赤泥是氧化铝工业生产过程中产生的高碱性废弃物,综合利用难度大,外排赤泥以堆存为主, 赤泥堆场的环境安全问题正严重威胁氧化铝工业的可持续发展.赤泥资源化利用是当前环境科学与工程领域的研究热点,在Pb、Cd、Zn等重金属污染环境治理领域已有较多研究,但在As污染环境治理方面的应用研究相对较少.本文在分析赤泥对As的钝化作用(吸附作用和沉淀作用)及影响因素( pH、共存离子、Eh、土壤质地等)的基础上,综述了国内外赤泥在水体和土壤As污染治理方面的研究成果,探讨了赤泥在环境修复过程中存在的环境风险,提出了赤泥在As污染环境治理研究方面应关注的问题以及未来的重点研究方向.
Bauxite residue ( Red mud) is an alkaline waste byproduct generated by the extraction of alumina from bauxite. Disposal and storage of the vast amounts of bauxite residue are an increasing environmental problem. The appropriate management of bauxite residue is receiving a global concern following the utilization of bauxite residue for environmental materials. There are numerous studies on the contamination remediation of Pb, Cd, Zn and other heavy metal by bauxite residues but fewer studies on the application of bauxite residue on As contamination. The mechanisms and influence factors in the application of bauxite residue on As contamination remediation were discussed. The research progress in recent years on the application of bauxite residue on As contaminated wastewater and soil was summarized. The environment risk in the application of bauxite residue on As contamination was analyzed. In addition, the problems in the process of bauxite residue application on As contamination were analyzed and the development trend of future studies was put forward.
参考文献
| [1] | Wanchao Liu;Jiakuan Yang;Bo Xiao.Application Of Bayer Red Mud For Iron Recovery And Building Material Production From Alumosilicate Residues[J].Journal of hazardous materials,20091(1):474-478. |
| [2] | G. Power;M. Grafe;C. Klauber.Bauxite residue issues: I. Current management, disposal and storage practices[J].Hydrometallurgy,20111/2(1/2):33-45. |
| [3] | 范美蓉;罗琳;廖育林;杨海君;田杰;夏海.赤泥在土壤重金属污染治理和农业生产中的应用[J].土壤通报,2010(06):1531-1536. |
| [4] | Shuo Qin;Bolin Wu.Effect of self-glazing on reducing the radioactivity levels of red mud based ceramic materials[J].Journal of hazardous materials,2011:269-274. |
| [5] | L Perez-Villarejo;F.A. Corpas-Iglesias;S. Martinez-Martinez;R. Artiaga;J. Pascual-Cosp.Manufacturing new ceramic materials from clay and red mud derived from the aluminium industry[J].Construction and Building Materials,2012:656-665. |
| [6] | Xiaoming Liu;Na Zhang.Structural investigation relating to the cementitious activity of bauxite residue - Red mud[J].Cement and Concrete Research,20118(8):847-853. |
| [7] | C. Laguna;F. Gonzalez;C. Garcia-Balboa;A. Ballester;M.L. Blazquez;J.A. Munoz.Bioreduction of iron compounds as a possible clean environmental alternative for metal recovery[J].Minerals Engineering,20111(1):10-18. |
| [8] | Abhilash;Shivendra Sinha;Manish Kumar Sinha.Extraction of lanthanum and cerium from Indian red mud[J].International Journal of Mineral Processing,2014:70-73. |
| [9] | Liu, Yanju;Naidu, Ravi.Hidden values in bauxite residue (red mud): Recovery of metals[J].Waste Management,201412(12):2662-2673. |
| [10] | Liu, Wanchao;Chen, Xiangqing;Li, Wangxing;Yu, Yanfen;Yan, Kun.Environmental assessment, management and utilization of red mud in China[J].Journal of cleaner production,2014Dec.1(Dec.1):606-610. |
| [11] | Sneha Samal;Ajoy K. Ray;Amitava Bandopadhyay.Proposal for resources, utilization and processes of red mud in India — A review[J].International Journal of Mineral Processing,2013:43-55. |
| [12] | Richard N. Collins;Malcolm W. Clark;Timothy E. Payne.Solid phases responsible for Mn~(-11), Cr~(III), Co~(II), Ni, Cu~(II) and Zn immobilization by a modified bauxite refinery residue (red mud) at pH 7.5[J].Chemical engineering journal,2014:419-429. |
| [13] | Hayrunnisa Nadaroglu;Ekrem Kalkan;Nazan Demir.Removal of copper from aqueous solution using red mud[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,20101/3(1/3):90-95. |
| [14] | Sally Brown;Barbara Christensen;Enzo Lombi;Mike McLaughlin;Steve McGrath;Jan Colpaert;Jaco Vangronsveld.An inter-laboratory study to test the ability of amendments to reduce the availability of Cd, Pb, and Zn in situ[J].Environmental Pollution,20051(1):34-45. |
| [15] | Viktoria Feigl;Attila Anton;Nikolett Uzigner;Katalin Gruiz.Red Mud as a Chemical Stabilizer for Soil Contaminated with Toxic Metals[J].Water, air and soil pollution,20123(3):1237-1247. |
| [16] | Vinod K. Gupta;Saurabh Sharma.Removal of cadmium and zinc from aqueous solutions using red mud[J].Environmental Science & Technology: ES&T,200216(16):3612-3617. |
| [17] | In situ stabilization of cadmium-, lead-, and zinc-contaminated soil using various amendments[J].Chemosphere: Environmental toxicology and risk assessment,20098(8):1069. |
| [18] | I. Smiciklas;S. Smiljanic;A. Peric-Grujic.Effect of acid treatment on red mud properties with implications on Ni(II) sorption and stability[J].Chemical engineering journal,2014:27-35. |
| [19] | Laura Santona;Paola Castaldi;Pietro Melis.Evaluation of the interaction mechanisms between red muds and heavy metals[J].Journal of hazardous materials,20062(2):324-329. |
| [20] | 杨俊兴;陈世宝;郭庆军.赤泥在重金属污染治理中的应用研究进展[J].生态学杂志,2013(7):1937-1944. |
| [21] | Yong Liu;Chuxia Lin;Yonggui Wu.Characterization of red mud derived from a combined Bayer Process and bauxite calcination method[J].Journal of hazardous materials,20071/2(1/2):255-261. |
| [22] | Akln Akinci;Recep Artir.Characterization of trace elements and radionuclides and their risk assessment in red mud[J].Materials Characterization,20084(4):417-421. |
| [23] | Janos Somlai;Viktor Jobbagy;Jozsef Kovacs;Sandor Tarjan;Tibor Kovacs.Radiological aspects of the usability of red mud as building material additive[J].Journal of hazardous materials,20083(3):541-545. |
| [24] | C. Klauber;M. Grafe;G. Power.Bauxite residue issues: II. options for residue utilization[J].Hydrometallurgy,20111/2(1/2):11-32. |
| [25] | 刘东燕;侯龙;王平.常见赤泥的物化特性及综合利用研究[J].材料导报,2012(z1):310-312,348. |
| [26] | 孙媛媛;曾希柏;白玲玉;王进进;李莲芳;苏世鸣;王亚男;段然;吴翠霞.双金属氧化物和改性赤泥对潮褐土中外源砷的调控研究[J].农业环境科学学报,2013(8):1545-1551. |
| [27] | Yanzhong Li;Changjun Liu;Zhaokun Luan;Xianjia Peng;Chunlei Zhu;Zhaoyang Chen;Zhongguo Zhang;Jinghua Fan;Zhiping Jia.Phosphate removal from aqueous solutions using raw and activated red mud and fly ash[J].Journal of hazardous materials,20061(1):374-383. |
| [28] | 韩玉芳;杨久俊;王晓;李建伟.烧结法和拜耳法赤泥的基本特性对比及利用价值研究[J].材料导报,2011(22):122-125. |
| [29] | M. Grafe;G. Power;C. Klauber.Bauxite residue issues: III. Alkalinity and associated chemistry[J].Hydrometallurgy,20111/2(1/2):60-79. |
| [30] | Liu YanJu;Ravi Naidu;Ming Hui.Red mud as an amendment for pollutants in solid and liquid phases.[J].Geoderma: An International Journal of Soil Science,20111/2(1/2):1-12. |
| [31] | Michael Komarek;Ales Vanek;Vojtech Ettler.Chemical stabilization of metals and arsenic in contaminated soils using oxides - A review[J].Environmental Pollution,2013Jan.(Jan.):9-22. |
| [32] | Jurate Kumpiene;Anders Lagerkvist;Christian Maurice.Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments A review[J].Waste Management,20081(1):215-225. |
| [33] | Lombi E.;Zhao FJ.;Zhang GY.;Sun B.;Fitz W.;Zhang H.;McGrath SP..In situ fixation of metals in soils using bauxite residue: chemical assessment[J].Environmental Pollution,20023(3):435-443. |
| [34] | Palmer, S.J.;Nothling, M.;Bakon, K.H.;Frost, R.L..Thermally activated seawater neutralised red mud used for the removal of arsenate, vanadate and molybdate from aqueous solutions[J].Journal of Colloid and Interface Science,20101(1):147-154. |
| [35] | Lee, Sang-Hwan;Kim, Eui Young;Park, Hyun;Yun, Jihoon;Kim, Jeong-Gyu.In situ stabilization of arsenic and metal-contaminated agricultural soil using industrial by-products[J].Geoderma: An International Journal of Soil Science,20111/2(1/2):1-7. |
| [36] | Veronika Dutre;Carlo Vandecasteele;Stefan Opdenakker.Oxidation of arsenic bearing fly ash as pretreatment before solidification[J].Journal of hazardous materials,19993(3):205-215. |
| [37] | Carlo Vandecasteele;Veroniek Dutre;Daneel Geysen.Solidification/stabilisation of arsenic bearing fly ash from the metalurgical industry. Immobilisation mechanism of arsenic[J].Waste Management,20022(2):143-146. |
| [38] | Ya-Feng Zhou;Richard J. Haynes.A Comparison of Water Treatment Sludge and Red Mud as Adsorbents of As and Se in Aqueous Solution and Their Capacity for Desorption and Regeneration[J].Water, air and soil pollution,20129(9):5563-5573. |
| [39] | H. Soner Altundogan;Sema Altundogan;Fikret Tumen.Arsenic removal from aqueous solutions by adsorption on red mud[J].Waste Management,20008(8):761-767. |
| [40] | H. Soner Altundogan;Sema Altundogan;Fikret Tumen.Arsenic adsorption from aqueous solutions by activated red mud[J].Waste Management,20023(3):357-363. |
| [41] | Study of sorption processes and FT-IR analysis of arsenate sorbed onto red muds (a bauxite ore processing waste)[J].Journal of hazardous materials,20101/3(1/3):172. |
| [42] | Anna F. Bertocchi;Marcello Ghiani;Roberto Peretti;Antonio Zucca.Red mud and fly ash for remediation of mine sites contaminated with As, Cd, Cu, Pb and Zn[J].Journal of hazardous materials,20061/3(1/3):112-119. |
| [43] | Shuwu Zhang;Changjun Liu;Zhaokun Luan;Xianjia Peng;Haijing Ren;Jun Wang.Arsenate removal from aqueous solutions using modified red mud[J].Journal of hazardous materials,20082(2):486-492. |
| [44] | VESNA L. VUKASINOVIC-PESIC;VLADANA N. RAJAKOVIC-OGNJANOVIC;NADA Z. BLAGOJEVIC.Enhanced Arsenic Removal from Water by Activated Red Mud Based on Hydrated Iron(III) and Titan(IV) Oxides[J].Chemical Engineering Communications,20127/9(7/9):849-864. |
| [45] | Utilization of activated CO_2-neutralized red mud for removal of arsenate from aqueous solutions[J].Journal of hazardous materials,20101/3(1/3):1007. |
| [46] | Zuleyha Ozlem Kocabas;Yuda Yurum.Kinetic Modeling of Arsenic Removal from Water by Ferric Ion Loaded Red Mud[J].Separation Science and Technology,201113/16(13/16):2380-2390. |
| [47] | X.L. Yan;L.Y. Lin;X.Y. Liao;W.B. Zhang;Y. Wen.Arsenic stabilization by zero-valent iron, bauxite residue, and zeolite at a contaminated site planting Panax notoginseng[J].Chemosphere: Environmental toxicology and risk assessment,20134(4):661-667. |
| [48] | Giovanni Garau;Margherita Silvetti;Salvatore Deiana;Pietrino Deiana;Paola Castaldi.Long-term influence of red mud on As mobility and soil physico-chemical and microbial parameters in a polluted sub-acidic soil[J].Journal of hazardous materials,20112/3(2/3):1241-1248. |
| [49] | 郝晓伟;黄益宗;崔岩山;胡莹;刘云霞.赤泥和骨炭对污染土壤As化学形态及其生物可给性的影响[J].环境化学,2010(3):383-387. |
| [50] | Xianjia Peng;Chuan Liang;Li Shi.Immobilization of phosphorus, copper, zinc and arsenic in swine manure by activated red mud[J].Environmental earth sciences,20145(5):2005-2014. |
| [51] | 黄益宗;郝晓伟.赤泥、骨炭和石灰对玉米吸收积累As、Pb和Zn的影响[J].农业环境科学学报,2013(3):456-462. |
| [52] | Namin Koo;Sang-Hwan Lee;Jeong-Gyu Kim.Arsenic mobility in the amended mine tailings and its impact on soil enzyme activity[J].Environmental geochemistry and health,20123(3):337-348. |
| [53] | Gray CW;Dunham SJ;Dennis PG;Zhao EJ;McGrath SP.Field evaluation of in situ remediation of a heavy metal contaminated soil using lime and red-mud[J].Environmental Pollution,20063(3):530-539. |
| [54] | Shaobin Wang;H.M.Ang;M.O.Tade;Ang;M;O;Tade.Novel Applications Of Red Mud As Coagulant, Adsorbent And Catalyst For Environmentally Benign Processes[J].Chemosphere: Environmental toxicology and risk assessment,200811(11):1621-1635. |
| [55] | Claudia Brunori;Carlo Cremisini;Paolo Massanisso;Valentina Pinto;Leonardo Torricelli.Reuse of a treated red mud bauxite waste: studies on environmental compatibility[J].Journal of hazardous materials,20051(1):55-63. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%