catalysis,2011,353(14):2739-2748. |
| [13] | 张变香,常姣,杨祺,吴群.S-苯并噻吩盐的合成的方法及其反应的研究进展[J].有机化学,2012(06):1150-1156. |
| [14] | Phipps RJ;Grimster NP;Gaunt MJ .Cu(II)-Catalyzed direct and site-selective arylation of indoles under mild conditions[J].Journal of the American Chemical Society,2008(26):8172-8174. |
| [15] | 聂俊,何勇,孙梦洲.紫外阳离子光固化研究进展[J].涂料技术与文摘,2007(10):1-4,9. |
| [16] | Radoslaw Podsiadly .12H-Quinoxalino[2,3-b][1,4]benzothiazine derivatives as novel visible photosensitizers in cationic photopolymerization[J].Journal of Photochemistry and Photobiology, A. Chemistry,2009(2/3):147-153. |
| [17] | Chen Y;Cho CH;Larock RC .A Novel Synthetic Route to 3-Sulfenyl- and 3-Selenylindoles by n-BU4NI-Induced Electrophilic Cyclization[J].Organic letters,2009(1):173-176. |
| [18] | Kumar P P;Reddy Y D;Reddy Ch;V R,Devi B R,Dubey P K .Dubey indium chloride:a versatile Lewis acid catalyst for the synthesis of 3-sulfenylindoles[J].Journal of Sulfur Chemistry,2014,35(04):356361. |
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