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By measuring the mass transfer coefficient of between water and oil, the oxygen transfer rate of bath in the BOF smelting process is researched, and the influence of top and bottom blowing gas flow rate on the mechanism of mass transfer between metal and slag is discussed. The results show that when the bottom blowing gas flow rate increases on the conditions of top blowing, the mass transfer rate evidently increases, and the influence ratio of top blowing on the mass transfer is 10 percent of bottom blowing; The relation among top gas flow rate, bottom gas flow rate and lance height are established by the stirring power density. The equation between the mass transfer coefficient between metal and slag is formed, which furnishes reference for optimizing process parameters of BOF. The relation between the emulsification ratio between water and oil and the bottom blowing gas flow rate on the condition of top and bottom blowing is obtained. The result shows that with the increase of the bottom blowing gas flow rate the emulsification ratio increases in linearity, which increases the mass transfer rate of benzoic acid between water and oil.

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