主要采用硝酸铜、柠檬酸、油酸和RDX成功制作了含有铜离子的溶胶凝胶前驱体炸药,并在密闭容器中氩气保护下炸药爆轰合成了球形、颗粒尺寸均匀、核壳结构的石墨包覆铜纳米颗粒(Cu-Gs).采用XRD、TEM、Raman等表征了爆轰产物的结构组成、形貌特征及包覆层构成.通过优化设计调整前驱体炸药的元素摩尔组成、密度及氧平衡,从而来寻求控制合成Cu-Gs的途径.最后简要讨论了Cu-Gs的生长机理.
参考文献
[1] | Park BK;Kim D;Jeong S;Moon J;Kim JS .Direct writing of copper conductive patterns by ink-jet printing[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(19):7706-7711. |
[2] | Jiao J.;Seraphin S. .Carbon encapsulated nanoparticles of Ni, Co, Cu, and Ti[J].Journal of Applied Physics,1998(5):2442-2448. |
[3] | Li, XS;Cai, WW;Colombo, L;Ruoff, RS .Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling[J].Nano letters,2009(12):4268-4272. |
[4] | Luo, N.;Liu, K.X.;Li, X.J.;Wu, Z.W.;Wu, S.Y.;Ye, L.M.;Shen, Y. .Synthesis of graphite-coated copper nanoparticles by the detonation of a copper-doped emulsion explosive[J].Mendeleev Communications,2012(5):248-249. |
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