综述了正丁烷选择性氧化制顺酐VPO催化剂的制备方法和催化机理的研究进展,分析了制备过程中添加载体及助剂对催化剂性能的影响,介绍了国内外对VPO催化剂选择氧化正丁烷制顺酐反应路径的最新认识,探讨了VPO催化刺的活性住的形成机制以及V4+相与V5+相的相间协同作用,并展望了VPO催化剂未来的发展方向.
参考文献
[1] | Genti G .Vanadyl pyrop hosphate:A critical overview[J].Catalysis Today,1993,16(01):5. |
[2] | Christopher J K;Andrew B;Sujata S et al.Characterisationof variations in vanadium phosphate catalyst microstrueture with preparation route[J].Journal of Catalysis,1996,162:31. |
[3] | 温宇龙;许文.正丁烷氧化制顺酐流化床催化剂的性能[J].化学工业与工程,2003(12):426. |
[4] | 牛童;王晓来;索继栓 .VPO/SiO2催化剂的制备及性能研究[J].分子催化,1998,12(03):234. |
[5] | Marc J L;Claude C;Vincent T et al.High-yield butane to maleic anhydride direct oxidation on vanadyl pyrophosphate supported on heat conductive materials:β-SiC,Si3N4,and BN[J].Journal of Catalysis,2001,203:495. |
[6] | Wei Y N;Zhong Y W;Wei Y J et al.Comparative studies on the VPO specimen supported on mesoporous Al-con taining MCM-41 and large-pore silica[J].Applied Catalysis A:General,2003,244:265. |
[7] | Xiao C Y;Chen X et al.The novel and highly selective fumed silica-supported VPO for partial oxidation of n-butane to maleic anhydride[J].Catalysis Today,2004,93:223. |
[8] | Xiu K L;Wei J J et al.n-butane oxidation over VPO catalysts supported on SBA-15[J].Journal of Catalysis,2006,238:232. |
[9] | Xiu K L;Wei J J et al.A comparison study on the partial oxidation of n-butane and propane over VPO catalysts supported on SBA-15,MCM-41,and fumed SiO2[J].Applied Catalysis A:General,2006,306:8. |
[10] | Ru M F;Xiu J Y et al.VPO catalyst supported on H3PO4treated ZrO2 highly active for n-butane oxidation[J].Journal of Catalysis,2007,246:166. |
[11] | Hutchings G J .Efrect of promoters and reactant concentration on the selective oxidation of n-butane to maleic anhydride using vanadium phosphorus oxide catalysts[J].Applied Catalysis,1991,72:1. |
[12] | Cavani F;Colombo A;Trifiro F et al.The effect of cobalt and iron dopants on the catalytic behaviOr of V/P/O catalvsts in the selective oxidation of n-pentane to maleic and phthalic anhydrides[J].Catalysis Letters,1997,43(3-4):241. |
[13] | 周吉萍,张丰胜,沈师孔.铈和铁助剂对VPO催化剂晶格氧传递速率的改善[J].石油化工,2000(11):832. |
[14] | 周凌,李然家,李剑锋,沈师孔.用于丁烷选择性氧化制顺酐的铈锆复合钒磷氧催化剂的研究[J].催化学报,2002(01):72-76. |
[15] | 叶代启,付名利,梁红,程胜中,荣铁志,庞先燊.添加剂对共沉淀法制备的VPO催化剂的影响[J].华南理工大学学报(自然科学版),2004(01):49-55,64. |
[16] | Andr'ea M;Duarte de F et al.Vanadium phosphorns oxide catalyst modified by niobium doping for mild oxidation of n-butane to maleic anhydride[J].Journal of Catalysis,2002,208:238. |
[17] | Beatriz T;Pierini E A .Structure and properties of Cr promoted VPO catalysts[J].Materials Chemistry and Physics,2005,92:197. |
[18] | Y.H.Taufiq-Yap,Y.Kamiya,K.P.Tan.Promotional Effect of Bismuth as Dopant in Bi-Doped Vanadyl Pyrophosphate Catalysts for Selective Oxidation of n-Butane to Maleic Anhydride[J].天然气化学(英文版),2006(04):297-302. |
[19] | Kubias B;Rodemerch U et al.The reaction net work of the selective oxidation of n-butane on(VO)2P2O7 catalysts:Nature of oxygen containing intermediates[J].Catalysis Today,1996,32:243. |
[20] | 梁日忠,李英霞,陈标华,李成岳.正丁烷选择氧化过程中VPO体系的表面物种[J].分子催化,2001(02):86-90. |
[21] | 梁日忠,李英霞,李成岳,陈标华.(VO)2P2O7催化剂上正丁烷选择氧化反应路径的原位瞬态DRIFTS研究[J].光谱学与光谱分析,2004(11):1309-1314. |
[22] | Guliants V V et al.Probing polyfunctional nature of vanadylpyrophosphate cataly sts:oxidation of 16 C4 molecules[J].Journal of Molecular Catalysis A:Chemical,2001,175:227. |
[23] | Rie S;Takamasa F .Theoretical study of vanadium-catalyzed butane oxidation[J].Catalysis Today,2001,71:137. |
[24] | Grasselli R K .Fundamental principles of selective heterogeneons oxidation cataly sis[J].Topics in Catalysis,2002,21(1-3):79. |
[25] | Gai-Boyes P L .A new structural transformation mechanism in catalytic oxidation[J].Applied Catalysis,1997,53:346. |
[26] | Duvauchelle N.;Bordes E. .Influence of the nanostructure and morphology of (VO)(2)P2O7 on its catalytic reactivity[J].Catalysis Letters,1999(1/2):81-88. |
[27] | Agaskar P A;De C L;Grasselli R K .A molecular level mechanism of n-butane oxidation to maleie anhydride over vanadyl phrophosphate[J].Catalysis Letters,1994,23:339. |
[28] | 汪洋,陈丰秋,詹晓力,陈飞.多相选择氧化/氨氧化催化中活性位分离和相间协同作用[J].化学进展,2006(01):7-18. |
[29] | 邹颖楠,赵静,季伟捷,陈懿.V5+物种对钒磷氧化物催化性能的影响[J].无机化学学报,2003(05):497-500. |
[30] | 姜浩锡,李永辉,刘潇雅.丁烷氧化制顺丁烯二酸酐催化剂活性相的研究[J].化学工业与工程,2004(01):29-32. |
[31] | Volta J C .Site isolation for light hydrocarbons oxidation[J].Topics in Catalysis,2001,15(2-4):121. |
[32] | Sananés-Schulz M T;Tuel A;Hutchings G J et al.The V4+/V5+ balance as a criterion of selection of vanadium phosphorus oxide catalysts for n-butane oxidation to maleic anhydride:A proposal to explain the role of Co and Fe dopants[J].Journal of Catalysis,1997,166(02):388. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%