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采用复合电沉积方法,在碳钢表面制备了质量组成为的Fe 38.3%、W 52.7%、ZrO2-9%的Fe-W-ZrO2纳米复合镀层,研究了ZrO2纳米微粒、热处理对镀层组织和结构的影响.结果表明,弥散分布的ZrO2纳米微粒对Fe-W基质镀层的结构有明显影响,镀态下Fe-W-ZrO2纳米复合镀层内部结构致密无裂纹,呈明显非晶态结构特征;经500℃热处理后,复合镀层开始晶化析出α-Fe相,随着热处理温度升高,晶化相不断析出并长大,700℃时复合镀层晶化已基本完成,M6C型碳化物F3W3C相出现,与α-Fe相两相并存,继续加热至800%:时,F3W3C成为涂层主相.

参考文献

[1] 蒋晓飞.非晶态Fe-W合金的电沉积方法及耐蚀性能[J].腐蚀科学与防护技术,1994(04):340.
[2] 姚素薇;赵水林;任丽彬 等.非晶态Fe-W合金镀层的表面改性[J].应用化学,1995,12(04):32-35.
[3] 王峰,伊藤清,渡边澈,姚素薇.Fe-W非晶态合金镀膜技术及其最佳制备条件的研究[J].化工进展,1999(06):47-49.
[4] Donten M;Cesiulis H;Stojek Z .Electrodepositiou and properties of Ni-W,Fe-W and Fe-Ni-W amorphous alloys:a comparative study[J].Electrochimica Acta,2000,45:3389-3396.
[5] Tharamani CN;Beera P;Jayaram V;Begum NS;Mayanna SM .Studies on electrodeposition of Fe-W alloys for fuel cell applications[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(4):2031-2037.
[6] Ruan Y F;Yao S W;Kowaka M .Amorphization of electrodeposited Fe-W alloy films and electrochemical behavior[J].Journal of Non-Crystalline Solids,1990,117-118:752-755.
[7] Lidia Benea;Pier Luigi Bonora;Alberto Borello .Composite Electrodeposition to Obtain Nanostructured Coatings[J].Journal of the Electrochemical Society,2001(7):C461-C465.
[8] Mullur B;Ferke H.Studies on nanecrystalline Ni/Al2O3 films by electrolytic DC plating[J].Journal of Metastable and Nanoerystalline Materials,2000(08):476-481.
[9] Mullur B;Ferkel H .Al2O3-nanoparticle distribution in plated nickel composite films[J].Nano-Structured Materials,1998,10(08):1285-1288.
[10] Ferkel H;Mullur B;Riehe Mann W .Electrodepositian of particle strengthened nickel films[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,1997,234-236:474-476.
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