Co-Ni-P化学镀层具有很多优点,在超声波辅助下化学镀层更光亮、细腻.在超声波辅助下在铝黄铜表面化学镀Co-Ni-P合金镀层,研究了镀液主盐浓度比、还原剂浓度、配位剂浓度、缓冲剂浓度、温度、pH值对沉积速率的影响,确定了超声波辅助下获得最佳沉积速率的化学镀Co-Ni-P工艺.结果表明:最佳工艺为11.0 g/LNiCl2·6H2O,5.5 g/L CoCl2·6H2O,17 g/L NaH2PO2·H2O,50 g/L Na3C6H5O7·2H2O,48 g/L NH4Cl,温度75℃,pH值9.0;超声波化学镀层为非晶态结构,分布更均匀,表面更光亮.
参考文献
[1] | Sayed SM.;Ashour EA.;Youssef GI.;El-Raghy SM. .Effect of sulfide ions on the stress corrosion behaviour of Al-brass and Cu10Ni alloys in salt water[J].Journal of Materials Science,2002(11):2267-2272. |
[2] | Seungman Sohn;Tak Kang .The effects of tin and nickel on the corrosion behavior of 60Cu-40Zn alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):281-289. |
[3] | 王吉会;姜晓霞;李诗卓 .硼砷抑制黄铜脱锌的协同作用机制[J].科学通报,1997,42(06):669-672. |
[4] | Toivaneo R O;Lindroors U K.The effect of boron on the selective corrosion resistance of the Cu-35wt%Zn alloy[A].Toronto,Ottawa:National Research Council of Canada,1984:641-645. |
[5] | Picketing H W .Characteristic features of alloy polarization curves[J].Corrosion Science,1983,23(10):1107. |
[6] | 《表面处理工艺手册》编审委员会.表面处理工艺手册[M].上海:上海科学技术出版社,1991:255. |
[7] | Lowenheim F A;北航103教研室.现代电镀[M].北京:机械工业出版社,1982:855. |
[8] | 刘珍.溶液pH值对化学镀Ni-Co-P合金的影响[J].电镀与精饰,1999(01):17-18. |
[9] | Mallory G O;Hadju J B.Electroless Plating:Fundamentals and Applications[M].Orlando:America Electroplaters and Surface Finishers Society,1991:1-56. |
[10] | Narayanan TSNS.;Selvakumar S.;Stephen A. .Electroless Ni-Co-P ternary alloy deposits: preparation and characteristics[J].Surface & Coatings Technology,2003(2/3):298-307. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%