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水泥基渗透结晶型防水涂料中的活性离子可以与钙离子形成一种溶于水的不稳定络合物,通过络合-取代反应生成不溶于水的结晶体沉淀来达到使水泥混凝土结构防水的目的.采用分光光度法对该不稳定络合物的稳定常数进行了测定.

An unstable water-soluble complex compound can be formed by the reaction between active ion of permeable crystalline coating and calcium ion,a great quantity of needle water-fast crystals are produced by complexation-substitution reaction,which can prevent the pores and cracks of concrete and improve the impermeability of concrete.In this paper,the stability constant of unstable complex compound is measured by spectrophotometry.

参考文献

[1] Wang Guiming,Yu Jianying.Self-healing Action of Permeable Crystalline Coating on Pores and Cracks in Cement-based Materials[J].武汉理工大学学报(材料科学版)英,2005(01):89-91,97.
[2] 陈艳芳 .用回归分析方法研究络合物的组成[J].湖南化工,1997,27(04):58.
[3] 曹伟;付佩玉;梁维安 .离解度-回归法测定不稳定络合物的摩尔吸光系数和稳定常数[J].分析化学,1998,26(11):1408.
[4] 许晓文;杨万龙;沈含熙.定量化学分析[M].天津:南开大学出版社,1996
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