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模拟压水堆一回路加锌水环境,对镍基690合金在加锌浓度为10μg/kg的320℃,15.20MPa溶液中进行了1000h的腐蚀试验。采用XPS深度分析法对试样氧化膜进行分析。结果表明,锌能有效地降低690合金的均匀腐蚀速率,加锌后氧化膜形貌和成分都有了明显改变,氧化膜厚度变薄。

Zinc primary coolant addition of zinc, morphology and addition effects on general corrosion of Nickel- with 10 μg/kg zinc addition at 320 ℃, 15. 20 base Alloy 690 were investigated in simulated PWR MPa for 1000 h. The results show that with the ively reduced. The surface oxide film is thinner, the changed.

参考文献

[1] 刘侠和,吴欣强,韩恩厚.轻水堆结构材料在加锌水中的腐蚀行为研究现状与进展[J].腐蚀科学与防护技术,2011(04):287-292.
[2] Machet A.;Galtayries A.;Marcus P.;Combrade P.;Jolivet P.;Scott P. .XPS study of oxides formed on nickel-base alloys in high-temperature and high-pressure water[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2002(1):197-200.
[3] 乔培鹏,张乐福,刘瑞芹,姜苏青,朱发文.压水堆条件下锌对奥氏体不锈钢腐蚀性能的影响[J].原子能科学技术,2010(06):690-693.
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