本文研究了带有阻挡型阳极氧化膜或空气中生成的氧化膜的纯铝浸泡在中性1MNa_2CrO_4/Na_2Cr_2O_7溶液中时的交流阻抗行为。高频下的阻抗数据主要跟膜的介电性质有关,而1Hz以下低频的数据反映了膜上进行的电化学过程。对于空气氧化膜,电化学反应速度逐步变慢,直至达到相应于稳定钝态的恒定值,同时电位向正移动,表明膜中的微裂纹不断得到修补。阳极氧化膜的情况较为复杂。开始时氧化膜比较厚,电化学反应主要局限在微裂纹内,由于阴极反应受抑止,电位变负;随着氧化膜减薄,电位变正,电化学反应速度加快,最后进入稳定钝态。
The impedance behaviour of aluminium supporting air-formed and anodie films has been examined during immersion in neut al molar Na_2CrO_4/Na_2Cr_2O_7 solution. High frequency data were largely associated with dielectric properties of the oxide films whilst low frequency data, below 1 Hz, gave information on faradaic processes proceeding at flaws. With air-formed films the faradaic processes decreased progressively to a constant rate consistant with the increase in potential, indicating the healing of surface flaws. The processes occurring on immersed anodic films were more complex. During the first 10 hours the initial film dissolution was accompanied by a decrease in potential with an apparent plugging of flaws. However, after about 20 hours, the anodic film thickness decreased sufficiently to allow the faradaic processes toinerease to, the final steady state value.
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