欢迎登录材料期刊网

材料期刊网

高级检索

采用两步法成功构筑SnO2/还原氧化石墨烯/聚苯胺(SnO2/RGO/PANI)三元复合材料.首先制备出均匀分散的SnO2/还原氧化石墨烯(SnO2/RGO)二元复合物,然后再以二元复合物为载体,通过苯胺(An)单体的化学氧化聚合获得终端产物.利用傅里叶红外光谱(FT-IR)、X射线衍射(XRD)和场发射扫描电镜(FESEM)对复合材料的结构和形貌等物理性质进行表征,利用循环伏安测试、恒电流充放电测试和交流阻抗测试对复合材料的电化学电容性能进行研究,并讨论了PANI的含量对复合材料的结构和性能的影响.结果表明,所合成的三元复合材料的比电容随PANI含量的增加而增大,最大达到424.8F/g,其电容性能的增强源于SnO2、RGO与PANI三者的相互协同作用.

参考文献

[1] Chemical Reviews Group .What Are Batteries,Fuel Cells,and Supercapacitors?[J].Chemical Reviews,2004(10):4245-4269.
[2] 章仁毅,张小燕,樊华军,何品刚,方禹之.基于碳纳米管的超级电容器研究进展[J].应用化学,2011(05):489-499.
[3] Hou, Y.;Cheng, Y.;Hobson, T.;Liu, J. .Design and synthesis of hierarchical MnO_2 nanospheres/carbon nanotubes/conducting polymer ternary composite for high performance electrochemical electrodes[J].Nano letters,2010(7):2727-2733.
[4] Sivakkumar S R;Ko J M;Kim D Y et al.Performance evaluation of CNTS/polypyrrole/MnO2 composite electrodes for electrochemical capacitors[J].Electrochimica Acta,2007,52(25):7377.
[5] 靳瑜,陈宏源,陈名海,刘宁,李清文.碳纳米管/聚苯胺/石墨烯复合纳米碳纸及其电化学电容行为[J].物理化学学报,2012(03):609-614.
[6] Hummers W S;Offeman R E .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(06):1339.
[7] Lifeng Cui;Jian Shen;Fangyi Cheng;Zhanliang Tao;Jun Chen .SnO_2 nanoparticles@polypyrrole nanowires composite as anode materials for rechargeable lithium-ion batteries[J].Journal of Power Sources,2011(4):2195-2201.
[8] Hu Z A;Xie Y L;Wang Y X et al.Polyaniline/SnO2 nanocomposite for supercapacitor applications[J].Materials Chemistry and Physics,2009,114(2-3):990.
[9] Mi HY;Zhang XG;An SY;Ye XG;Yang SD .Microwave-assisted synthesis and electrochemical capacitance of polyaniline/multi-wall carbon nanotubes composite[J].Electrochemistry communications,2007(12):2859-2862.
[10] 姜遵群,程起林,张玲,严燕芳,李春忠.网络结构的聚苯胺-二氧化锰纳米复合材料的制备及其电化学性能[J].功能高分子学报,2011(02):158-163.
[11] Girija T C;Sangaranarayanan M V .Analysis of polyanilinebased nickel electrodes for electrochemical supercapacitors[J].Journal of Power Sources,2006,156(02):705.
[12] Ryu K S;Lee Y;Han K S et al.Electrochemical supercapacitor based on polyaniline doped with lithium salt and active carbon electrodes[J].Solid State Ionics,2004,175(1-4):765.
[13] 臧杨,郝晓刚,王忠德,张忠林,刘世斌.碳纳米管/聚苯胺/铁氰化镍复合膜的电化学共聚制备与电容性能[J].物理化学学报,2010(02):291-298.
[14] 陈洁,黄可龙,刘素琴.球形纳米Fe3O4的制备及超级电容性能研究[J].无机化学学报,2008(04):621-626.
[15] Juan Xu;Lan Gao;Jianyu Cao;Wenchang Wang;Zhidong Chen .Preparation and electrochemical capacitance of cobalt oxide (Co_3O_4) nanotubes as supercapacitor material[J].Electrochimica Acta,2010(2):732-736.
[16] Gupta V;Gupta S;Miura N .Potentiostatically deposited nanostructured CoxNi1-x layered double hydroxides as electrode materials for redox-supercapacitors[J].Journal of Power Sources,2008,175(01):680.
[17] Lin Cao;Feng Xu;Yan-Yu Liang;Hu-Lin Li .Preparation of the Novel Nanocomposite Co(OH)_2/Ultra-Stable Y Zeolite and Its Application as a Supercapacitor with High Energy Density[J].Advanced Materials,2004(20):1853-1857.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%