采用反向滴定沉淀法合成Bi2Cu01V09O5.35(BICUVOX.10)纳米粉体材料.通过热重-差热分析和X射线衍射研究BICUVOX.10粉料的相形成过程和相特性.结果表明,样品在500 ℃以上4h退火后已完全形成单一的室温稳定四方γ导电相.用X射线多功能电子能谱对BICUVOX.10粉末的组分分布及化学态进行分析:样品中Bi、V、Cu元素的摩尔比约为20:9:1.透射电镜对样品颗粒分散性的研究表明:一定量表面活性剂PEG4000(聚乙二醇4000)的添加可有效提高纳米BICUVOX.10粉体颗粒的分散性；当PEG4000添加量为5％时,BICUVOX.10纳米颗粒产物的分散性最佳.
参考文献
| [1] | Abraham F;Boivin J C;Mairesse G et al.The BIMEVOX series-a new family of high performances oxide ion conductors[J].Solid-State Ionicis,1990,40/41(02):934-937. |
| [2] | Boivin JC.;Mairesse G. .Recent material developments in fast oxide ion conductors [Review][J].Chemistry of Materials,1998(10):2870-2888. |
| [3] | Goodenough J B .Ceramic technology-oxide-ion conductors by design[J].Nature,2000,404:821-823. |
| [4] | S. Lazure;Ch. Vernochet;R.N. Vannier;G. Nowogrocki;G. Mairesse .Composition dependence of oxide anion conduction in the BIMEVOX family[J].Solid state ionics,1996(1/4):117-123. |
| [5] | H.S. Cho;G. Sakai;K. Shimanoe;N. Yamazoe .Preparation of BiMeVO_x (Me = Cu, Ti, Zr, Nb, Ta) compounds as solid electrolyte and behavior of their oxygen concentration cells[J].Sensors and Actuators, B. Chemical,2005(2):307-314. |
| [6] | M.C.Steil and P.Labrune .BICOVOX: sintering and grain size dependence of the electrical properties[J].Journal of the European Ceramic Society,1999(6/7):815-818. |
| [7] | Hervoches CH;Steil MC;Muccillo R .Synthesis by the polymeric precursor technique of Bi2Co0.1V0.9O5.35 and electrical properties dependence on the crystallite size[J].Solid state sciences,2004(2):173-177. |
| [8] | Bhattacharya A K;Mallick K K;Thomas P A .Low-temperature synthesis of a bismuth vanadium-oxide isomorphous with gamma-Bi4V2O11[J].Solid State Communications,1994,91(05):357-360. |
| [9] | Sheng-Yong Yao;Zhao-Hui Xie .Deagglomeration treatment in the synthesis of doped-ceria nanoparticles via coprecipitation route[J].Journal of Materials Processing Technology,2007(1/3):54-59. |
| [10] | 逯庆国,李明利,周宇松,周春江,刘正伟.W-Ni-Fe系纳米复合粉体的制备工艺研究[J].兵器材料科学与工程,2011(02):90-93. |
| [11] | Beg S;Al-Alas A;Niyazi A S et al.Study on structural and electrical properties of layered perovskite-type oxide-ion conductor[J].Materials Chemistry and Physics,2010,124(01):305-311. |
| [12] | R.S. Joshi;R.K. Nimat;S.H. Pawar .Synthesis of fuel cell grade Bi_2Co_(0.1)V_(0.9)O_(5.35) solid electrolyte thin films[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):461-465. |
| [13] | M.H. Paydar;A.M. Hadian;K. Shiamnoe .The effects of zirconia addition on sintering behavior, mechanical properties and ion conductivity of BICUVOX. 1 material[J].Journal of the European Ceramic Society,2001(10/11):1825-1829. |
| [14] | Li Zhang;Dairong Chen;Xiuling Jiao .Monoclinic Structured BiVO4 Nanosheets:Hydrothermal Preparation,Formation Mechanism,and Coloristic and Photocatalytic Properties[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(6):2668-2673. |
| [15] | Guisheng Li;Dieqing Zhang;Jimmy C. Yu .Ordered Mesoporous BiVO4 through Nanocasting: A Superior Visible Light-Driven Photocatalyst[J].Chemistry of Materials: A Publication of the American Chemistry Society,2008(12):3983-3992. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%