环境友好型材料的合成已成为当前研究的热点.纳米零价铁因卓越还原性能应用潜力巨大,纳米铁颗粒的绿色合成技术可避免污染并降低成本,提高修复效率.本文介绍了纳米铁合成工艺的绿色化进展,其中包括采用各类原始材料新型合成方法、合成工艺条件选择和制备产物的生成过程,经济性分析等.另外还比较了纳米铁颗粒绿色分散和负载改性过程中工艺试验参数、收率和选择性等,并对绿色纳米零价铁技术的工程应用和关键问题进行讨论,以及未来发展趋势进行展望.
参考文献
| [1] | 程荣;王建龙;张伟贤.纳米金属铁降解有机卤化物的研究进展[J].化学进展,2006(1):93-99. |
| [2] | Nadagouda MN;Varma RS.Green and controlled synthesis of gold and platinum nanomaterials using vitamin B-2: density-assisted self-assembly of nanospheres, wires and rods[J].Green chemistry,20066(6):516-518. |
| [3] | Mittal, Amit Kumar;Chisti, Yusuf;Banerjee, Uttam Chand.Synthesis of metallic nanoparticles using plant extracts[J].Biotechnology Advances: An International Review Journal,20132(2):346-356. |
| [4] | Oxana V. Kharissova;H.V. Rasika Dias;Boris I. Kharisov.The greener synthesis of nanoparticles[J].Trends in biotechnology,20134(4):240-248. |
| [5] | Huang, Lanlan;Luo, Fang;Chen, Zuliang;Megharaj, Mallavarapu;Naidu, Ravendra.Green synthesized conditions impacting on the reactivity of Fe NPs for the degradation of malachite green[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2015Pt.1(Pt.1):154-159. |
| [6] | Njagi, E.C.;Huang, H.;Stafford, L.;Genuino, H.;Galindo, H.M.;Collins, J.B.;Hoag, G.E.;Suib, S.L..Biosynthesis of iron and silver nanoparticles at room temperature using aqueous sorghum bran extracts[J].Langmuir: The ACS Journal of Surfaces and Colloids,20111(1):264-271. |
| [7] | Lanlan Huang;Xiulan Weng;Zuliang Chen;Mallavarapu Megharaj;Ravendra Naidu.Green synthesis of iron nanoparticles by various tea extracts: Comparative study of the reactivity[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2014:295-301. |
| [8] | Prasad, Kumar Suranjit;Gandhi, Pooja;Selvaraj, Kaliaperumal.Synthesis of green nano iron particles (GnIP) and their application in adsorptive removal of As(III) and As(V) from aqueous solution[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2014Oct.30(Oct.30):1052-1059. |
| [9] | Laufenberg G.;Kunz B.;Nystroem M..Transformation of vegetable waste into value added products: (A) the upgrading concept; (B) practical implementation [Review][J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,20032(2):167-198. |
| [10] | Xin Zhang;Shen Lin;Xiao-Qiao Lu.Removal of Pb(II) from water using synthesized kaolin supported nanoscale zero-valent iron[J].Chemical engineering journal,20103(3):243-248. |
| [11] | Tingyi Liu;Zhong-Liang Wang;Xiaoxing Yan.Removal of mercury (II) and chromium (VI) from wastewater using a new and effective composite: Pumice-supported nanoscale zero-valent iron[J].Chemical engineering journal,2014:34-40. |
| [12] | Wang, X.;Zhu, M.;Liu, H.;Ma, J.;Li, F..Modification of Pd-Fe nanoparticles for catalytic dechlorination of 2,4-dichlorophenol[J].Science of the Total Environment,2013:157-167. |
| [13] | 和婧;王向宇;王培;刘坤乾.PAA改性纳米铁强化还原降解水中亚甲基蓝[J].环境科学,2015(3):980-988. |
| [14] | Sun YP;Li XQ;Zhang WX;Wang HP.A method for the preparation of stable dispersion of zero-valent iron nanoparticles[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,20071/3(1/3):60-66. |
| [15] | 吴智威 .改性竹炭负载Fe/Cu对废水中氯霉素去除研究[D].华中科技大学,2012. |
| [16] | 周筱菲;刘文莉;朱剑炯;宋健;林梦露;孙妙善;陈嘉都.竹炭负载纳米级零价铁去除水中的甲基橙[J].广东化工,2013(14):19-20. |
| [17] | Yanmei Zhou;Bin Gao;Andrew R. Zimmerman;Hao Chen;Ming Zhang;Xinde Cao.Biochar-supported zerovalent iron for removal of various contaminants from aqueous solutions[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2014:538-542. |
| [18] | Chun Y;Sheng GY;Chiou CT;Xing BS.Compositions and sorptive properties of crop residue-derived chars[J].Environmental Science & Technology: ES&T,200417(17):4649-4655. |
| [19] | Zhengguo Song;Fei Lian;Zhihong Yu.Synthesis and characterization of a novel MnO_x-loaded biochar and its adsorption properties for Cu~(2+) in aqueous solution[J].Chemical engineering journal,2014:36-42. |
| [20] | Yan, Jingchun;Han, Lu;Gao, Weiguo;Xue, Song;Chen, Mengfang.Biochar supported nanoscale zerovalent iron composite used as persulfate activator for removing trichloroethylene[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2015:269-274. |
| [21] | Inyang, M.;Gao, B.;Yao, Y.;Xue, Y.;Zimmerman, A.R.;Pullammanappallil, P.;Cao, X..Removal of heavy metals from aqueous solution by biochars derived from anaerobically digested biomass[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,20121(1):50-56. |
| [22] | Ming Zhang;Bin Gao.Removal of arsenic, methylene blue, and phosphate by biochar/AlOOH nanocomposite[J].Chemical engineering journal,2013:286-292. |
| [23] | Devi, Parmila;Saroha, Anil K..Simultaneous adsorption and dechlorination of pentachlorophenol from effluent by Ni-ZVI magnetic biochar composites synthesized from paper mill sludge[J].Chemical engineering journal,2015:195-203. |
| [24] | 高国振;李金轩;李小燕;李寻;王长柏;贺彩婷.纳米零价铁/玉米淀粉的制备及其对pb2+的吸附[J].化工环保,2014(4):376-379. |
| [25] | Gustavo Lopez-Tellez;Carlos E. Barrera-Diaz;Patricia Balderas-Hernandez.Removal of hexavalent chromium in aquatic solutions by iron nanoparticles embedded in orange peel pith[J].Chemical engineering journal,20112(2):480-485. |
| [26] | Man Zhang;Deborah B. Bacik;Christopher B. Roberts;Dongye Zhao.Catalytic hydrodechlonnation of tnchloroethylene in water with supported CMC-stabilized palladium nanoparticles[J].Water research: A journal of the international water association,201311(11):3706-3715. |
| [27] | FENG HE;DONGYE ZHAO.Manipulating the Size and Dispersibility of Zerovalent Iron Nanoparticles by Use of Carboxymethyl Cellulose Stabilizers[J].Environmental Science & Technology: ES&T,200717(17):6216-6221. |
| [28] | 吉毅;李宗石;乔卫红.瓜尔胶的化学改性[J].日用化学工业,2005(2):111-114. |
| [29] | Tiraferri A;Chen KL;Sethi R;Elimelech M.Reduced aggregation and sedimentation of zero-valent iron nanoparticles in the presence of guar gum[J].Journal of Colloid and Interface Science,20081/2(1/2):71-79. |
| [30] | Kuang, Ye;Du, Jianhua;Zhou, Rongbing;Chen, Zuliang;Megharaj, Mallavarapu;Naidu, Ravendra.Calcium alginate encapsulated Ni/Fe nanoparticles beads for simultaneous removal of Cu (II) and monochlorobenzene[J].Journal of Colloid and Interface Science,2015:85-91. |
| [31] | FENG HE;DONGYE ZHAO.Preparation and Characterization of a New Class of Starch-Stabilized Bimetallic Nanoparticles for Degradation of Chlorinated Hydrocarbons in Water[J].Environmental Science & Technology: ES&T,20059(9):3314-3320. |
| [32] | Wang, Xiangyu;Le, Lan;Alvarez, Pedro J. J.;Li, Fang;Liu, Kunqian.Synthesis and characterization of green agents coated Pd/Fe bimetallic nanoparticles[J].Journal of the Taiwan Institute of Chemical Engineers,2015:297-305. |
| [33] | Mohan Basnet;Subhasis Ghoshal;Nathalie Tufenkji.Rhamnolipid Biosurfactant and Soy Protein Act as Effective Stabilizers in the Aggregation and Transport of Palladium-Doped Zerovalent Iron Nanoparticles in Saturated Porous Media[J].Environmental Science & Technology: ES&T,201323(23):13355-13364. |
| [34] | Pijit Jiemvarangkul;Wei-xian Zhang;Hsing-Lung Lien.Enhanced transport of polyelectrolyte stabilized nanoscale zero-valent iron (nZVI) in porous media[J].Chemical engineering journal,20112/3(2/3):482-491. |
| [35] | Wang, Xiangyu;Wang, Pei;Ma, Jun;Liu, Huiling;Ning, Ping.Synthesis, characterization, and reactivity of cellulose modified nano zero-valent iron for dye discoloration[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2015Aug.1(Aug.1):57-66. |
| [36] | Wang, Xiangyu;Li, Fang;Yang, Jiacheng.Polyvinyl pyrrolidone-modified Pd/Fe nanoparticles for enhanced dechlorination of 2,4-dichlorophenal[J].Desalination and water treatment: Science and engineering,201440/42(40/42):7925-7936. |
| [37] | Cao, J.;Xu, R.;Tang, H.;Tang, S.;Cao, M..Synthesis of monodispersed CMC-stabilized Fe-Cu bimetal nanoparticles for in situ reductive dechlorination of 1, 2, 4-trichlorobenzene[J].Science of the Total Environment,201111(11):2336-2341. |
| [38] | Hwa-Young Shin;Naresh Singhal;Jae-Woo Park.Regeneration of iron for trichloroethylene reduction by Shewanella alga BrY[J].Chemosphere: Environmental toxicology and risk assessment,20076(6):1129-1134. |
| [39] | Luna, M.;Gastone, F.;Tosco, T.;Sethi, R.;Velimirovic, M.;Gemoets, J.;Muyshondt, R.;Sapion, H.;Klaas, N.;Bastiaens, L..Pressure-controlled injection of guar gum stabilized microscale zerovalent iron for groundwater remediation[J].Journal of contaminant hydrology,2015Oct.(Oct.):46-58. |
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