欢迎登录材料期刊网

材料期刊网

高级检索

对熔炼铁捕集物采用两段逆流浸出工艺富集铂族金属进行研究。结果表明,在铁捕集物粉粒度为–0.425 mm,一段浸出温度为常温,浸出硫酸浓度为1.7~1.8 mol/L,固液比(S:L)=1:10,反应时间为0.5 h;二段浸出温度为75℃,浸出硫酸浓度为2 mol/L,S:L=1:50,反应时间为4 h。经此两段浸出后,铂族金属的平均富集倍数为70.6,铂族金属回收率大于99.8%。

The enrichment process of platinum group metals (PGMs) in the PGM-bearing iron-trapping material was investigated by using the“two-stage countercurrent leaching”technology. When particle size of iron-trapping material was–0.425 mm, the experimental condition for the first stage leaching was room temperature, sulfuric acid concentration of 1.7~1.8 mol/L, solid and liquid ratio (S:L) of 1:10 and leaching for 0.5 h, while that for the second stage leaching was 75℃, sulfuric acid concentration of 2 mol/L, solid and liquid ratio of 1:50 and leaching for 4 h. After two stages leaching, PGMs were enriched about 70.6 times in the iron-trapping material and at least 99.8%of PGMs could be recovered.

参考文献

[1] 刘时杰.铂族金属冶金学[M].长沙:中南大学出版社,2013
[2] 巢亚军,熊长芳,朱超.废工业催化剂回收技术进展[J].工业催化,2006(02):64-67.
[3] 赵桂良,高超,史建公,张敏宏,张毅,尹国海,石勤智,刘志坚.含铂废催化剂综合利用技术进展[J].中外能源,2010(03):65-71.
[4] 姜东,廖秋玲,龚卫星.我国失效汽车尾气净化器回收现状及发展前景[J].中国资源综合利用,2009(09):7-9.
[5] Chen Jing;Xie Mingjin;Chen Yinan.Recovering platinum group metals from collector obtained fusion[A].Kunming,1997
[6] 付光强,范兴祥,董海刚,吴跃东,刘杨,闫君禺,行卫东,左川.贵金属二次资源回收技术现状及展望[J].贵金属,2013(03):75-81.
[7] 王金利,刘洋.国内废催化剂中铂的回收及提纯技术[J].化学工业与工程技术,2011(01):20-24.
[8] M.A.Barakat;M.H.H.Mahmoud;Y.S.Mahrous .Recovery and separation of palladium from spent catalyst[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(2):182-186.
[9] Sri Harjanto;Yucai Cao;Atsushi Shibayama .Leaching of Pt, Pd and Rh from Automotive Catalyst Residue in Various Chloride Based Solutions[J].Materials transactions,2006(1):129-135.
[10] 吴晓峰,汪云华,童伟锋.湿-火联合法从汽车尾气失效催化剂中提取铂族金属新工艺研究[J].贵金属,2010(04):24-28,31.
[11] 吴晓峰;董海刚;童伟锋 .从氧化铝载体石化催化剂中熔炼提取铂族金属的方法[P].中国,CN201310005494.8 ,2013-04-03.
[12] 汪云华;吴晓峰;童伟锋 .矿相重构从汽车催化剂中提取铂钯铑的方法[P].中国,CN200910094112.7,2010-08-25.
[13] 吴晓峰;汪云华;童伟锋 .湿-火联合法从汽车催化剂中提取贵金属的方法[P].中国,CN200910094317.5,2010-10-13.
[14] 董海刚;陈家林;吴跃东 .一种从熔炼铁捕集物料中除铁富集铂族金属的方法[P].中国,CN201310099297.7,2013-07-03.
[15] 干方良 .熔炼富集-湿法分离工艺从失效汽车催化剂中提取贵金属的方法[P].中国,CN201210060308.6,2013-07-10.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%