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采用热压成型工艺制备了导电钛酸钾晶须(PTWs)/聚丙烯(PP)复合材料,研究了晶须用量对复合材料导热性能、抗静电性能和力学性能的影响。结果表明,随着PTWs用量的增加,PTWs/PP复合材料的热导率提高、体积电阻率和摩擦静电荷下降;材料的拉伸强度、弯曲强度均随PTWs用量的增加呈先增大后减小的趋势;而熔体流动速率则呈增大趋势。当PTWs体积分数达到0.38%时,材料的热导率达到最大值0.5105 W.m-1.K-1,电阻率降低到109Ω.cm以下,满足一般抗静电材料的要求。

Conductive potassium titanate whiskers(PTWs) were used as a novel filler to prepare PTWs/ polypropylene(PP) composites by hot-press forming technology,for which the good thermally conductive and antistatic properties were obtained.The effects of PTWs content on thermal conductivity,volume resistivity,mechanical properties and formability of the PTWs/PP composites were investigated.The results show that with the increase of the PTWs content,thermal conductivity of the PTWs/PP composites increases whi1e volume resistivity decreases,besides,tensile and flexural strength of the PTWs/PP composites exhibits a tendency to increase firstly and then decrease,and the melt flow rate exhibits a tendency to increase.The PTWs/PP composite filled with 0.38% of PTWs presents the maximum thermal conductivity with the value of 0.5105 W·m-1·K-1 and the minimum volume resistivity of 109 Ω·cm,which meets the requirements for antistatic materials.

参考文献

[1] 蒋晓文.一种新型抗静电材料——碳纳米管抗静电复合材料的研究[C].2006中国国际毛纺织会议暨IWTO羊毛论坛论文集(上册),2006:228-232.
[2] M. Omastova';I. Chodak .Electrical and mechanical properties of conducting polymer composites[J].Synthetic Metals,1999(1/3):1251-1252.
[3] Ragimov A V;Mamedov B A;Gasanova S G .New efficient dielectric and antistatic materials based on oligoaminophenols[J].Polymer International,1997,43(04):343-346.
[4] 张诚,祝军,马淳安.聚合物/碳纳米管导电复合材料研究进展[J].浙江工业大学学报,2010(01):1-6.
[5] 金欣,肖长发,俞传坤,谢淳.碳黑/聚酯纤维非连续性导电行为研究[J].材料研究学报,2010(03):311-314.
[6] Zhifei Li;Guohua Luo;Fei Wei;Yi Huang .Microstructure of carbon nanotubes/PET conductive composites fibers and their properties[J].Composites science and technology,2006(7/8):1022-1029.
[7] Xia HS;Wang Q;Li KS;Hu GH .Preparation of polypropylene/carbon nanotube composite powder with a solid-state mechanochemical pulverization process[J].Journal of Applied Polymer Science,2004(1):378-386.
[8] Sumita M;Sakata K;Asal S et al.Dispersion of filler and the electrical conductivity of polymer blends filled with carbon black[J].Polymer Bulletin,1991,25(02):265-271.
[9] Dhawan S K;Singhb N;Rodriguesb D .Electromagnetic shielding behaviour of conducting polyaniline composites[J].Composites Science andTechnology,2004,64(13-14):2089-2096.
[10] 李光吉,冯晖,童奇勇.四针状氧化锌晶须/PP导热绝缘复合材料的制备与性能研究[J].材料研究与应用,2008(04):511-516.
[11] 金亚旭,华林.镍-磷-钛酸钾晶须化学复合镀层的制备及性能[J].中国有色金属学报,2007(08):1280-1285.
[12] 林有希,高诚辉,陈明辉.碳酸钙晶须增强聚醚醚酮自润滑复合材料的动态力学行为[J].材料热处理学报,2009(06):36-40.
[13] 吕通建;隗学礼;赵宽放 等.钛酸钾晶须增强PA6的研究[J].工程塑料应用,1995,23(06):5-8.
[14] 程存康;邵雷雷;徐宏 等.导电晶须的制备方法[P].中国,200410015659,2005-12-21.
[15] 杜新胜,吕锋.聚丙烯研究与进展[J].化工中间体,2008(12):10-14.
[16] 周柳 .环氧树脂基导热绝缘复合材料的制备与性能研究[D].武汉理工大学,2008.
[17] Kirkpatrick S .Percolation and conduction[J].Reviews of Modern Physics,1973,45:574-588.
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